纺织学报 ›› 2016, Vol. 37 ›› Issue (10): 1-7.

• 纤维材料 •    下一篇

壳聚糖改性静电纺聚砜纤维膜对染料的过滤性能

  

  • 收稿日期:2015-12-07 修回日期:2016-07-25 出版日期:2016-10-15 发布日期:2016-10-31

Filtration property of chitosan-modified electrospun polysulfone fibrous membrane for dyes

  • Received:2015-12-07 Revised:2016-07-25 Online:2016-10-15 Published:2016-10-31

摘要:

为提高静电纺聚砜(PSF)纤维膜的亲水性、力学性能及其对可溶性染料的过滤性能,采用戊二醛交联壳聚糖溶液浸轧处理静电纺PSF纤维膜。研究了纤维膜的表面润湿性、力学性能及其在0.1MPa 恒压死端过滤条件下对分散蓝2BLN和弱酸性蓝N-RL的过滤性能。研究结果表明:处理后的静电纺PSF纤维膜的表面润湿性和力学性能均得到显著改善;未经处理的静电纺PSF纤维膜和体积分数为0.4%戊二醛交联壳聚糖溶液处理纤维膜对分散蓝2BLN的截留率都能达到94%以上,对弱酸性蓝N-RL的截留率都小于35%,但都能保持较高的过滤通量;而体积分数为0.48%戊二醛交联壳聚糖溶液处理纤维膜对分散蓝2BLN 和弱酸性蓝N?RL 的过滤效率分别为99.5%和92.4%,但是过滤通量急剧下降。

关键词: 静电纺聚砜纤维膜, 交联壳聚糖, 润湿性, 力学性能, 过滤性能

Abstract:

In order to improving poor wettability, mechanical property and rejection rate to water soluble dyes, the electrospun PSF fibrous membrane was padding with 2%-0.4% and 2%-0.48% chitosan solution cross-linked by glutaraldehyde. The wettability, mechanical property, and filtration property to disperse blue 2BLN and weak acid blue N-RL with dead-end filtration method under constant pressure 0.1MPa of electrospun PSF fibrous membrane before and after treatment were studied . The result showed that the wettability and mechanical property of electrospun PSF fibrous membrane have significantly improved after treatment. It also showed that the untreated and 2%-0.4% fibrous membranes had high rejection rate to disperse blue 2BLN which were all above 94%, and low rejection rate to weak acid blue N-RL which were all under 35%, but both of them had high filtration flux. However, the 2%-0.48% fibrous membrane had much higher rejection rate to disperse blue 2BLN and weak acid blue N-RL, was 99.5% and 92.4%, respectively, but the filtration flux was decreased greatly.

Key words: electrospun polysulfone fiberus membrane, cross-linked chitosan, wettability, mechanical property, filtration property

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