阳离子化棉织物的纳米乳胶荧光颜料染色

摘要/Abstract

摘要：

针对常规分散加工荧光颜料分散体粒径较大，稳定性较差的问题，采用细乳液聚合法制备了纳米乳胶荧光颜料，并将其作为着色剂用于改性棉织物染色，探讨了纳米荧光乳胶颜料对阳离子化棉织物的染色工艺。结果表明，依据本法制备的纳米乳胶荧光颜料的平均粒径为162 nm，Zeta电位为-34.3 mV，最大吸收波长为425 nm，最大荧光发射波长为517 nm。该着色剂对棉织物的染色性能与其阳离子化程度密切相关，在改性剂3-氯-2-羟基丙基三甲基氯化铵用量为0.10 mol/L时，改性棉织物较佳的染色工艺为pH值为7，染色温度50 °C，染色时间40 min，浴比1:30，染色织物具有良好的干湿摩擦牢度。

关键词: 纳米乳胶荧光颜料, 阳离子化棉织物, 细乳液聚合, 染色

Abstract:

As fluorescent pigment dispersion prepared by conventional disperse process has large particle size and poor stability, nanoscale latex fluorescent pigment was prepared via miniemulsion polymerization method and applied in dyeing of modified cotton fabric. The dyeing process of cationic cotton fabrics with nanoscale latex fluorescent pigment was investigated. The results show that the particle size of prepared nanoscale latex fluorescent pigment was 162 nm, and the obtained Zeta potential was -34.3 mV, the maximum adsorption wavelength was 425 nm, the maximum fluorescence emission wavelength was 517 nm. The dyeing performance of cationic cotton fibers with nanoscale latex fluorescent pigment was closely related to the cationization degree. Results show that when the concentration of 3-chloro-2-hydroxytrimethyl ammonium chloride was 0.10 mol/L, the optimized dyeing conditions were that the pH value was 7, the temperature and time were 50 °C, 40 min, the liquor ratio was 1:30, and the dyed cotton fabrics has good rubbing fastness.

Key words: nanoscale latex fluorecent pigment, cationic cotton fabrics, miniemulsion polymerization, dyeing

刘杰杜长森张丽平李敏付少海. 阳离子化棉织物的纳米乳胶荧光颜料染色[J]. 纺织学报, 2016, 37(10): 56-61.

参考文献

[1] 孟春丽, 安刚, 曹毅. 改性棉织物的涂料染色工艺探讨[J]. 印染助剂, 2011, 28(1): 42-45. MENG Chunli, AN Gang, CAO Yi. Discuss on pigment dyeing of modified cotton fabrics[J]. Textile Auxiltaries, 2011, 28(1): 42-45. [2] 崔浩然. 活性艳蓝 KN-R 染色色花成因与防止措施[J]. 印染, 2004, 30(13): 11-13. CUI Haoran. Reasons for defects arising in reactive brill blue KN-R dyeing and their preventive measures[J]. Dyeing and Finishing, 2004, 30(13): 11-13. [3] 蒋家云. 布速与气流染色[J]. 染整技术, 2010, 32(4): 42-45. JIANG Jiayun. Fabric Speed in air-flow dyeing[J]. Textile Dyeing and Finishing Journal, 2010, 32(4): 42-45. [4] Wu H T, Huang K Y, Lee K T. Supercritical fluid-assisted dispersion of CI pigment violet 23 in an organic medium[J]. Powder Technology, 2011, 206(3): 322-326. [5] WANG L, MA W, ZHANG S, et al. Preparation of cationic cotton with two-bath pad-bake process and its application in salt-free dyeing[J]. Carbohydrate Polymers, 2009, 78(3): 602-608. [6] HAO L, WANG R, LIU J, et al. Investigating the adsorption performance of nanoscale pigment on cationized cotton substrate[J]. Powder Technology, 2012, 222: 176-181. [7] 吴丹, 朱学坤, 王树根, 等. 阳离子醚化改性棉织物活性无盐染色[J]. 印染, 2011, 37(7): 28-30. WU Dan, ZHU Xuekun, WANG Shugen, et al. Salt-free reactive dyeing of cotton fabric modified by cationic etherifying agent[J]. Dyeing and Finishing, 2011, 37(7): 28-30. [8] 姚丹丹, 李小丽, 田安丽, 等. 超细颜料表面改性及其染色性能[J]. 印染, 2011, 37(4): 10-13. YAO Dandan, LI Xiaoli, TIAN Aali, et al. Surface modification of ultra-fine pigment and its dyeing performance[J]. Dyeing and Finishing, 2011, 37(4): 10-13. [9] 郝龙云, 许益, 蔡玉青, 等. 超细涂料染色工艺研[J].印染, 2004, 30(13): 1-4. HAO Longyun, XU Yi, CAI Yuqing, et al. Surface modification of ultra-fine pigment and its dyeing performance[J]. Dyeing and Finishing, 2004, 30(13): 1-4. [10] 潘煜怡, 马胜军, 富秀玲, 等. 无甲醛耐热荧光树脂颜料的研究进展[J]. 涂料工业, 2003, 33(7): 39-41. PAN Yuyi, MA Shengjun, FU Xiuling, et al. Technical progress in formaldehyde-free heat resistant fluorescent resin pigments[J]. Printing and Coating Industries, 2003, 33(7): 39-41. [11] WEBSTER J R. Fluorescent pigment compositions: America, US 6683124[P]. 2004-1-27. [12] HYCHE K W. Fluorescent pigment concentrates: America, US 5439971[P]. 1995-8-8. [13] NOWAK M T, Chen Q. Solvent-based fluorescent inks for writing instruments based upon pigment dispersions in non-aqueous solvents: America, US 6425948[P]. 2002-7-30. [14] 王平, 张丽平, 田安丽, 等. 荧光颜料对海藻纤维纺丝液及其膜性能的影响[J]. 纺织学报, 2015, 36(05): 48-53. WANG Ping, ZHANG Lipng, TIAN Anli, et al. Influence of fluorescent pigments on properties of alginate fiber spinning solution and its membrane[J]. Journal of Textile Research, 2015, 36(05): 48-53. [15] 李峻, 程建, 孙荣兴. 棉及其混纺针织面料荧光涂料染色[J]. 针织工业, 2011, 12: 1-11. LI Jun, CHENG Jian, SUN Rongxing. Fluorescent pigment dyeing of cotton and its blending fibers[J]. Knitting Industries, 2011, 12: 1-11. [16] 刘杰, 张丽平, 田安丽, 等. 利用细乳液聚合由溶剂黄43 制备纳米乳胶荧光颜料[J]. 精细化工, 2015, 32(9):1067-1071. LIU Jie, ZHANG Liping, TIAN Anli, et al. Preparation of nanoscale latex fluorescent pigment by miniemulsion polymerization method[J]. Fine Chemicals, 2015, 32(9):1067-1071. [17] 踪文争, 宋春燕, 刘建平, 等. 棉纤维阳离子改性及应用探究[J]. 染整技术, 2011, 33(12): 13-16. ZONG Wenzheng, SONG Chunyan, LIU Jianping, et al. Investigating the cationization of cotton fibers and its application[J]. Textile Dyeing and Finishing Journal, 2011, 33(12): 13-16. , [1] 孟春丽, 安刚, 曹毅. 改性棉织物的涂料染色工艺探讨[J]. 印染助剂, 2011, 28(1): 42-45. MENG Chunli, AN Gang, CAO Yi. Discuss on pigment dyeing of modified cotton fabrics[J]. Textile Auxiltaries, 2011, 28(1): 42-45. [2] 崔浩然. 活性艳蓝 KN-R 染色色花成因与防止措施[J]. 印染, 2004, 30(13): 11-13. CUI Haoran. Reasons for defects arising in reactive brill blue KN-R dyeing and their preventive measures[J]. Dyeing and Finishing, 2004, 30(13): 11-13. [3] 蒋家云. 布速与气流染色[J]. 染整技术, 2010, 32(4): 42-45. JIANG Jiayun. Fabric Speed in air-flow dyeing[J]. Textile Dyeing and Finishing Journal, 2010, 32(4): 42-45. [4] Wu H T, Huang K Y, Lee K T. Supercritical fluid-assisted dispersion of CI pigment violet 23 in an organic medium[J]. Powder Technology, 2011, 206(3): 322-326. [5] WANG L, MA W, ZHANG S, et al. Preparation of cationic cotton with two-bath pad-bake process and its application in salt-free dyeing[J]. Carbohydrate Polymers, 2009, 78(3): 602-608. [6] HAO L, WANG R, LIU J, et al. Investigating the adsorption performance of nanoscale pigment on cationized cotton substrate[J]. Powder Technology, 2012, 222: 176-181. [7] 吴丹, 朱学坤, 王树根, 等. 阳离子醚化改性棉织物活性无盐染色[J]. 印染, 2011, 37(7): 28-30. WU Dan, ZHU Xuekun, WANG Shugen, et al. Salt-free reactive dyeing of cotton fabric modified by cationic etherifying agent[J]. Dyeing and Finishing, 2011, 37(7): 28-30. [8] 姚丹丹, 李小丽, 田安丽, 等. 超细颜料表面改性及其染色性能[J]. 印染, 2011, 37(4): 10-13. YAO Dandan, LI Xiaoli, TIAN Aali, et al. Surface modification of ultra-fine pigment and its dyeing performance[J]. Dyeing and Finishing, 2011, 37(4): 10-13. [9] 郝龙云, 许益, 蔡玉青, 等. 超细涂料染色工艺研[J].印染, 2004, 30(13): 1-4. HAO Longyun, XU Yi, CAI Yuqing, et al. Surface modification of ultra-fine pigment and its dyeing performance[J]. Dyeing and Finishing, 2004, 30(13): 1-4. [10] 潘煜怡, 马胜军, 富秀玲, 等. 无甲醛耐热荧光树脂颜料的研究进展[J]. 涂料工业, 2003, 33(7): 39-41. PAN Yuyi, MA Shengjun, FU Xiuling, et al. Technical progress in formaldehyde-free heat resistant fluorescent resin pigments[J]. Printing and Coating Industries, 2003, 33(7): 39-41. [11] WEBSTER J R. Fluorescent pigment compositions: America, US 6683124[P]. 2004-1-27. [12] HYCHE K W. Fluorescent pigment concentrates: America, US 5439971[P]. 1995-8-8. [13] NOWAK M T, Chen Q. Solvent-based fluorescent inks for writing instruments based upon pigment dispersions in non-aqueous solvents: America, US 6425948[P]. 2002-7-30. [14] 王平, 张丽平, 田安丽, 等. 荧光颜料对海藻纤维纺丝液及其膜性能的影响[J]. 纺织学报, 2015, 36(05): 48-53. WANG Ping, ZHANG Lipng, TIAN Anli, et al. Influence of fluorescent pigments on properties of alginate fiber spinning solution and its membrane[J]. Journal of Textile Research, 2015, 36(05): 48-53. [15] 李峻, 程建, 孙荣兴. 棉及其混纺针织面料荧光涂料染色[J]. 针织工业, 2011, 12: 1-11. LI Jun, CHENG Jian, SUN Rongxing. Fluorescent pigment dyeing of cotton and its blending fibers[J]. Knitting Industries, 2011, 12: 1-11. [16] 刘杰, 张丽平, 田安丽, 等. 利用细乳液聚合由溶剂黄43 制备纳米乳胶荧光颜料[J]. 精细化工, 2015, 32(9):1067-1071. LIU Jie, ZHANG Liping, TIAN Anli, et al. Preparation of nanoscale latex fluorescent pigment by miniemulsion polymerization method[J]. Fine Chemicals, 2015, 32(9):1067-1071. [17] 踪文争, 宋春燕, 刘建平, 等. 棉纤维阳离子改性及应用探究[J]. 染整技术, 2011, 33(12): 13-16. ZONG Wenzheng, SONG Chunyan, LIU Jianping, et al. Investigating the cationization of cotton fibers and its application[J]. Textile Dyeing and Finishing Journal, 2011, 33(12): 13-16.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed