纺织学报 ›› 2025, Vol. 46 ›› Issue (03): 82-89.doi: 10.13475/j.fzxb.20240403601

• 纺织工程 • 上一篇    下一篇

基于镀银锦纶/锦纶/水性聚氨酯复合纱的一维结构柔性电容传感器

岳欣琰1,2, 邵剑波1,2, 王小虎1,2,3, 韩潇1,2, 赵晓曼1,2, 洪剑寒1,2,3()   

  1. 1.绍兴文理学院 纺织科学与工程学院, 浙江 绍兴 312000
    2.浙江省清洁染整技术研究重点实验室, 浙江 绍兴 312000
    3.浙江洁达新材料科技有限公司, 浙江 绍兴 312000
  • 收稿日期:2024-04-15 修回日期:2024-09-27 出版日期:2025-03-15 发布日期:2025-04-16
  • 通讯作者: 洪剑寒(1982—),男,教授,博士。主要研究方向为新型纺织材料的制备与应用。E-mail:jhhong@usx.edu.cn
  • 作者简介:岳欣琰(2000—),女,硕士生。主要研究方向为智能服装柔性器件的设计开发与应用。
  • 基金资助:
    国家自然科学基金项目(52300167);浙江省自然科学基金探索公益项目(LTGY24E030001);国家级大学生创新创业训练计划项目(202310349025)

One-dimensional structured flexible capacitive sensors based on silver coated polyamide fiber/polyamide fiber/waterborne polyurethane composite yarns

YUE Xinyan1,2, SHAO Jianbo1,2, WANG Xiaohu1,2,3, HAN Xiao1,2, ZHAO Xiaoman1,2, HONG Jianhan1,2,3()   

  1. 1. School of Textile Science and Engineering, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
    3. Zhejiang Jieda New Material Technology Co., Ltd., Shaoxing, Zhejiang 312000, China
  • Received:2024-04-15 Revised:2024-09-27 Published:2025-03-15 Online:2025-04-16

摘要: 为制备新型电容式柔性传感器,在镀银锦纶(SCN)芯纱表面包覆锦纶拉伸变形丝(PA),并对其浸渍水性聚氨酯(WPU)得到SCN/PA/WPU复合纱,然后利用复合纱设计制备了一维结构电容式柔性传感器。对SCN芯纱、SCN/PA包覆纱、SCN/PA/WPU复合纱进行形貌观察、力学性能测试,分析传感器的应变传感性能,并应用于人体生理活动的监测。结果表明:SCN/PA/WPU复合纱和SCN/PA包覆纱的力学性能较SCN芯纱有明显提升;传感器表现出良好的应变-电容传感性能,具有0%~140%的工作响应范围;在10%的拉伸应变下,其灵敏度系数为0.66,且重复性良好,能够承受1 200次以上的拉伸-卸载循环,可用于人体运动与生理活动的实时监控。

关键词: 镀银锦纶, 锦纶, 包覆纱, 一维结构, 电容式传感器, 人体运动监测, 水性聚氨酯

Abstract:

Objective Wearable flexible sensors have become an important part of smart textiles, and flexible capacitive wearable sensors continue to develop in the direction of flexibility, miniaturization, portability and flexibility. In order to develop new flexible capacitive sensors and promote the continuous production of wearable flexible sensors, low-cost and high-efficiency preparation processes have received attention of researchers.

Method Silver coated nylon (SCN) as core yarn and nylon DTY (PA) as outer wrapper were selected to produce SCN/PA wrapped yarn through the automated wrapping yarn production process. The SCN/PA wrapped yarns were obtained by double-layer reverse twisting method, the inner yarns were twisted with S-twist and the outer winding yarns were twisted with Z-twist, with a twist rate of 1 000 t/m under the process parameters. The SCN/PA wrapped yarn was impregnated with waterborne polyurethane (WPU) to obtain the SCN/PA/WPU composite yarn, and then the composite yarn was adopted to design and prepare a one-dimensional structured flexible capacitive sensor. The SCN core yarn, SCN/PA wrapped yarn, and SCN/PA/WPU composite yarn were subjected to morphological observation, mechanical property tests, and the strain sensing properties of the sensors were investigated and practically applied to the monitoring of human activities.

Results The mechanical properties of both SCN/PA/WPU composite yarn and SCN/PA wrapped yarn were significantly improved compared with SCN core yarn. The design of one-dimensional flexible capacitive sensors using SCN/PA/WPU composite yarns by spiral winding method showed good tensile strain-capacitance sensing performance. The sensor has an operating response range of 0-140%. As the tensile strain was increased sequentially, the capacitance value of the sensor got decreased, and when the strain was small, the sensor exhibited good linearity and sensitivity factor. When the strain continued to increase, the sensor linearity and gauge factor began to weaken. At 10% of the tensile strain, its gauge factor was 0.66. The sensor can withstand 1 200 times of tension-unloading cycle, and its capacitance value is relatively stable, demonstrating good repeatability. The change in capacitance of the sensor remained stable with the constant change in tensile velocity, both at small strains of 40% and at large strains of 100%, demonstrating that the change in tensile speed was hardly a negative influence on the sensing performance of the sensor. Applying the sensor to real-time monitoring of human movement, it can accurately monitor the continuous bending and intermittent movement states of the joint parts of the human body at the fingers, wrists, and elbows. In addition, the sensors can accurately record small amplitude differences between changes in continuous bending movements of the human body. The sensor was also attached to near the volunteer's mouth, the sensor also captured the signal of small tensile strainswhen the mouth made.

Conclusion A low-cost, high-efficiency, continuous processing automated production process of covering yarn was adopted to prepare SCN/PA wrapping yarn, then dip-coating WPU treatment was carried out to prepare SCN/PA/WPU composite yarn. The design of one-dimensional structure flexible capacitive sensors based on SCN/PA/WPU composite yarns demonstrated excellent gauge factor, stability, and repeatability. The application of the sensor to real-time monitoring of human movement can accurately monitor the continuous bending and intermittent motion state of the joint parts of the human body in the fingers, wrists and elbows, and can also monitor small changes in the activity of the human mouth. The sensor capacitance changes can also be utilized to distinguish the motion action as well as calculate the angle of human joint motion. In view of the superior sensing properties of this one-dimensional structured flexible capacitive sensor, it has potential applications in the fields of sports health monitoring, medical health promotion and smart wearable devices.

Key words: wrapped yarn, one-dimensional structure, capacitive sensor, human motion monitoring, waterborne polyurethane

中图分类号: 

  • TS104

图1

一维结构电容式柔性传感器"

图2

人体生理活动监测的应用"

图3

SCN芯纱、SCN/PA包覆纱、SCN/PA/WPU复合纱形貌"

图4

SCN芯纱、SCN/PA包覆纱和SCN/PA/WPU复合纱的拉伸断裂性能"

表1

SCN芯纱、SCN/PA包覆纱、SCN/PA/WPU复合纱的断裂强力和断裂伸长率"

试样名称 断裂强力/N 断裂伸长率/%
SCN芯纱 1.92 12.67
SCN/PA包覆纱 7.78 17.42
SCN/PA/WPU复合纱 8.03 18.16

图5

电容式柔性传感器的传感原理"

图6

不同拉伸应变下的传感器相对电容值变化"

图7

不同应变下拉伸速度变化对传感器传感性能的影响"

图8

一维结构柔性电容传感器的稳定性"

图9

传感器对人体生理活动监测"

[1] YU A, ZHU M, CHEN C, et al. Implantable flexible sensors for health monitoring[J]. Advanced Healthcare Materials, 2024. DOI: 10.1002/adhm.202302460.
[2] HUYNH T P, HAICK H. Autonomous flexible sensors for health monitoring[J]. Advanced Materials, 2018. DOI: 10.1002/adma.201802337.
[3] MEI Yang, Yongfa Cheng, Yang Yue, et al. High-performance flexible pressure sensor with a self-healing function for tactile feedback[J]. Advanced Science, 2022. DOI: 10.1002/advs.202200507.
[4] LI J, YIN J, WEE M G V, et al. A self-powered piezoelectric nanofibrous membrane as wearable tactile sensor for human body motion monitoring and recog-nition[J]. Advanced Fiber Materials, 2023, 5(4),1417-1430.
[5] ZHU Y, ZHAO B, LEI L, et al. Facile construction of a flexible smartcore-sheath flax yarns with temperature-responsive resistance for ultra-fast fire-alarm response[J]. Chemical Engineering Journal, 2023. DOI: 10.1016/j.cej.2023.144718.
[6] GAO H, CHEN T. A flexible ultra-highly sensitive capacitive pressure sensor for basketball motion monitoring[J]. Discover Nano, 2023. DOI: 10.1186/s11671-023-03783-y.
[7] LIANG Q, ZHANG D, WU Y, et al. Stretchable helical fibers with skin-core structure for pressure and proximity sensing[J]. Nano Energy, 2023. DOI: 10.1016/j.nanoen.2023.108598.
[8] ZHANG S C, XU J T. PDMS/Ag/mxene/polyurethane conductive yarn as a highly reliable and stretchable strain sensor for human motion monitoring[J]. Polymers, 2022. DOI: 10.3390/polym14245401.
[9] XIE X, HUANG H, ZHU J, et al. A spirally layered carbon nanotube-graphene/polyurethane composite yarn for highly sensitive and stretchable strain sensor[J]. Composites Part A: Applied Science and Manufacturing, 2020. DOI: 10.1016/j.compositesa.2020.105932.
[10] LI F, XUE H, LIN X, et al. Wearable temperature sensor with high resolution for skin temperature monitoring[J]. ACS Applied Materials & Interfaces, 2022, 14(38): 43844-43852.
[11] COOPER C B, ARUTSELVAN K, LIU Y, et al. Stretchable capacitive sensors of torsion, strain, and touch using double helix liquid metal fibers[J]. Advanced Functional Materials, 2017. DOI: 10.1002/adfm.201605630.
[12] GENG W, CUTHBERT T J, MENON C. Conductive thermoplastic elastomer composite capacitive strain sensors and their application in a wearable device for quantitative joint angle prediction[J]. ACS Applied Polymer Materials, 2020, 3(1): 122-129.
[13] HAN Xiao, FAN Mengjing, YUE Xinyan, et al. Linear flexible capacitive sensor with double helix structure based on multi-needle water-bath electrospinning technology[J]. Smart Materials and Structures, 2023. DOI: 10.1088/1361-665x/acb40d.
[14] 周歆如, 范梦晶, 岳欣琰, 等. 导电微纳纤维复合纱的制备及其气敏特性[J]. 纺织学报, 2024, 45(2):52-58.
ZHOU Xinru, FAN Mengjing, YUE Xinyan, et al. Preparation of conductive micro-nano fiber composite yarns and their gas-sensitive properties[J]. Journal of Textile Research, 2024, 45(2):52-58.
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