纺织学报 ›› 2021, Vol. 42 ›› Issue (10): 172-179.doi: 10.13475/j.fzxb.20201203808

• 综合述评 • 上一篇    下一篇

芳香族聚酰胺分离膜制备方法及应用进展

赖星1, 王纯1,2(), 肖长发2, 王黎明1, 辛斌杰1   

  1. 1.上海工程技术大学 纺织服装学院, 上海 201620
    2.天津工业大学 分离膜与膜过程国家重点实验室, 天津 300387
  • 收稿日期:2020-12-14 修回日期:2021-05-31 出版日期:2021-10-15 发布日期:2021-10-29
  • 通讯作者: 王纯
  • 作者简介:赖星(1995—),男,硕士生。主要研究方向为高分子膜材料。
  • 基金资助:
    国家自然科学基金项目(21808165)

Progress in preparation and application of aromatic polyamide separation membrane

LAI Xing1, WANG Chun1,2(), XIAO Changfa2, WANG Liming1, XIN Binjie1   

  1. 1. School of Textile and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
    2. State Key Laboratory of Separation Membrane and Membrane Processes, Tiangong University,Tianjin 300387, China
  • Received:2020-12-14 Revised:2021-05-31 Published:2021-10-15 Online:2021-10-29
  • Contact: WANG Chun

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摘要：

为更好地了解可用于特种分离领域的芳香族聚酰胺分离膜材料研究现状,综述了国内外近年来以芳香族聚酰胺为成膜聚合物的多孔分离膜材料研究进展,重点评述了现阶段芳香族聚酰胺多孔分离膜的制备方法及其特点,着重分析了芳香族聚酰胺多孔分离膜在废水处理、空气过滤、锂离子电池隔膜以及纤维增强膜等领域的应用现状。最后提出芳香族聚酰胺多孔分离膜目前仍存在的不足,并展望了芳香族聚酰胺多孔分离膜的应用前景及发展方向,以期为实现芳香族聚酰胺多孔分离膜的低能耗、高效率制备以及高值化利用提供参考。

关键词: 芳香族聚酰胺, 多孔分离膜, 废水处理, 空气过滤, 锂离子电池隔膜, 纤维增强膜

Abstract:

In order to better understand the research status of aromatic polyamide separation membrane materials which can be used in special separation field, this paper reviewed the research progress of porous membrane materials with aromatic polyamide as membrane-forming polymer at home and abroad in recent years, and reviewed the preparation methods and characteristics of aromatic polyamide porous membrane at present stage. In addition, it was analyzed that the application of aromatic polyamide porous membrane is suitable for wastewater treatment, air filtration, lithium ion battery separator and fiber reinforced membrane. Finally, the shortcomings of the porous membrane of aromatic polyamide were spelt out, and the application prospect and development direction of the porous membrane of aromatic polyamide were prospected, so as to provide reference for the realization of low energy consumption, high efficiency preparation and high value utilization of aromatic polyamide porous membrane.

Key words: aromatic polyamide, porous membrane, wastewater treatment, air filtration, lithium ion battery separator, fiber reinforced membrane

中图分类号: 

  • TQ028.8

表1

芳香族聚酰胺多孔分离膜制备方法及主要性能"

制备方法 膜形式 膜基材 溶剂 主要特点 参考文献
相转化法 平板膜 PPTA H2SO4 操作简单,膜结构易调控 [11]
去质子化法 纳米纤维膜 PPTA DMSO-KOH 制备条件温和,原纤化程度高,
但仅适用于实验室研究		 [12]
干-湿法纺丝 中空纳米纤维膜 PMIA DMAc 生产效率高,膜自支撑性好 [13]
静电纺丝法 纳米纤维膜 PMIA DMAc 纤维尺寸可控,但制备效率低,调控因素多,
较难以实现规模化		 [14]
同质纤维增强 纤维增强型中空纤维膜 PMIA DMAc 界面结合高,力学性能高,使用寿命长 [15]

图1

纤维增强型中空纤维膜横截面形貌"

图2

芳香族聚酰胺多孔分离膜的应用"

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