纺织学报 ›› 2022, Vol. 43 ›› Issue (05): 26-31.doi: 10.13475/j.fzxb.20211206006

• 特约专栏:第十一届中国纺织学术年会专家观点 • 上一篇    下一篇

蓖麻油基紫外光固化水性涂料墨水制备及其印花性能

戚栋明1, 樊高晴1, 虞一浩2, 符晔2, 张艳1, 陈智杰3()   

  1. 1.浙江理工大学 绿色低碳染整技术浙江省工程研究中心, 浙江 杭州 310018
    2.浙江凯瑞博科技有限公司,浙江 湖州 313100
    3.温州职业技术学院 聚合物材料及机电产品表面改性技术研究重点实验室, 浙江 温州 325035
  • 收稿日期:2021-12-18 修回日期:2022-02-11 出版日期:2022-05-15 发布日期:2022-05-30
  • 通讯作者: 陈智杰
  • 作者简介:戚栋明(1978—),男,教授,博士。主要研究方向为功能性复合乳胶制备及成膜。
  • 基金资助:
    浙江省重点研发计划项目(2021C01077);温州市科技局基础性科研项目(G2020025)

Preparation and printing properties of castor oil-based UV-curable water-based coating ink

QI Dongming1, FAN Gaoqing1, YU Yihao2, FU Ye2, ZHANG Yan1, CHEN Zhijie3()   

  1. 1. Zhejiang Provincial Engineering Center for Green and Low-Carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Zhejiang King Label Technology Co., Ltd., Huzhou, Zhejiang 313100, China
    3. Key Laboratory of Surface Modification Technology for Polymer Materials and Electromechanical Products, Wenzhou Polytechnic, Wenzhou, Zhejiang 325035, China
  • Received:2021-12-18 Revised:2022-02-11 Published:2022-05-15 Online:2022-05-30
  • Contact: CHEN Zhijie

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摘要：

为解决传统涂料印花存在的手感和牢度难以兼顾的问题,以蓖麻油、异佛尔酮二异氰酸酯、2,2-二羟甲基丁酸缩聚,再以季戊四醇三丙烯酸酯为封端剂,制得具有优异分散性、耐水性、黏结牢度的水性聚氨酯乳液,并在加入纳米颜料后制得蓖麻油基紫外光固化水性涂料墨水。研究并分析了蓖麻油含量对乳液粒径、固化胶膜性能、耐水性等的影响及原因。随后以涤纶平纹织物为代表,对比表征了蓖麻油基紫外光固化水性涂料墨水喷墨印花织物表面形貌和硬挺度、耐干湿摩擦色牢度等性能,结果表明,在最佳蓖麻油质量分数为42.1%时,喷墨印花织物具有良好的柔性和色牢度。

关键词: 蓖麻油, 聚氨酯, 涂料印花, 紫外光固化, 喷墨印花织物

Abstract:

Waterborne polyurethane emulsions were prepared aiming at difficulty in achieve good handle and fastness through the traditional coat printing. This emulsion was produced by condensing castor oil, isophorone diisocyanate, and 2,2-bis(hydroxymethyl)butyric acid, using pentaerythritol triacrylate as a capping agent, for improved dispersibility, water resistance, and bonding fastness. Castor oil-based ultraviolet (UV)-curable waterborne coating inks were obtained by adding nano-pigments to the waterborne polyurethane emulsions. The effect and mechanism of castor oil content on the emulsion particle size, cured film performance, and water resistance were studied and analyzed. Subsequently, the castor oil-based UV-curable water-based coating ink was sprayed on polyester plain fabrics, and the surface morphology, stiffness and wet and dry friction fastness of the printed fabrics were comparatively characterized. The results obtained showed that the ink-jet printed fabric has good flexibility and color fastness under the optimum amount of castor oil 42.1%.

Key words: castor oil, polyurethane, pigment printing, ultraviolet curing, ink-jet printed fabric

中图分类号: 

  • TQ325

图1

蓖麻油质量分数对聚氨酯乳液的粒径影响"

图2

不同蓖麻油质量分数的聚氨酯胶膜DSC曲线"

表1

蓖麻油质量分数对聚氨酯胶膜吸水率的影响"

蓖麻油质量分数/% 吸水率/%
30.5 8.64
36.4 6.85
42.1 3.23
47.7 3.12
53.3 3.10

图3

不同蓖麻油质量分数聚氨酯所制印花织物表面扫描电镜照片(×2 000)"

图4

蓖麻油质量分数对印花织物硬挺度的影响"

表2

蓖麻油质量分数对印花织物耐摩擦色牢度的影响"

蓖麻油质量分数/% 耐摩擦色牢度/级
干 湿
30.5 2 2
36.4 4 2
42.1 4~5 4~5
47.7 4 4
53.3 4 4
[1] HAROUN A A, DIAB H A, HAKEIM O A. Cellulosic fabrics printing with multifunctional encapsulated phthalocyanine pigment blue using phase separation method[J]. Carbohydrate Polymers, 2016, 146: 102-108.
doi: 10.1016/j.carbpol.2016.03.039
[2] 付少海, 王大同, 杜长森, 等. 提高喷墨印花颜料墨水印花牢度的方法[J]. 纺织学报, 2015, 36(2): 141-147.
FU Shaohai, WANG Datong, DU Changsen, et al. Improve color fastness of inkjet printing textiles using pigment ink[J]. Journal of Textile Research, 2015, 36(2): 141-147.
[3] 汪芬萍, 李家炜, 黄骅隽, 等. 纺织品着色用有机颜料改性技术的研究进展[J]. 纺织学报, 2021, 42(7): 192-200.
WANG Fenping, LI Jiawei, HUANG Huajuan, et al. Research progress of organic pigment modification technology for textiles coloration[J]. Journal of Textile Research, 2021, 42(7): 192-200.
[4] 关玉, 王大同, 杜长森, 等. 细乳液聚合炭黑/乳胶粒纳米复合粒子的制备及其性能[J]. 纺织学报, 2014, 35(9): 73-78.
GUAN Yu, WANG Datong, DU Changsen, et al. Preparation and printing behavior of carbon black/latex nanocomposite particles by miniemulsion polymeriza-tion[J]. Journal of Textile Research, 2014, 35(9): 73-78.
doi: 10.1177/004051756503500108
[5] 张凯, 王春霞, 田安丽, 等. 基于细乳液聚合法的超细包覆炭黑制备及其性能[J]. 纺织学报, 2013, 34(1): 79-83.
ZHANG Kai, WANG Chunxia, TIAN Anli, et al. Preparation and properties of encapsulated ultrafine carbon black by miniemulsion polymerization[J]. Journal of Textile Research, 2013, 34(1): 79-83.
doi: 10.1177/004051756403400113
[6] 陈智杰, 胡旭东, 黄卓, 等. 基于细乳液法含硅颜料胶囊的制备及其对涤纶的印花性能[J]. 纺织学报, 2019, 40(8): 69-75.
CHEN Zhijie, HU Xudong, HUANG Zhuo, et al. Preparation of silicone-containing pigment capsules by miniemulsion polymerization and printing performance thereof on polyester fabric[J]. Journal of Textile Research, 2019, 40(8): 69-75.
[7] LEELAJARIYAKUL S, NOGUCHI H, KIATKAMJORNWONG S. Surface-modified and micro-encapsulated pigmented inks for ink jet printing on textile fabrics[J]. Progress in Organic Coatings, 2008, 62(2): 145-161.
doi: 10.1016/j.porgcoat.2007.10.005
[8] 冯艳荣, 袁剑民, 王文力, 等. 水性聚丙烯酸酯涂料染色黏合剂的合成及其性能[J]. 纺织学报, 2017, 38(4): 90-96.
FENG Yanrong, YUAN Jianmin, WANG Wenli, et al. Synthesis and properties of waterborne polyacrylate coating dyeing binder[J]. Journal of Textile Research, 2017, 38(4): 90-96.
[9] 杨帆, 陈远辉, 顾晨成, 等. 紫外光固化水性聚氨酯丙烯酸酯黏合剂的印花性能[J]. 纺织学报, 2016, 37(3): 82-86.
YANG Fan, CHEN Yuanhui, GU Chencheng, et al. Printing performance of UV curable waterborne polyurethane acrylate adhesive[J]. Journal of Textile Research, 2016, 37(3): 82-86.
[10] SONG Y, FANG K, BUKHARI M N, et al. Green and efficient inkjet printing of cotton fabrics using reactive dye@copolymer nanospheres[J]. ACS Applied Materials & Interfaces, 2020, 12(40): 45281-45295.
[11] 宋亚伟, 房宽峻, 张建波, 等. 喷墨技术及其在纺织品印花中的应用进展[J]. 纺织学报, 2015, 36(8): 165-172.
SONG Yawei, FANG Kuanjun, ZHANG Jianbo, et al. Inkjet technology and its application in textile printing[J]. Journal of Textile Research, 2015, 36(8): 165-172.
[12] 李敏, 赵影, 张丽平, 等. 涤纶针织物数码印花清晰度的影响因素[J]. 纺织学报, 2018, 39(5): 62-66.
LI Min, ZHAO Ying, ZHANG Liping, et al. Factors influencing printing accuracy of digital printing for knitted polyester fabric[J]. Journal of Textile Research, 2018, 39(5): 62-66.
[13] 孟一丁, 邵建中, 黄益, 等. 一体化聚氨酯丙烯酸酯的合成及其在光固化数码印花中的应用[J]. 纺织学报, 2018, 39(2): 97-105.
MENG Yiding, SHAO Jianzhong, HUANG Yi, et al. Synthesis of integrated polyurethane acrylate and application thereof in photo-curable ink-jet printing[J]. Journal of Textile Research, 2018, 39(2): 97-105.
doi: 10.1177/004051756903900116
[14] 张思, 吴敏. 紫外光固化密胺树脂的合成及涂层织物性能测试[J]. 纺织学报, 2019, 40(6): 65-68.
ZHANG Si, WU Min. Synthesis of UV curing melamine resin and performance testing of its coating fabric[J]. Journal of Textile Research, 2019, 40(6): 65-68.
[15] AHN B U, LEE S K, LEE S K, et al. High performance UV curable polyurethane dispersions by incorporating multifunctional extender[J]. Progress in Organic Coatings, 2007, 60(1): 17-23.
doi: 10.1016/j.porgcoat.2007.06.001
[16] DEFLORIAN F, FEDEL M, DIGIANNI A, et al. Corrosion protection properties of new UV curable waterborne urethane acrylic coatings[J]. Corrosion Engineering, Science and Technology, 2008, 43(1): 81-86.
doi: 10.1179/174327808X286194
[17] CHEN S, ZHANG S, LI Y, et al. Synthesis and properties of novel UV-curable hyperbranched waterborne polyurethane/Fe3O4 nanocomposite films with excellent magnetic properties[J]. RSC Advances, 2015, 5(6): 4355-4363.
doi: 10.1039/C4RA13683G
[18] BOTON L, PUGUAN J M, LATIF M, et al. Synthesis and properties of quick-drying UV-curable hyperbranched waterborne polyurethane coating[J]. Progress in Organic Coatings, 2018, 125: 201-206.
doi: 10.1016/j.porgcoat.2018.09.017
[19] ZHANG Y, ZHANG W, WANG X, et al. Waterborne polyurethanes from castor oil-based polyols for next generation of environmentally-friendly hair-styling agents[J]. Progress in Organic Coatings, 2020, 142: 105588.
doi: 10.1016/j.porgcoat.2020.105588
[20] ZHANG C, LIANG H, LIANG D, et al. Renewable castor-oil-based waterborne polyurethane networks: simultaneously showing high strength, self-healing, processability and tunable multishape memory[J]. Angewandte Chemie International Edition, 2021, 60(8): 4289-4299.
doi: 10.1002/anie.202014299
[21] LIANG H, LIU L, LU J, et al. Castor oil-based cationic waterborne polyurethane dispersions: storage stability, thermo-physical properties and antibacterial properties[J]. Industrial Crops and Products, 2018, 117: 169-178.
doi: 10.1016/j.indcrop.2018.02.084
[22] LU J, ZHANG Y, TAO Y, et al. Self-healable castor oil-based waterborne polyurethane/MXene film with outstanding electromagnetic interference shielding effectiveness and excellent shape memory performance[J]. Journal of Colloid and Interface Science, 2021, 588: 164-174.
doi: 10.1016/j.jcis.2020.12.076
[23] AN X P, CHEN J H, LI Y D, et al. Rational design of sustainable polyurethanes from castor oil: towards simultaneous reinforcement and toughening[J]. Science China Materials, 2018, 61(7): 993-1000.
doi: 10.1007/s40843-017-9192-8
[24] LIANG H, WANG S, HE H, et al. Aqueous anionic polyurethane dispersions from castor oil[J]. Industrial Crops and Products, 2018, 122: 182-189.
doi: 10.1016/j.indcrop.2018.05.079
[25] ZHANG J, WU Y, ZHANG H, et al. Castor oil-glycerol-based waterborne polyurethane dispersions[J]. Progress in Organic Coatings, 2021, 157: 106333.
doi: 10.1016/j.porgcoat.2021.106333
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