Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (04): 177-184.doi: 10.13475/j.fzxb.20180203008

• Comprehensive Review • Previous Articles    

Review on novel halogen-free polymer flame retardants

LI Qianglin1,2(), HUANG Fangqian2, XIAO Xiuchan1, QIU Cheng1, WU Juzhen1   

  1. 1. Center of Big Data for Smart Environmental Protection, Chengdu Technological University,Chengdu, Sichuan 611730, China
    2. Chengdu Textile College, Chengdu, Sichuan 611731, China
  • Received:2018-02-08 Revised:2018-12-14 Online:2019-04-15 Published:2019-04-16

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Abstract:

In order to improve the durability and washable resistance of flame retardant textiles, and avoid the generation of secondary pollutants such as dioxins and hydrogen halides at high temperature for conventional halogenated flame retardants, using halogen-free polymer flame retardant is one of the effective methods. This paper systematically described a series of branched, linear and crosslinked polymer flame retardants and their monomers containing flame retardant elements such as phosphorus, nitrogen and silicon. The types, structures, synthesis, properties and applications of polymer flame retardants such as phosphates (phosphonates), phosphoramides (phosphonamides), phosphorus-containing polysiloxane and bio-based flame retardants were mainly introduced. The current problems of flame retardants for textiles were analyzed. It was pointed out that the durable flame retardant should focus on the synthesis of eco-friendly flame retardants with high phosphorus-nitrogen content and high reactivity, and should increase the research on synergistic mechanism of multi-component compounds, and accelerate the research direction of modern physical finishing technology research.

Key words: flame retardant textile, halogen-free flame retardant, bio-based flame retardant, coating, polymer

CLC Number: 

  • TS106.5

Fig.1

Schematic diagrame of graft reaction for preparation of branched-chain polymatic flame retardant"

Fig.2

Structure of MOPEHCP and EOPEHCP"

Fig.3

Schematic diagrame of copolymerization for preparation of branched-chain flame-retardant polymers"

Fig.4

Structure diagram of multifunctional monomer block copolymer flame retardants"

Fig.5

Structure diagram of bifunctional flame retardant monomers"

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