Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (02): 114-118.doi: 10.13475/j.fzxb.20180708905

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel

LIU Fei1,2, LI Qiujin1,2,3(), GONG Jixian1,2, LI Zheng1,2, LIU Xiuming1,2,3, ZHANG Jianfei1,2,4   

  1. 1. School of Textile Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
    2. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China
    3. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    4. Collaborative Innovation Center for Eco-Textiles of Shangdong Province, Shandong, Qingdao 266071, China
  • Received:2018-07-30 Revised:2018-11-05 Online:2019-02-15 Published:2019-02-01
  • Contact: LI Qiujin E-mail:vicmaldini@126.com

RichHTML

3

PDF (PC)

178

Abstract:

The oppositely charged sodium alginate (Alg), chitosan (Chi), hyaluronic acid (HA) were coated onto the CaCO3 template via layer-by-layer (LBL) self-assembled technique. The template was removed by using ethylenediaminetetraacetic acid (EDTA) to obtain hollow Alg/Chi/HA microcapsules. The purpose is to prepare biosafety functional fabrics.The morphology and thermal stability of microcapsules were studied by optical microscope with a large-depth-of-field, scanning electron microscope, infrared spectroscopy and comprehensive thermal analyzer. The results show that Alg/Chi/HA microcapsules have good hollow structure and strong stability. The pH-stimuli release behavior of microcapsules were investigated. These Alg/Chi/HA microcapsules were finished in the cotton fiber to manufacture the sustained releasing textile. This work is beneficial for the development of functional fabrics.

Key words: layer-by-layer self-assembly, polysaccharide microcapsule, stimuli-responsive, controlled release, fabric modification

CLC Number: 

  • TS195.5

Fig.1

FT-IR sprectra of Alg, Chi, HA and Alg/Chi/HA microcapsules"

Fig.2

Thermal analysis of Alg/Chi/HA microcapsules. (a) TG curve; (b) DTG curve; (c) DSC curve"

Fig.3

SEM image (a) and optical microscope image with a large-depth-of filed(b) of Alg/Chi/HA microcapsules"

Fig.4

Cumulative RhB release from Alg/Chi/HA microcapsules at pH=5.8 and pH=7.4"

Fig.5

SEM images of cotton fabrics before(a) and after(b) Alg/Chi/HA/Chi microcapsules modifcation"

Tab.1

Moisture permeability of microcapsules finishing fabric"

样品
编号		 初始质量
W0/g		 0.5 h后质量
W1/g		 1 h后质量
W2/g		 透湿量/
(g·m-2·d-1)
1 251.80 252.39 253.61 7 612
2 251.56 252.11 253.27 7 237
[1] DECHER G. Fuzzy nanoassemblies: toward layered polymeric multicomposites[J]. Science, 1997,277(5330):1232-1237.
[2] 张维, 李秋瑾, 张健飞. 层层组装微胶囊的制备及其缓释性能[J]. 纺织学报, 2015,36(3):58-62.
ZHANG Wei, LI Qiujin, ZHANG Jianfei. Preparation and controlled release of microcapsules via layer-by-layer assembly[J]. Journal of Textile Research, 2015,36(3):58-62.
[3] 冯建国, 杨关天, 袁小勇, 等. 高效氯氰菊酯微胶囊的制备、表征及释放性能[J]. 高等学校化学学报, 2017,38(11):1974-1981.
FENG Jianguo, YANG Guantian, YUAN Xiaoyong, et al. Preparation, characterization and release properties of β-cypermethrin microcapsules[J]. Chemical Journal of Chinese Universties, 2017,38(11):1974-1981.
[4] 杨辉, 李通, 仝维鋆, 等. 基于碳酸钙模板的特殊形状层层组装微胶囊的制备[J]. 高等学校化学学报, 2018,39(1):172-177.
YANG Hui, LI Tong, TONG Weijun, et al. Fabrication of microcapsules with special shapes by layer-by-layer assembly on CaCO3 microparticles[J]. Chemical Journal of Chinese Universities, 2018,39(1):172-177.
[5] COOK M T, TZORTZIS G, CHARALAMPOPOULOS D, et al. Production and evaluation of dry alginate-chitosan microcapsules as an enteric delivery vehicle for probiotic bacteria[J]. Biomacromolecules, 2011,12(7):2834-2840.
pmid: 21574635
[6] DENG L, LI Q, AL-REHILI S A, et al. Hybrid iron oxide-graphene oxide-polysaccharides microcapsule: a micro-matryoshka for on-demand drug release and antitumor therapy in vivo[J]. ACS Applied Materials & Interfaces, 2016,8(11):6859-6868.
doi: 10.1021/acsami.6b00322 pmid: 26915062
[7] TAHTAT D, MAHLOUS M, BENAMER S, et al. Oral delivery of insulin from alginate/chitosan crosslinked by glutaraldehyde[J]. International Journal of Biological Macromolecules, 2013,58:160-168.
doi: 10.1016/j.ijbiomac.2013.03.064 pmid: 23567292
[8] 王亚, 黄菁菁, 张如全. 艾蒿油-壳聚糖抗菌微胶囊的制备及其应用[J]. 纺织学报, 2018,39(10):99-103.
WANG Ya, HUANG Jingjing, ZHANG Ruquan. Preparation and application of antimicrobial mug wort oil-chitosan microcapsules[J]. Journal of Textile Research, 2018,39(10):99-103.
[9] CAÑIBANO-HERNÁNDEZ A, SAENZ DEL BURGO L, ESPONA-NOGUERA A, et al. Alginate microcapsules incorporating hyaluronic acid recreate closerin vivo environment for mesenchymal stem cells[J]. Molecular Pharmaceutics, 2017,14(7):2390-2399.
doi: 10.1021/acs.molpharmaceut.7b00295 pmid: 28558467
[10] 杨晨辰. 基于透明质酸的刺激响应纳米凝胶的构建及其靶向药物传输治疗方面的应用研究[D]. 南京: 南京大学, 2016: 17-20.
YANG Chenchen. Study on the preparation of stimuli-responsive nanogels based on hyaluronic acid and its application in targeting drug delivery[D]. Nanjing: Nanjing University, 2016: 17-20.
[11] DETEMMERMAN M, DEMEESTER J, DEVOS F, et al. Encapsulation performance of layer-by-layer microcapsules for proteins[J]. Biomacromolecules, 2011,12(4):1283-1289.
doi: 10.1021/bm101559w pmid: 21375235
[1] WANG Fanghe, WANG Rui, WEI Lifei, WANG Zhaoying, ZHANG Anying, WANG Deyi. Preparation and properties of layer-by-layer self-assembled flame retardant modified polyester fabrics [J]. Journal of Textile Research, 2019, 40(11): 106-112.
[2] FAN Jingjing, WANG Hongbo, FU Jiajia, WANG Wencong. Preparation of composite conductive cotton fabric based on carbon nanotubes by layer-by-layer self-assembly [J]. Journal of Textile Research, 2019, 40(04): 90-95.
[3] . Flame retardancy properties of dopamine modified polyester/cotton blended fabric treated by electrostatic layer-by-layer self-assembly [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(09): 94-100.
[4] . Structure and properties of cotton fabric by amide modification of silk fibroin [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(02): 134-140.
[5] . Preparation and controlled release of microcapsules via Layer-by-Layer assembly [J]. Journal of Textile Research, 2015, 36(03): 58-62.
[6] . Preparation and controlled release effect of soybean protein/multicarboxylic acids modified cotton fabric [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(6): 73-78.
[7] . Structure and properties of chitosan imine modification cotton fibers  [J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(9): 35-39.
[8] ZHANG Xiaofei;YU Dengguang;ZHU Sijun;SHEN Xiaxia;Chris Branford-White;ZHU Limin. Investigation of electrospun acyclovir-loaded ultrafine fiber mats [J]. JOURNAL OF TEXTILE RESEARCH, 2009, 30(04): 1-4.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd