Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (09): 122-127.doi: 10.13475/j.fzxb.20181205906

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and application of polyacrylate/rhodamine B composite latex by miniemulsion polymerization

XIANG Wei(), YANG Honglin, QUAN Qiongying   

  1. Jianhu Institute, Zhejiang Industry Polytechnic College, Shaoxing, Zhejiang 312000, China
  • Received:2018-12-26 Revised:2019-06-18 Online:2019-09-15 Published:2019-09-23

RichHTML

1

PDF (PC)

63

Abstract:

In order to improve the stability of rhodamine B in water, polyacrylate/rhodamine B composite latex was prepared by miniemulsion polymerization and the property of polyacrylate/rhodamine B composite latex was also discussed. The particle size, Zeta potential, morphological structure and fluorescenct performance of rhodamine B solution and composite latex were tested by particle size analysis, transmission electron microscopy, X-ray diffractometry and fluorescence spectrometry, respectively. The influences of composite latex mass percent and binder mass percent on the fluorescent properties of cotton fabrics were discussed as application of polyacrylate/rhodamine B composite latex on the cotton fabrics by scraping. It is found that the average particle size and Zeta potential of polyacrylate/rhodamine B composite latex are 86.2 nm and -54.7 mV, respectively. The dispersion stability and fluorescent performance of composite latex are enhanced. The K/S values and fluorescent reflectance of cotton fabrics are higher, and the washing fastness and rubbing fastness reaches grade 4 and 3-4 under the condition of the mass percent of latex 10% and the binder mass percent of latex 20%, respectively.

Key words: miniemulsion polymerization, composite latex, fluorescence property, polyacrylate, rhodamine B

CLC Number: 

  • TS194.9

Tab.1

Average particle sizes and Zeta potential of composite latex at different weight contents of rhodamine B"

罗丹明B
质量分数/%		 平均粒径/
nm		 PDI Zeta电位值/
mV
0.4 70.3 0.053 -50.7
0.6 78.0 0.488 -45.8
0.8 85.8 0.515 -44.0
1.0 89.8 0.483 -37.2
1.2 116.5 0.588 -27.2

Fig.1

Diagrams of different structures. (a) Rhodamine B;(b)Polyacrylate/rhodamine B composite latex"

Tab.2

Average particle sizes and Zeta potential of composite latex at different contents of emulsifier"

乳化剂质量
分数/%		 平均粒径/
nm		 PDI Zeta电位值/
mV
0.4 89.8 0.483 -37.2
2.0 88.4 0.501 -45.6
4.0 87.1 0.377 -49.9
6.0 86.2 0.324 -54.7

Fig.2

TEM images of polyacrylate/rhodamine B composite latex at different magnifications"

Fig.3

XRD patterns of rhodamine B and polyacrylate/rhodamine B composite latex"

Fig.4

Fluorescence spectra of polyacrylate/rhodamine B composite latex at different contents of rhodamine B"

Tab.3

Influence of different composite latex contents on fluorescent reflectance of fabrics"

复合乳胶质量分数/% K/S值 ΔR/%
5 0.882 7 3.92
10 1.578 6 5.05
15 2.150 8 3.15
20 2.616 1 1.67
25 3.406 1 1.66

Tab.4

Influence of different binder contents on fluorescent reflectance of fabrics"

黏合剂质量分数/% K/S值 ΔR/%
5 1.598 5 5.27
10 1.532 4 5.23
20 1.578 6 5.05
30 1.467 8 5.02
[1] 项伟, 杨宏林, 邵艺, 等. 环卫职业服面料仿丝绸染整工艺[J]. 印染, 2014,40(5):23-26.
XIANG Wei, YANG Honglin, SHAO Yi, et al. Wet processing of silk-like polyester clothing for professional use[J]. China Dyeing & Finishing, 2014,40(5):23-26.
[2] 项伟, 杨宏林, 冯云. 涤纶织物分散荧光黄染色性能[J]. 印染, 2018,44(10):23-26.
XIANG Wei, YANG Honglin, FENG Yun. Dyeing properties of polyester fabrics with fluorescent yellow-dyes[J]. China Dyeing & Finishing, 2018,44(10):23-26.
[3] LI Weili, WANG Jun, XIE Yixiao, et al. Water-based fluorescent paint: presenting a novel approach to study and solve the aggregation caused quench (ACQ) effect in traditional fluorescent materials[J]. Progress in Organic Coatings, 2018,120:1-9.
doi: 10.1016/j.porgcoat.2018.03.003
[4] LI Weili, QIU Zhenyu, MIKE Tebyetekerwa, et al. Preparation of silica/polymer nanocomposites with aggregation-induced emission properties as fluorescent responsive coatings[J]. Progress in Organic Coatings, 2019,127:8-15.
doi: 10.1016/j.porgcoat.2018.11.001
[5] ZHAO Xiao, ZHOU Shuxue, CHEN Min, et al. Supramolecular architecture, spectroscopicproperties and stability of C.I. Basic Violet 10 (Rhodamine B) at high concentration[J]. Dyes and Pigment, 2009,80:212-218.
doi: 10.1016/j.dyepig.2008.07.003
[6] HUANG Yan, ZHENG Xiang, FENG Suping, et al. Enhancement of rhodamine B removal bymodifying activated carbon developed from Lythrum salicaria. with pyruvic acid[J]. Colloids and Surfaces A Physicochemical and Engeering Aspects, 2015,89:154-162.
[7] 邱振宇, 解义晓, 周黎明, 等. 基于聚集诱导发光机理的复合荧光乳胶的研究及其应用[J]. 中国涂料, 2018,33(6):60-65.
QIU Zhenyu, XIE Yixiao, ZHOU Liming, et al. Study and application of composite fluorescent latex based on aggregation induced emission[J]. China Coatings, 2018,33(6):60-65.
[8] 沈文军, 王绍明, 徐杰, 等. 环氧改性丙烯酸树脂复合乳胶的合成及其性能研究[J]. 涂料工业, 2017,47(2):33-39.
SHEN Wenjun, WANG Shaoming, XU Jie, et al. Preparation and properties of hybrid latex based on epoxy:modified acrylate resin[J]. Paint & Coating Industry, 2017,47(2):33-39.
[9] 陈智杰, 吴明华, 史鹤鹤, 等. 涂料印染用自黏性有机颜料亚微胶囊的细乳液法制备[J]. 纺织学报, 2017,38(3):91-98.
CHEN Zhijie, WU Minghua, SHI Hehe, et al. Preparation of self-adhesive submicron organic pigment-containing capsules by miniemulsion polymerization for paint coloring[J]. Journal of Textile Research, 2017,38(3):91-98.
[10] 戚栋明, 徐杰, 陈智杰, 等. 聚丙烯酸酯/铜酞菁蓝复合乳胶膜中颜料颗粒的分散状态[J]. 化工学报, 2013,64(5):1876-1883.
QI Dongming, XU Jie. CHEN Zhijie, et al. Dispersion of pigment particles in polyacrylate latex film containing phthalocyanine blue[J]. CIESC Journal, 2013,64(5):1876-1883
[11] 张东阳, 朱东, 王木立, 等. 水性涂料用丙烯酸酯乳液的研究进展[J]. 中国涂料, 2011, 26(9):14-17.
ZHANG Dongyang, ZHU Dong, WANG Muli, et al. Progress of acrylate emulsionfor water-borne coatings[J]. China Coatings, 2011,26(9):14-17.
[12] 陶佳, 钟毅, 张琳萍, 等. 互穿结构涂料印花粘合剂的合成与应用[J]. 涂料工业, 2014,44(12):6-11.
TAO Jia, ZHONG Yi, ZHANG Linping, et al. Synjournal and application of printing binder with interpenetrating polymer networks[J]. Paint & Coating Industry, 2014,44(12):6-11.
[13] 黄宏志, 沈玲, 熊娉婷, 等. 可聚合乳化剂对丙烯酸乳液性能的影响[J]. 涂料工业, 2006,36(12):28-30.
HUANG Hongzhi, SHEN Ling, XIONG Pingting, et al. The influence of polymerizable emulsifier on performance of acrylic emulsion[J]. Paint & Coating Industry, 2006,36(12):28-30.
[14] 张奇鹏, 蒋少军, 盛冠忠, 等. 有机硅改性丙烯酸酯细乳液的合成及其涂料印花性能研究[J]. 涂料工业, 2018,48(6):12-16.
ZHANG Qipeng, JIANG Shaojun, SHENG Guanzhong, et al. Preparation of polysiloxane modified miniemulsion andits performance of pigment printing[J]. Paint & Coating Industry, 2018,48(6):12-16.
[15] KOZAKIEWICZ J, OFAT I, TRZASKOWSKA J. Silicone containing aqueous polymer dispersions with hybrid particlestructure[J]. Advances in Colloid & Interface Science, 2015,223:1-39.
doi: 10.1016/j.cis.2015.04.002 pmid: 26094081
[16] 刘杰, 杜长森, 张丽平, 等. 阳离子化棉织物的纳米乳胶荧光颜料染色[J]. 纺织学报, 2016,37(10):56-61.
LIU Jie, DU Changsen, ZHANG Liping, et al. Dyeing process of nanoscale latex fluorescent pigment on cationic cotton fabrics[J]. Jouranl of Textile Research, 2016,37(10):56-61.
[17] EL-MOLLA M M. Synjournal of polyurethane acrylate oligomers as aqueous UV-curable binder for inks of ink jet in textile printing and pigment dyeing[J]. Dyes and Pigments, 2007,749(2):371-379.
[18] 胡靓, 汪澜, 林俊雄. 荧光腈纶纱线的荧光性能[J]. 纺织学报, 2009,30(5):68-72,87.
HU Liang, WANG Lan, LIN Junxiong. Fluorescent property of fluorescent acrylic yarn[J]. Jouranl of Ttextile Research, 2009,30(5):68-72,87.
[19] 王红波, 罗敏亚, 李亚萍, 等. 活性荧光黄FL的染色性能[J]. 印染, 2013,39(13):36-38.
WANG Hongbo, LUO Minya, LI Yaping, et al. Dyeing behaviors of reactive fluorescent yellow FL[J]. China Dyeing & Finishing, 2013,39(13):36-38.
[20] 姜太良, 田素珍, 孙丕喜. 不同环境因子对罗丹明B影响的试验[J]. 黄渤海海洋, 1985,3(4):79-83.
JIANG Tailiang, TIAN Suzhen, SUN Pixi. The experiment of various enviroment factors effect on rhodamine B[J]. Journal of Oceanography Huanghai & Bohai Seas, 1985,3(4):79-83.
[21] LI Hang, WEI Shiqiang, QING Changle, et al. Discussion on the position of the shear plane[J]. Journal of Colloid and Intersurface Science, 2003,58:40-44.
[22] KAMAL Shakir, AHMED Faouzy Elkafrawy, HUSSEIN Fouad Ghoneimy, et al. Removal of rhodamine B (a basic dye) and thoron (an acidic dye) from dilute aqueous solutions and wastewater simulants by ion flotation[J]. Water Research, 2010,44:1449-1461.
pmid: 19942250
[23] KUO Shenglung, CHEN Yanncheng, GER Mingder, et al. Nano-particles dispersion effect on Ni/Al2O3 composite coatings[J]. Materials Chemistry and Physics, 2004,86:5-10.
doi: 10.1016/j.matchemphys.2003.11.040
[24] 沈志平, 季媛. 染整技术:染色分册[M]. 北京: 中国纺织出版社, 2014: 40-41.
SHEN Zhiping, JI Yuan. Dyeing and Finishing Techni-ques: Dyeing Fascicles[M]. Beijing: China Textile & Apparel Press, 2014: 40-41.
[25] WILFRED Smulders, MACHAEL J Monteiro. Seeded emulsion polymerization of block copolymer core-shell nanoparticles with controlled particle size and molecular weight distribution using xanthate-based RAFT polymerization[J]. Macromolecules, 2004,37(12):4474-4483.
doi: 10.1021/ma049496l
[1] ZHU Qing, XU Dandan, PAN Yuange, WANG Chenglong, ZHENG Jinhuan. Influence of waterborne polyacrylate on printing effect of coated label fabrics [J]. Journal of Textile Research, 2020, 41(08): 55-62.
[2] . De-curling control of single-weft knitted fabric in open width pad-steam dyeing [J]. Journal of Textile Research, 2019, 40(05): 91-96.
[3] WANG Fengbo, WANG Jiayi, SUN Zheng, MA Yanxue, LÜ Yingzhi, ZHANG Weifeng, LÜ Yan, LÜ Mingming, CHEN Siyu, LI Yuling, CHEN Xiaoguang. Pilot study on treatment of polyacrylate sizing wastewater [J]. Journal of Textile Research, 2019, 40(01): 108-113.
[4] . Synthesis and properties of hydrophilic antistatic polyester masterbatch by melt blending [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(07): 6-10.
[5] . Synthesis and application performance of polyacrylate modified silica sol [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(05): 86-92.
[6] . Synthesis and properties of waterborne polyacrylate coating dyeing binder [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(04): 90-96.
[7] . Preparation of self-adhesive submicron organic pigment-containing capsules by miniemulsion polymerization for paint coloring [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(03): 91-98.
[8] . Dyeing process of nanoscale latex fluorescent pigment on cationic cotton fabrics [J]. JOURNAL OF TEXTILE RESEARCH, 2016, 37(10): 56-61.
[9] . Water resistance of β-cyclodextrin/polyacrylate nanofiber films and their supramolecular capturing performance for heavy metal ions [J]. JOURNAL OF TEXTILE RESEARCH, 2016, 37(09): 1-5.
[10] . Research of polyacrylate/nano-ZnO composite emulsion and its application on textile pigment printing [J]. JOURNAL OF TEXTILE RESEARCH, 2015, 36(08): 78-83.
[11] . Removal of polyacrylate size from PET fabric by combination of plasma and wet desizing [J]. JOURNAL OF TEXTILE RESEARCH, 2014, 35(1): 78-0.
[12] . Development of fabric-based carbon PTC functional materials [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(2): 136-140.
[13] . Synthesis and performance of polyacrylate latex modified with double terminated acryloyloxy-propyl polysiloxane [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(12): 90-0.
[14] ZHAO Xiao, SHA Ying, AN Ni, LIANG Lie-Feng. Preparation of functionalized nanocapsule and nanocolorants via miniemulsion technology [J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(7): 69-74.
[15] LIN Jian-Yuan, LUO Lin-Feng, CHEN Liang, YU Hong-Zhe. Synthesis,characterization and antibacterial activity of rare earth lanthanum- rutin complex [J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(5): 81-85.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd