Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (03): 78-83.doi: 10.13475/j.fzxb.20190800606

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Influence of extreme hydrophobic dye structure on dyeing properties of ultrahigh molecular weight polyethylene fibers

WANG Xiaochun1(), ZHANG Jianfei1, ZHANG Liping2, WANG Nana2, YAN Jinlong2, ZHAO Guoliang2   

  1. 1. School of Textiles Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Materials Design and Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China
  • Received:2019-08-02 Revised:2019-12-16 Online:2020-03-15 Published:2020-03-27

RichHTML

5

PDF (PC)

90

Abstract:

In order to solve the dyeing problem of ultrahigh molecular weight polyethylene (UHMWPE) fibers, the dyes with extreme hydrophobicity and good planarity were selected. The influence of dye structure on dyeing properties of UHMWPE fibers was studied by the determination of the K/S value of dyed fibers and the thermodynamic parameters such as the affinity, the partition coefficient, enthalpy change and entropy change between dyes and fibers. The number and chain length of hydrophobic groups, the polar groups such as nitro group and solubility parameter of hydrophobic dyes were analyzed. The results show that extreme hydrophobic dyes have satisfactory color depth on UHMWPE fibers. The hydrophobicity and solubility parameter of dyes are important factors affecting the dyeing properties of UHMWPE fiber. Azo-structured dyes are easier to obtain better dyeing performance for UHMWPE fiber than anthraquinone-structured dyes.

Key words: ultrahigh molecular weight polyethylene fiber, extreme hydrophobic dye, dyeing thermodynamics, adsorption isotherm

CLC Number: 

  • TQ624

Fig.1

Dyeing process curve"

Tab.1

K/S value and color fastness to rubbing of UHMWPE fiber"

染料 K/S值 耐摩擦牢度/级
干 湿
乙基黄 11.6 4~5 4~5
苏丹蓝Ⅱ 4.0 3 3~4
油红O 13.7 3 3~4
分散红1 0.7 2~3 3
分散蓝291 0.9 2 2~3
分散橙25 0.4 2~3 2~3

Fig.2

Adsorption isotherm of UHMWPE fiber"

Fig.3

Structure of dyes. (a)Ethyl yellow; (b)Sudan yellowⅠ; (c)Sudan red G;(d)Sudan red Ⅲ; (e)Sudan red Ⅳ;(f)Sudan red B;(g)Oil Red O;(h)Anthraquinone blue;(i)Sudan blue Ⅱ;(j)Disperse orange 25"

Tab.2

Effect of dye structure on standard affinity"

序号 染料 K/S值 分配
系数K		 -Δμ0/
(kJ·mol-1)		 偶极矩/
D		 摩尔体积/
(cm3·mol-1)
1 乙基黄 11.6 5.35 -5.55 4.124 7 179.935
2 苏丹黄Ⅰ 4.8 9.56 -7.47 2.013 1 168.467
3 苏丹红G 3.4 6.22 -6.05 2.276 6 205.009
4 苏丹红Ⅲ 3.1 16.35 -9.25 2.498 9 278.365
5 苏丹红Ⅳ 5.3 17.73 -9.51 3.112 6 243.503
6 苏丹红B 10.2 29.26 -11.17 1.824 3 264.291
7 油红O 13.7 107.50 -15.48 2.920 2 290.521
8 蒽醌蓝 0.9 2.16 -2.55 3.039 7 184.899
9 苏丹蓝Ⅱ 4.0 22.46 -10.30 3.163 6 304.766
10 分散橙25 0.4 0.93 -0.25 8.523 5 260.539

Tab.3

Enthalpy and entropy changes of UHMWPE fiber"

染料 分配系数K -Δμ0/(kJ·mol-1) 染色热
ΔH0/(kJ·mol-1)		 染色熵ΔS0/(kJ·mol-1·K-1)
100 ℃ 125 ℃ 100 ℃ 125 ℃ 100 ℃ 125 ℃
乙基黄 3.55 5.35 -4.19 -5.55 -27.10 -0.09 -0.08
蒽醌蓝 0.62 2.16 -1.56 -2.55 -34.36 -0.10 -0.09
苏丹蓝Ⅱ 10.17 22.46 -7.68 -10.30 -87.61 -0.26 -0.25
苏丹红Ⅲ 9.32 16.35 -7.39 -9.25 -60.15 -0.19 -0.17
苏丹红Ⅳ 9.64 17.13 -7.50 -9.51 -65.57 -0.20 -0.19
苏丹红B 8.28 29.26 -6.99 -11.17 -144.64 -0.42 -0.39
油红O 28.24 107.50 -11.05 -15.48 -149.49 -0.44 -0.41

Tab.4

Solubility parameter and K/S value of dyes"

序号 染料 溶解度参数 K/S值
1 乙基黄 8.24 11.6
2 苏丹黄 8.57 4.8
3 苏丹红Ⅲ 8.43 3.1
4 苏丹红Ⅳ 8.52 5.3
5 苏丹红B 8.51 10.2
6 油红O 8.54 13.7
7 蒽醌蓝 9.94 0.9
8 苏丹蓝Ⅱ 9.43 4.0
9 分散红1 9.76 0.7
10 分散蓝291 10.89 0.9
11 分散橙25 9.88 0.4
[1] 王晓春, 闫金龙, 张丽平, 等. 超高分子质量聚乙烯纤维分散染料染色性能[J]. 纺织学报, 2017,38(11):85-90.
WANG Xiaochun, YAN Jinlong, ZHANG Liping, et al. Dyeing properties of ultrahigh molecular weight polyethylene fibers with disperse dye[J]. Journal of Textile Research, 2017,38(11):85-90.
[2] 王晓春, 张健飞, 刘铭, 等. 熔纺 UHMWPE/聚烯烃纤维的原液着色[J]. 北京服装学院学报, 2019,39(1):28-32.
WANG Xiaochun, ZHANG Jianfei, LIU Ming, et al. Study on dope dyeing of UHMWPE /Polyolefin fiber by melt spinning[J]. Journal of Beijing Institute of Clothing Technology, 2019,39(1):28-32.
[3] 闫金龙, 张丽平, 王晓春, 等. 超高分子量聚乙烯纤维染色研究进展[J]. 纺织导报, 2016(6):84-86.
YAN Jinlong, ZHANG Liping, WANG Xiaochun, et al. Research progress in dyeing process of UHMWPE fiber[J]. China Textile Leader, 2016(6):84-86.
[4] 杭州翔盛高强纤维材料股份有限公司. 一种超高分子量聚乙烯纤维有机颜料分散锚固原液着色方法:ZL103572397A[P]. 2014-01-12.
Hangzhou Xiangsheng High Strength Fiber Materials Co., Ltd. Organic pigment dispersing and anchoring dope dyeing method for ultra-high molecular weight polyethylene fiber: ZL103572397A[P]. 2014-01-12.
[5] 浙江金昊特种纤维有限公司. 超高分子量聚乙烯有色细旦纤维的生产方法: ZL101718003A[P]. 2010-06-02.
Zhejiang Jinhao Special Fiber Co., Ltd. Method for producing ultra-high molecular weight polyethylene colored fine denier fiber: ZL101718003A[P]. 2010-06-02.
[6] 顾群, 王宗宝, 王剑, 等. 一种超高分子量聚乙烯有色纤维的制备方法:ZL103866416A[P]. 2016-04-18.
GU Qun, WANG Zongbao, WANG Jian, et al. Preparation method for ultra-high molecular weight polyethylene colored fibers: ZL103866416A[P]. 2014-06-18.
[7] 绍兴金渔纺织新技术有限公司. 有色超高分子量聚乙烯纤维的制备方法: ZL103046403A[P]. 2013-04-17.
Shaoxing Jinyu Textile New Technology Co., Ltd. Method for preparing colored UHMW (ultra-high molecular weight) polyethylene fibers: ZL103046403A[P]. 2013-04-17.
[8] 杭州祥盛高强纤维材料股份有限公司. 一种超高分子量聚乙烯纤维染色装置及其方法:ZL102953186A[P]. 2013-03-06.
Hangzhou Xiangsheng High Strength Fiber Material Co., Ltd. Ultra high molecular weight polyethylene fiber dyeing device and method: ZL102953186A[P]. 2013-03-06.
[9] 北京同益中特种纤维技术开发有限公司, 中纺投资发展股份有限公司. 一种超高分子量聚乙烯纤维的染色方法: ZL103711007A[P]. 2014-04-09.
Beijing Tongyizhong Specialty Fiber Technology Dev.Co., Ltd,Sinotex Invest & Dev Co., Ltd. Dyeing method for ultrahigh molecular weight polyethylene fibers: ZL103711007A[P]. 2014-04-09.
[10] KIM Taekyeong, JEON Seonhee. Coloration of ultrahigh molecular weight polyethylene fibers using alkyl-substituted monoazo yellow and red dyes[J]. Fibers and Polymers, 2013,14(1):105-109.
[11] BAE Jinseok, KIM Taekyeong, LEE Changwhan. Synjournal of novel violet dyes for polyolefin fibers using N,N-dihexyl-2-methoxy-5-methylaniline and various diazo components[J]. Fibers and Polymers, 2014,15(12):248-253.
[12] MARYAM Ataeefard, MAJID Mohseni, SIAMAK Moradian. Polypropylene/clay nanacomposite: kinetic and nanacomposite: kinetic and thermodynamic of dyeing with various disperse dyes[J]. Journal of The Textile Institute, 2016,107(2):182-190.
[13] 陈荣圻. 溶解度参数在分散染料拼混染色中的应用[J]. 染整技术, 2018,40(10):1-5.
CHEN Rongqi. Applications of solubility parameter in combination dyeing of disperse dye (continued one)[J]. Textile Dyeing and Finishing Journal, 2018,40(10):1-5.
[14] 陈荣圻. 溶解度参数在聚酯类纤维分散染色中的应用:二[J]. 印染, 2013(6):49-54.
CHEN Rongqi. Application of solubility parameter to disperse dyeing of polyester fibers:Ⅱ[J]. China Dyeing & Finishing, 2013(6):49-54.
[15] 刘思俊. 超高分子量聚乙烯相分离及微孔膜制备的研究[D]. 上海:上海交通大学, 2013: 30.
LIU Sijun. Study on phase separation and membrane preparation of ultra-high molecular weight poly-ethylene[D]. Shanghai:Shanghai Jiaotong University, 2013: 30.
[1] ZHAN Xiaoqing, LI Fengyan, ZHAO Jian, LI Haiqiong. Thermal mechanical stability of ultrahigh molecular weight polyethylene fiber#br# [J]. Journal of Textile Research, 2020, 41(08): 9-14.
[2] . Coupling modification and process regulation of tyrosine residues on silk fibroin [J]. Journal of Textile Research, 2018, 39(09): 102-108.
[3] . Adsorption of modified waste cotton to Cu+2 in aqueous solution [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(12): 112-118.
[4] . Dyeing peoperties of ultrahigh molecular weight polyethylene fibers with disperse dye [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(11): 84-90.
[5] . Simple quantitative detection of cationic degree on cotton fiber [J]. Journal of Textile Research, 2016, 37(4): 75-79.
[6] . Dyeing thermodynamics of acrylic acid photografted linen fabric with cationic dyes [J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(12): 49-52.
[7] . Study on Adsorption Kinetic of Octylphenol ethoxylates onto Silk fiber [J]. JOURNAL OF TEXTILE RESEARCH, 2011, 32(9): 64-68.
[8] . Mechanism of Benzyl Alcohol on Acrylic Fiber Dyeing with Cationic Dye [J]. JOURNAL OF TEXTILE RESEARCH, 2011, 32(5): 80-85.
[9] DING Feifei;WANG Lan;LIN Junxiong. Dyeing mechanism of disperse dye on bi-component sheath-core fiber with low melting point [J]. JOURNAL OF TEXTILE RESEARCH, 2011, 32(1): 67-72.
[10] XIANG Wei ;CAI Zaisheng . Clean dyeing of silk fabrics with acid dyes [J]. JOURNAL OF TEXTILE RESEARCH, 2010, 31(11): 77-82.
[11] ZHANG Feng;CHEN Yuyue;ZHANG Desuo;HUA Yanrong;ZHAO Bing. Mechanism of salt-free dyeing of HBP—NH_2 grafted oxidized cotton fabrics [J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(11): 71-75.
[12] JIANG Sheng. Properties of plasma treated UHMWPE/LDPE composites [J]. JOURNAL OF TEXTILE RESEARCH, 2007, 28(9): 57-60.
[13] JIANG Sheng;YAN Xiong;CAI Yong-dong. Improvement of ultrahigh molecular weight polyethylene fibers′ interface property by atmospheric argon plasma [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(11): 36-38.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd