Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (11): 81-88.doi: 10.13475/j.fzxb.20200101308

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of anthraquinone additive on properties of glycol solvent degummed ramie fibers

QU Yongshuai1,2, SHI Zhaohe1,2, ZHANG Ruiyun1,2,3(), ZHAO Shuyuan1,2, LIU Liu3   

  1. 1. College of Textiles, Donghua University, Shanghai 201620, China
    2. Key Laboratory of Textile Science & Technology,Ministry of Education, Donghua University, Shanghai 201620, China
    3. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
  • Received:2020-01-08 Revised:2020-03-10 Online:2020-11-15 Published:2020-11-26
  • Contact: ZHANG Ruiyun E-mail:ryzhang@dhu.edu.cn

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Abstract:

In order to solve the problem of property degradation of ramie fiber due to easy oxidation during degumming process using glycol organic solvent, anthraquinone (AQ) as degumming additive was used with glycol solvent. The properties of fibers prepared with different amounts of AQ were characterized, including polymerization degree, crystallinity, hemicellulose contents, physical and mechanical properties, and so on. The results show that the hemicellulose contents increase when AQ concentration arises. Meanwhile, the polymerization degree value, crystallinity, physical and mechanical properties of fiber show formation of peaks with the increase of AQ content. Under the best AQ mass fraction of 0.3%, the polymerization degree value, crystallinity, yield, tenacity, elongation and fracture work of fiber increase by 7.32%, 20.53%, 1.46%, 9.55%, 6.89%, 33.33%, respectively, while the residual gum content and density of fiber decrease by 17.91%, 7.24%, respectively.

Key words: ramie, glycol, anthraquinone, degumming, cellulose, hemicellulose, lignin

CLC Number: 

  • S563.1

Fig.1

Oxidation of hydroxyl group in glucose ring"

Fig.2

Peeling reaction of cellulose"

Fig.3

Stopping reaction of cellulose"

Fig.4

Reaction among anthraquinone,carbohydrates and lignin"

Tab.1

Chemical composition and yield of ramie fiber treated with and without anthraquinone%"

类型 纤维素 半纤维素 木质素 其他 制成率
未加蒽醌 95.98 2.28 0.42 1.32 74.2
添加蒽醌 96.70 2.69 0.33 0.28 75.3

Fig.5

Effect of AQ mass fraction on hemicellulose contents and DP value of fiber"

Fig.6

Effect of AQ mass fraction on density and residual gum content of fibers"

Fig.7

Effect of AQ mass fraction on X-ray diffraction curves of fibers"

Fig.8

Effect of AQ mass fraction on fiber crystallinity"

Fig.9

Effect of AQ mass fraction on physical and mechanical properties of fibers"

Fig.10

FT-IR pattern of raw ramie and ramie fibers with different treatments"

Fig.11

Effect of AQ on degumming rate"

Tab.2

Effect of AQ on fiber properties in different stages of degumming"

阶段 蒽醌质量分数/% 残胶率/% 制成率/% 半纤维素含量/% 线密度/dtex 断裂强度/(cN·dtex-1) 断裂伸长率/%
升温阶段 0 7.82 77.34 4.53 7.23 6.27 2.01
(0~60 min) 0.3 6.23 75.93 3.96 6.99 6.02 2.32
保温阶段 0 4.02 74.20 2.28 6.88 6.44 2.71
(60~120 min) 0.3 3.30 75.10 2.76 6.39 7.12 2.92
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