Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (12): 102-110.doi: 10.13475/j.fzxb.20200306909

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Fabrication of photocatalytic floating spheres for degradation of methyl-orange under illumination of visible light

SONG Yingqi, PAN Jiahao, WU Liguang, WANG Ting(), DONG Chunying   

  1. School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou, Zhejiang 310012, China
  • Received:2020-03-25 Revised:2020-08-03 Online:2020-12-15 Published:2020-12-23
  • Contact: WANG Ting E-mail:zjwtwaiting@hotmail.com

Abstract:

In order to extend the application of heterogeneous photocatalytic technology in deep level treatment for special wastewater, a visible light-driven photocatalytic component deposited by visible light with high performance was prepared via adsorbed-layer nanoreactor synthesis coupling with thermal reduction treatment. Followed that, the porous polyurethane sponge particle was firstly employed as a carrier to load the photocatalytic component, and the supported polyurethane sponge was filled into a polypropylene hollow sphere to fabricate a floating photocatalytic sphere for photodegrading methyl-orange in high saline waste water. The results show that noble metal nanoparticles with small size could be deposited on the surface of TiO2 closely combined with TiO2 by adsorbed-layer nanoreactor synthesis. Due to the introduction of the Fermi level and the plasmon resonance effect into the photocatalytic components, the degradation performance for methyl orange is enhanced in highly saline wastewater illuminated by visible light. Because of loading by noble metal deposition photocatalytic components with high performance, the resulting floating photocatalytic spheres could also stably and efficiently degrade methyl orange in highly saline wastewater.

Key words: adsorbed-layer nanoreactor synthesis, noble metal deposition, photocatalysis irradiated by visible light, floating photocatalytic sphere, high saline wastewater, wastewater treatment

CLC Number: 

  • O647

Tab.1

Addition contents of reactants of photocatalytic componentsmg"

催化剂
名称
反应物 NaOH加入量
名称 加入量
Ag-P25 硝酸银 36.52 8.70
Au-P25 氯金酸 21.27 21.27
Pt-P25 氯铂酸 32.41 32.41

Fig.1

Polyurethane sponge particles before (a) and after (b) loading photocatalytic components andresulting filled floating spheres (c)"

Fig.2

Fabrication scheme of floating spheres filled with polyurethane sponge particles loading photocatalytic components"

Fig.3

Photo-degradation for methyl orange and corres-ponding degradation curve in highly saline wastewater by filled floating spheres. (a) Photodegradation process by floating photocatalytic spheres;(b) Top view of photodegradation process by floating photocatalytic spheres; (c) Photodegradation curves for methyl-orange by floating photocatalytic spheres"

Fig.4

TEM images of different photocatalytic components. (a) Modified P25; (b) Ag-P25; (c) AU-P25; (d) Pt-P25"

Fig.5

FT-IR spectra of different photocatalytic components"

Fig.6

XRD patterns of different photocatalytic components"

Fig.7

XPS profiles of Ag3d (a) and Ti2p (b) in Ag-P25"

Fig.8

XPS profiles of Au4f (a) and Ti2p (b) in Au-P25"

Fig.9

XPS profiles of Pt4f (a) and Ti2p (b) in Pt-P25"

Fig.10

UV-vis diffuse reflectance spectra of different photocatalytic components"

Fig.11

PL spectra of different photocatalytic components"

Fig.12

Photodegradation for methyl-orange in highly saline wastewater by different photocatalytic components"

Fig.13

Photodegradation for methyl-orange in different saline wastewater by Pt-P25"

Fig.14

Photodegradation for methyl-orange in saline wastewater by floating photocatalytic sphere loaded with different Pt-P25 contents. (a)Degradation curves by floating photocatalytic spheres loaded with different Pt-P25 contents;(b)Photodegradation for methyl-orange in saline wastewater for three cycles"

Fig.15

Powders obtained by centrifuging supernatant after a porous polyurethane sponge"

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