Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 106-111.doi: 10.13475/j.fzxb.20210704006

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and photocatalytic properties of cotton fabrics loaded with polymetallic organic framework material

ZHENG Linjuan1, YU Jia1, YIN Chong2, LIANG Zhijie1, MAO Qinghui1()   

  1. 1. School of Textile and Clothing, Nantong University, Nantong, Jiangsu 226019, China
    2. Nantong Hymo Industrial Co., Ltd., Nantong, Jiangsu 226000, China
  • Received:2021-07-14 Revised:2022-04-21 Online:2022-10-15 Published:2022-10-28
  • Contact: MAO Qinghui E-mail:1731mqh@ntu.edu.cn

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Abstract:

To prepare cotton fabrics with photocatalytic properties, the in-situ growth of polyacids on cotton fabrics was achieved by introducing metal organic framework materials into which polymetallic oxides of suitable dimensions were loaded. The effects of metal ion reaction time, amount of polymetallic acid, organic ligand and reaction time of polymetallic acid on the photocatalytic performance of the prepared cotton fabrics loaded with polymetallic organic framework material (POMOF) were investigated, and the morphology and structure of cotton fabrics loaded with POMOF were characterized with the aid of scanning electron microscopy and FT-IR spectrometry. The results show that the carboxylation modification of cotton fabrics is able to form multiple active sites on its surface, and the degradation rate of cotton fabrics loaded with POMOF to Rhodamine B solution (10 mg/L) reached 92.23% in 135 min when the modified cotton fabric was reacted in copper nitrate solution for 12 h, the amount ratio of homophthalic acid to polytungstate was 1∶4, and the reaction time of organic ligand and polyacid was 10 h. This cotton fabric loaded with POMOF demonstrated good photocatalytic performance and has great potential in the degradation of printing and dyeing wastewater.

Key words: polytungstate, metal-organic frame, Rhodamine B, photocatalytic degradation, wastewater treatment, printing and dyeing wastewater

CLC Number: 

  • TS195.5

Fig.1

SEM images of cotton fabric before and after carboxylation. (a) Unmodified;(b) Carboxyl modified"

Fig.2

Content of copper ions on cotton fabric at different reaction time"

Fig.3

In situ growth mechanism of POMOF on cotton fabric"

Tab.1

Effect of polyoxometalate dosage on photocatalytic degradation rate of Rhodamine B"

有机配体与多
钨酸盐的量比		 降解
率/%		 有机配体与多
钨酸盐的量比		 降解
率/%
1∶10 78.07 1∶14 92.23
1∶11 77.64 1∶15 92.96
1∶12 82.51 1∶16 93.12
1∶13 84.63 1∶17 93.37

Fig.4

Effect of reaction time between polytungstate and phthalic acid on photocatalytic degradation rate of Rhodamine B"

Fig.5

SEM images of pure cotton fabric(a) and cotton fabric loaded with POMOF(b)"

Tab.2

Relative element content of POMOF based cotton fabric%"

元素 质量分数 原子分数
C 57.2 0.2
O 26.7 0.2
Cu 9.0 0.1
W 7.1 0.3
P 0.0 0.2

Fig.6

Infrared spectra comparison of pure cotton fabric,modified cotton fabric and cotton fabric loaded with POMOF"

Fig.7

Influence of illumination time on Rhodamine B degradation rate"

Fig.8

SEM images of cotton fabric loaded with POMOF before (a)and after (b)photocatalysis"

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