Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (01): 147-152.doi: 10.13475/j.fzxb.20210907106

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of dyeing promoter on dyeing kinetics and thermodynamics of polybutylene succinate fiber dyeing with disperse dye

WANG Chenglong1,2, LI Lixin2,3, WU Shaoming2, CHAI Liqin1,2, ZHOU Lan1,2()   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Engineering Research Center of Ecological Dyeing and Finishing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018,China
    3. Hangzhou Xinsheng Printing & Dyeing Co., Ltd., Hangzhou, Zhejiang 311200, China
  • Received:2021-09-22 Revised:2021-11-08 Online:2022-01-15 Published:2022-01-28
  • Contact: ZHOU Lan E-mail:lan_zhou330@163.com

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Abstract:

In order to develop polybutylene succinate (PBS) fiber disperse dye low-temperature dyeing technology, the role of dyeing promoters in the dyeing process was studied. Diethyl succinate was used to prepare dyeing promoter for the dyeing of PBS fiber with disperse dye. C.I. Disperse Red 60 was used to dye PBS fiber, the influence of dyeing promoter on the dyeing kinetics and thermodynamics of PBS fiber was studied, and dyeing mechanism of PBS fiber was investigated. The result showed that the dyeing kinetic equation of C.I. Disperse Red 60 on PBS fiber was in accordance with the quasi second order kinetic equation. Compared to dye without dyeing promoter, with the condition of dyeing at 70 ℃ with dye promoter, the equilibrium adsorption capacity of C.I. Disperse Red 60 on PBS fibers was increased, and the dyeing rate significantly was faster, the half-staining time was shortened, and the diffusion coefficient was also significantly increased. The addition of dyeing promoter played a certain role in promoting the dyeing of PBS fibers with disperse dyes. With or without dyeing accelerators, the dyeing of C.I. Disperse Red 60 on PBS fiber conformed to the Nernst type adsorption isotherm.

Key words: polybutylene succinate fiber, disperse dye, dyeing promoter, dyeing kinetics, dyeing thermodynamics

CLC Number: 

  • TS193.1

Fig.1

Dyeing rate curve for dyeing of PBS fiber with C.I. Disperse Red 60"

Fig.2

Fitting of quasi-first-order kinetic equation of C.I. Disperse Red 60 adsorption on PBS fiber"

Tab.1

Quasi-first-order kinetic parameters of C.I. Disperse Red 60 dyeing on PBS fiber"

有无染色
促进剂		 准一级动力学参数
C∞,exp/(mg·g-1) C∞,cal/(mg·g-1) k1/min-1
无 8.08 2.32 2.73×10-2
有 19.16 8.35 1.00×10-1

Fig.3

Fitting of quasi-second-order kinetic equation of C.I. Disperse Red 60 adsorption on PBS fiber"

Tab.2

Quasi-second-order kinetic parameters of C.I. Disperse Red 60 dyeing on PBS fiber"

有无染色
促进剂		 准二级动力学参数
C∞,exp/(mg·g-1) C∞,cal/(mg·g-1) k2/min-1
无 8.08 10.42 2.97×10-3
有 19.16 19.24 3.00×10-1

Tab.3

Dyeing kinetic parameters of C.I. Disperse Red 60 with different dyeing conditions"

有无染色促进剂 半染时间 t1/2/min 扩散系数D/
(10-15m2·min-1)
无 20.82 1.221
有 5.70 18.184

Fig.4

Adsorption isotherm of C.I. Disperse Red 60 on PBS fiber"

Fig.5

Nernst-type fitting curve of adsorption of C.I. Disperse Red 60 to PBS fiber"

Tab.4

Nernst-type fitting parameters of adsorption of C.I. Disperse Red 60 to PBS fiber"

染色温
度/℃		 有无染色
促进剂		 Kn/
(L·g-1)		 拟合公式 拟合
系数R2
70 无 0.444 9 y=0.444 9x+3.882 8 0.991 2
有 1.338 8 y=1.338 8x+4.263 5 0.994 9
90 无 1.476 5 y=1.476 5x+3.729 5 0.998 2
有 1.770 8 y=1.770 8x+4.458 5 0.997 3
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