Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (12): 125-130.doi: 10.13475/j.fzxb.20211107106

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Rapid determination of quinoline in textiles

YIN Zhe1,2, ZHAO Hailang2(), XU Hong1, MAO Zhiping1, TAN Yujing2   

  1. 1. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. Shanghai Institute of Quality Inspection and Technical Research, Shanghai 200040, China
  • Received:2021-11-16 Revised:2022-09-14 Online:2022-12-15 Published:2023-01-06
  • Contact: ZHAO Hailang E-mail:zhaohl@sqi.org.cn

RichHTML

5

PDF (PC)

122

Abstract:

In order to reduce the extraction time from small amount of organic reagent, a rapid analytical method for the determination of quinoline in textiles by pyrolysis/thermal desorption-gas chromatography-mass spectrometry(Py/TD-GC-MS) was established. This method requires no sample processing, and the quinoline is thermally desorbed directly in the pyrolysis/thermal desorption device before entering the GC-MS for qualitative and quantitative determination. To solve the problem of quinoline volatilization before and during the analysis process, polyvinyl chloride(PVC) was added as the adsorbent of quinoline to improve the accuracy of quinoline standard solution analysis. The thermal desorption temperature was 240 ℃, the thermal desorption time was 6 s, the heating rate was 50 ℃/min and the interface temperature was 300 ℃. The results show that the linear range of the method was 10-1 000 mg/kg, the correlation coefficient was 0.994, the limit of detection was 3.520 mg/kg, the limit of quantification was 11.760 mg/kg, the spiked recoveries were 90.02%-102.07%, and the relative standard deviation was 1.27%-4.53%. All these suggest that this method is suitable for rapid determination of quinoline in textiles.

Key words: textile, quinoline, adsorbent, thermal desorption-gas chromatography-mass spectrometry, rapid determination method, polyvinyl chloride

CLC Number: 

  • O657.63

Fig.1

Effect of waiting time on response intensity of quinoline mass spectrometry"

Fig.2

Effect of PVC solution concentration on response strength of quinoline mass spectrometry"

Fig.3

EGA-MS selective ion diagrams of PVC solution and quinoline standard solution B"

Fig.4

Influence of pyrolysis temperature on response intensity of quinoline mass spectrometry"

Fig.5

Effect of pyrolysis time on response intensity of quinoline mass spectrometry"

Fig.6

Effect of heating rate on response intensity of quinoline mass spectrometry"

Fig.7

Effect of interface temperature on responseintensity of quinoline mass spectrometry"

Fig.8

Linear relation of quinoline standard curve"

Tab.1

Spiked recovery and precision of quinoline"

纺织面料 加标量/(mg·kg-1) 平均加标回收率/% RSD/%
棉 10 91.79 4.22
200 96.77 1.89
1 000 102.07 3.44
羊毛 10 94.51 4.53
200 97.84 3.33
1 000 101.31 1.27
涤纶 10 90.75 4.25
200 94.92 1.54
1 000 98.59 1.71
锦纶 10 90.02 3.93
200 93.13 1.48
1 000 97.49 1.63

Tab.2

Comparison between chemical extraction detection method and Py/TD-GC-MS method"

检测方法 样品处理
有机试剂		 样品处理
时间/min		 喹啉含量/(mg·kg-1)
橙色纱线 黑色纱线
化学提取检测法 15 mL甲醇 30 69.73 60.33
Py/TD-GC-MS法 - 5 91.63 79.04
[1] LAM P, KAN C, YUEN M C, et al. Studies on quinoline type dyes and their characterisation studies on acrylic fabric[J]. Coloration Technology, 2012, 128(3): 192-198.
doi: 10.1111/j.1478-4408.2012.00363.x
[2] LUONGO G, THORSÉN G, ÖSTMAN C. Quinolines in clothing textiles: a source of human exposure and wastewater pollution?[J]. Analytical and Bioanalytical Chemistry, 2014, 406(12): 2747-2756.
doi: 10.1007/s00216-014-7688-9
[3] LENSEN G, JUNGBAUER F, GONÇALO M, et al. Airborne irritant contact dermatitis and conjunctivitis after occupational exposure to chlorothalonil in textiles[J]. Contact Dermatitis, 2007, 57(3): 181-186.
pmid: 17680869
[4] OLIVEIRA D P, CARNEIRO P A, SAKAGAMI M K, et al. Chemical characterization of a dye processing plant effluent: identification of the mutagenic components[J]. Mutation Research/Genetic Toxicology and Environmental Mutagenesis, 2007, 626(1/2): 135-142.
doi: 10.1016/j.mrgentox.2006.09.008
[5] LUONGO G, IADARESTA F, MOCCIA E, et al. Determination of aniline and quinoline compounds in textiles[J]. Journal of Chromatography A, 2016, 1471(11): 11-18.
doi: 10.1016/j.chroma.2016.09.068
[6] KARLBERG A T, BERGSTRÖM M A, BÖRJE A, et al. Allergic contact dermatitis: formation, structural requirements, and reactivity of skin sensitizers[J]. Chemical Research in Toxicology, 2008, 21(1): 53-69.
doi: 10.1021/tx7002239
[7] KEZIC S, NIELSEN J B. Absorption of chemicals through compromised skin[J]. International Archives of Occupational and Environmental Health, 2009, 82(6): 677-688.
doi: 10.1007/s00420-009-0405-x pmid: 19238423
[8] NEUWOEHNER J, REINEKE A K, HOLLENDER J, et al. Ecotoxicity of quinoline and hydroxylated derivatives and their occurrence in groundwater of a tar-contaminated field site[J]. Ecotoxicology and Environmental Safety, 2009, 72(3): 819-827.
doi: 10.1016/j.ecoenv.2008.04.012 pmid: 18550163
[9] 季浩, 沈日炯, 傅萍. 气相色谱法测定染料产品中喹啉的含量[J]. 染料与染色, 2014, 51(5): 58-61.
JI Hao, SHEN Rijiong, FU Ping. Determination of quinoline in dyestuff by gas chromatography[J]. Dyestuff and Dyeing, 2014, 51(5): 58-61.
[10] 保琦蓓, 毛英俊, 沈波音, 等. 气相色谱-质谱法测定纺织品中喹啉及其同分异构体异喹啉的残留量[J]. 理化检验(化学分册), 2020, 56(4): 423-427.
BAO Qibei, MAO Yingjun, SHEN Boyin, et al. Determination of quinoline and its isomer isoquinoline residues in textiles by gas chromatography-mass spectrometry[J]. Physical Testing and Chemical Analysis Part B: Chemical Analysis, 2020, 56(4): 423-427.
[11] PAUK V, KREJČÍ M, LEMR K. Unified chromatography-mass spectrometry as a versatile tool for determination of food dyes[J]. Analytica Chimica Acta, 2021, 1157(5): 1-11.
[12] 林金美, 薛建平, 杨燕, 等. 高效液相色谱法测定纺织品中喹啉的含量[J]. 福建轻纺, 2020 (9): 19-23.
LIN Jinmei, XUE Jianping, YANG Yan, et al. Determination of the content of quinoline in textile via gas chromatography-mass spectrometric method[J]. The Light & Textile Industries of Fujian, 2020(9): 19-23.
[13] KLUSKA M, KOMASIŃSKA M, JABŁOŃSKA J, et al. Challenges of HPLC determination of quinoline derivatives used in the treatment of malaria[J]. Journal of Liquid Chromatography & Related Technologies, 2018, 41(8): 451-457.
doi: 10.1080/10826076.2018.1448870
[14] KIM Y M, KIM J W, MOON H M, et al. Rapid quantification of N-methyl-2-pyrrolidone in polymer matrices by thermal desorption-GC/MS[J]. Analytical Sciences, 2017, 33(7): 821-824.
doi: 10.2116/analsci.33.821
[15] HOSAKA A, WATANABE A, WATANABE C, et al. Polymer-coated sample cup for quantitative analysis of semi-volatile phthalates in polymeric materials by thermal desorption-gas chromatography-mass spectrometry[J]. Journal of Chromatography A, 2015, 1391(1): 88-92.
doi: 10.1016/j.chroma.2015.02.066
[16] 王强, 王静, 曹亚丽, 等. 气相色谱-质谱法研究聚氯乙烯的热裂解行为[J]. 塑料科技, 2012, 40(5): 93-95.
WANG Qiang, WANG Jing, CAO Yali, et al. Study on pyrolysis behavior of polyvinyl chloride by gas chromatography-mass spectrometry[J]. Plastic Science and Technology, 2012, 40(5): 93-95.
[17] 柘植新, 大谷肇, 渡边忠一. 聚合物的裂解气相色谱-质谱图集[M]. 北京: 化学工业出版社, 2016: 108-109.
TSUGE Shin, OHTANI Hajime, WATANABE Chuichi. Pyrolysis-GC/MS date book of synthetic polymers[M]. Beijing: Chemical Industry Press, 2016: 108-109.
[1] GAO Yiping, LI Yichen, WANG Xiaohui, LIU Guojin, ZHOU Lan, SHAO Min, SHAO Jianzhong. Preparation and properties of flexible structural color film based on immobilization of liquid photonic crystals [J]. Journal of Textile Research, 2022, 43(12): 1-7.
[2] ZHANG Chudan, WANG Rui, WANG Wenqing, LIU Yanyan, CHEN Rui. Synthesis and properties of cationic modified flame retardant polyester fabrics [J]. Journal of Textile Research, 2022, 43(12): 109-117.
[3] AN Yijin, XUE Wenliang, DING Yi, ZHANG Shunlian. Evaluation of textile color rubbing fastness based on image processing [J]. Journal of Textile Research, 2022, 43(12): 131-137.
[4] ZHAO Lunyu, SUI Xiaofeng, MAO Zhiping, LI Weidong, FENG Xueling. Research progress in aerogel materials application for textiles [J]. Journal of Textile Research, 2022, 43(12): 181-189.
[5] CHU Yanyan, LI Shichen, CHEN Chao, LIU Yingying, HUANG Weihan, ZHANG Yue, CHEN Xiaogang. Research progress in bulletproof flexible textile materials and structures [J]. Journal of Textile Research, 2022, 43(12): 203-212.
[6] FANG Yinchun, CHEN Lüxin, LI Junwei. Preparation and properties of flame retardant and superhydrophobic polyester/cotton fabrics [J]. Journal of Textile Research, 2022, 43(11): 113-118.
[7] CAO Congcong, TANG Longshi, LIU Yuanjun, ZHAO Xiaoming. Research progress of inorganic antibacterial fabrics [J]. Journal of Textile Research, 2022, 43(11): 203-211.
[8] WANG Mingliang, ZHANG Huile, YUE Xiaoli, CHEN Huimin. Measurement of micro deformation of yarns and fabrics based on digital image correlation method [J]. Journal of Textile Research, 2022, 43(11): 52-58.
[9] CHENG Ningbo, MIAO Dongyang, WANG Xianfeng, WANG Zhaohui, DING Bin, YU Jianyong. Review in functional textiles for personal thermal and moisture comfort management [J]. Journal of Textile Research, 2022, 43(10): 200-208.
[10] XIAO Yuan, LI Qian, ZHANG Wei, HU Hanchun, GUO Xinlei. Influencing factors on flexible fabric-based electrical circuit formation by micro-jet printed primary cell replacement deposition [J]. Journal of Textile Research, 2022, 43(10): 89-96.
[11] ZHANG Jie, XU Chuqiao, WANG Junliang, ZHENG Xiaohu. Advancement in data-driven intelligent control system for roboticized textile production [J]. Journal of Textile Research, 2022, 43(09): 1-10.
[12] CHEN Junxian, LI Weiping, FU Qixuan, FENG Xinxing, ZHANG Hua. Preparation and properties of aramid/flame retardant viscose/flame retardant polyamide blended fabrics [J]. Journal of Textile Research, 2022, 43(09): 107-114.
[13] DU Huanzheng, LIU Jiancheng, LU Sha. Green innovation and development of textile industry under dual carbon goals [J]. Journal of Textile Research, 2022, 43(09): 120-128.
[14] YANG Mengfan, WANG Chaoxia, YIN Yunjie, QIU Hua. Printing and photochromic properties of spiropyran microcapsules on cotton fabrics [J]. Journal of Textile Research, 2022, 43(09): 137-142.
[15] YANG Huiyu, ZHOU Jingyi, DUAN Zijian, XU Weilin, DENG Bo, LIU Xin. Research progress in textile surface multifunctional modification by atomic layer deposition [J]. Journal of Textile Research, 2022, 43(09): 195-202.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd