Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 65-70.doi: 10.13475/j.fzxb.20210803106

• Textile Engineering • Previous Articles     Next Articles

Preparation and performance of spacer fabric-based photothermal-thermoelectric composites

LI Mufang, CHEN Jiaxin, ZENG Fanjia, WANG Dong()   

  1. Key Laboratory of Textile Fiber and Products, Ministry of Education, Wuhan Textile University,Wuhan, Hubei 430200, China
  • Received:2021-08-04 Revised:2022-03-18 Online:2022-10-15 Published:2022-10-28
  • Contact: WANG Dong E-mail:wangdon08@126.com

RichHTML

15

PDF (PC)

136

Abstract:

In order to improve the thermoelectric performance of flexible wearable energy supply equipment, NaOH and dimethylsulfoxide (DMSO) are used together to dope poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)to prepare NaOH/DMSO/PEDOT:PSS thermoelectric film, and the influence of NaOH and DMSO concentration on the conductivity, Seebeck coefficient and power factor of PEDOT:PSS were studied. Cotton/polyester spacer fabric was used as the substrate, and the photothermal-thermoelectric composite thermoelectric material was prepared by compounding NaOH/DMSO/PEDOT:PSS and coating ZrC/polyurethane (PU) photothermal layer, and the morphology, structure and thermoelectric properties of the composites were characterized. The results show that when 0.5% NaOH and 3.5% DMSO are added, the power factor of NaOH/DMSO/PEDOT:PSS thermoelectric film reaches the peak value of 25.6 μW/(m·K2), which is 2 327 times that of pure PEDOT:PSS film. The Seebeck coefficient of the photothermal-thermoelectric composite material is 35.5 μV/K, and the voltage generated by the thermoelectric composite material under illumination after adding the photothermal layer is 6.3 times that of the thermoelectric composite material without a photothermal layer.

Key words: photothermal material, thermoelectric material, spacer fabric, ZrC, polyurethane, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), flexible wearable energy supply equipment

CLC Number: 

  • TB34

Fig.1

Influence of NaOH concentration on Seebeck coefficient, conductivity(a) and power factor(b) of PEDOT:PSS thermoelectric film"

Fig.2

Effect of DMSO concentration on Seebeck coefficient, conductivity(a) and power factor(b) of PEDOT:PSS thermoelectric film"

Fig.3

Morphology of spacer fabric-based photothermal-thermoelectric composite. (a) Cross-sectional of composite(×33);(b) Surface of spacer fabric(×1 000); (c) Cross-sectional of ZrC/PU photothermal layer(×50)"

Fig.4

Thermoelectric properties of spacer fabric-based photothermal-thermoelectric composite materials. (a) Resistance changes with DMSO concentration; (b) Voltage changes with temperature; (c) Voltage changes with time"

Fig.5

Voltage generated by photothermal-thermoelectric composite under light and thermoelectric unit series structure. (a) Effect of optical power density on voltage generated;(b) Thermoelectric unit series structure; (c) Voltagechanges with time"

[1] GAO J Y G, SHANG K Z, DING Y C, et al. Material and configuration design strategies towards flexible and wearable power supply devices: a review[J]. Journal of Materials Chemistry A, 2021, 9: 8950-8965.
doi: 10.1039/D0TA11260G
[2] KIM C S, LEE G S, CHOI H, et al. Structural design of a flexible thermoelectric power generator for wearable applications[J]. Applied Energy, 2018, 214: 131-138.
doi: 10.1016/j.apenergy.2018.01.074
[3] 张雪飞, 李婷婷, 许炳铨, 等. 用低温界面聚合法制备多功能核壳结构热电织物[J]. 纺织学报, 2021, 42(2): 174-179.
ZHANG Xuefei, LI Tingting, XU Bingquan, et al. Preparation of multifunctional core-shell structure thermoelectric fabrics by low-temperature interfacial polymerization[J]. Journal of Textile Research, 2021, 42(2): 174-179.
[4] FAN X, NIE W, TSAI H, et al. PEDOT:PSS for flexible and stretchable electronics: modifications, strategies, and applications[J]. Advanced Science, 2019. DOI: 10.1002/advs.201900813.
doi: 10.1002/advs.201900813
[5] KIM G H, SHAO L, ZHANG K, et al. Engineered doping of organic semiconductors for enhanced thermoelectric efficiency[J]. Nature Materials, 2013, 12: 719-723.
doi: 10.1038/nmat3635 pmid: 23644522
[6] KIM N, KANG H, LEE J H, et al. Highly conductive all-plastic electrodes fabricated using a novel chemically controlled transfer-printing method[J]. Advanced Materials, 2015, 27: 2317-2323.
doi: 10.1002/adma.201500078
[7] DENG W, DENG L, LI Z, et al. Synergistically boosting thermoelectric performance of PEDOT:PSS/SWCNT composites via the ion-exchange effect and promoting SWCNT dispersion by the ionic liquid[J]. ACS Applied Materials and Interfaces, 2021, 13: 12131-12140.
doi: 10.1021/acsami.1c01059
[8] QU S, CHEN Y, SHI W, et al. Cotton-based wearable poly(3-hexylthiophene) electronic device for thermoelectric application with cross-plane temperature gradient[J]. Thin Solid Films, 2018, 667: 59-63.
doi: 10.1016/j.tsf.2018.09.046
[9] DU Y, CAI K F, CHEN S, et al. Thermoelectric fabrics: toward power generating clothing[J]. Scientific Reports, 2015. DOI: 10.1038/srep06411.
doi: 10.1038/srep06411
[10] SUN T, ZHOU B, ZHENG Q, et al. Stretchable fabric generates electric power from woven thermoelectric fibers[J]. Nature Communications, 2020. DOI: 10.1038/s41467-020-14399-6.
doi: 10.1038/s41467-020-14399-6
[11] WEIJTENS C, ELSBERGEN V, KOK M, et al. Effect of the alkali metal content on the electronic properties of PEDOT:PSS[J]. Organic Electronics, 2005, 6 (2): 97-104.
doi: 10.1016/j.orgel.2005.02.005
[12] PARK H, LEE S H, KIM F S, et al. Enhanced thermoelectric properties of PEDOT:PSS nanofilms by a chemical dedoping process[J]. Journal Materials Chemistry A, 2014, 2: 6532-6539.
doi: 10.1039/C3TA14960A
[13] 李晓英, 蒋高明, 马丕波, 等. 三维横编间隔织物的编织工艺及其性能[J]. 纺织学报, 2016, 37(7): 66-70.
LI Xiaoying, JIANG Gaoming, MA Pibo, et al. Knitting processes and properties of three-dimensional computer flat-knitted spacer fabrics[J]. Journal of Textile Research, 2016, 37(7): 66-70.
[14] KARAMI M, AKHAVAN-BAHABADI M A, DEHKORDI M R, et al. Thermo-optical properties of copper oxide nanofluids for direct absorption of solar radiation[J]. Solar Energy Materials and Solar Cells, 2016, 144: 136-142.
doi: 10.1016/j.solmat.2015.08.018
[1] XIE Ziwen, LI Jiawei, WANG Fenping, QI Dongming, YAN Xiaofei, ZHU Chenkai, ZHAO Lei, HE Guiping. Preparation of polydimethylsiloxane modified waterborne polyurethane acrylate hybrid latex and its applications in pigment printing [J]. Journal of Textile Research, 2022, 43(08): 119-125.
[2] YANG Wenbo, ZHANG Aojie, LIU Youyan, LI Qingyun. Adsorption and decolorization of Reactive Blue 4 by polyurethane foam-immobilized biosystem [J]. Journal of Textile Research, 2022, 43(08): 132-139.
[3] XUE Chao, ZHU Hao, YANG Xiaochuan, REN Yu, LIU Wanwan. Preparation and properties of polyurethane-based carbon nanotube/liquid metal conductive fibers [J]. Journal of Textile Research, 2022, 43(07): 29-35.
[4] ZHAO Boyu, LI Luhong, CONG Honglian. Preparation of cotton/Ti3C2 conductive yarn and performance of pressure capacitance sensor [J]. Journal of Textile Research, 2022, 43(07): 47-54.
[5] QUAN Heng, REN Jingzhi, CHEN Wenlong, YUAN Hui, XIE Nanping, WU Ruozi, NI Lijie. Migration and distribution of organic silicon and its blends on polyamide/polyurethane fabrics [J]. Journal of Textile Research, 2022, 43(06): 115-120.
[6] QI Dongming, FAN Gaoqing, YU Yihao, FU Ye, ZHANG Yan, CHEN Zhijie. Preparation and printing properties of castor oil-based UV-curable water-based coating ink [J]. Journal of Textile Research, 2022, 43(05): 26-31.
[7] SUN Zheru, ZHANG Qingle, HAO Lincong, CHENG Lu, XIA Xin. Preparation and performance of polyurethane/polydimethylsiloxane waterproof and moisture permeable membrane with star like topological geometry structure [J]. Journal of Textile Research, 2022, 43(04): 40-46.
[8] XIE Kaifang, LUO Fengxiang, BAO Xinjun, ZHOU Hengshu, XU Guangbiao. Preparation and performance of composite coated polyester harness cord with high wearability [J]. Journal of Textile Research, 2022, 43(03): 123-131.
[9] LIN Meixia, WANG Jiawen, XIAO Shuang, WANG Xiaoyun, LIU Hao, HE Yin. Preparation and performance of high sensitive ultra-compressed bio-based carbonized flexible pressure sensor [J]. Journal of Textile Research, 2022, 43(02): 61-68.
[10] MA Yiping, FAN Wuhou, WU Jinchuan, PU Zongyao. Preparation and application of fully aqueous organic-inorganic hybrid fluorine-free water-repellant finishing agents [J]. Journal of Textile Research, 2022, 43(02): 183-188.
[11] LI Zhenzhen, ZHI Chao, YU Lingjie, ZHU Hai, DU Mingjuan. Preparation and properties of waste cotton regenerative aerogel/warp-knitted spacer fabric composites [J]. Journal of Textile Research, 2022, 43(01): 167-171.
[12] XU Shilin, YANG Shiyu, ZHANG Yaru, HU Liu, HU Yi. Preparation and properties of thermoplastic polyurethane/tefluororone amorphous fluoropolymer superhydrophobic nanofiber membranes [J]. Journal of Textile Research, 2021, 42(12): 42-42.
[13] ZHU Lanfang, BAI Jie, ZHOU Yincheng, HOU Chengwei. Effect of ultrasonic treatment on 4,4'-diaminodiphenylmethane in polyurethane coating of polyester fabric [J]. Journal of Textile Research, 2021, 42(11): 124-128.
[14] CAO Yuanming, ZHENG Mi, LI Yifei, ZHAI Wangyi, LI Liyan, CHANG Zhuningzi, ZHENG Min. Preparation of MoS2/polyurethane composite fibrous membranes and their photothermal conversion properties [J]. Journal of Textile Research, 2021, 42(09): 46-51.
[15] DAI Shenhua, WENG Liang, LI Bingyan, ZHANG Jianping, YANG Xuhong. Preparation and properties of nano-ZnO loaded polyurethane/polyester foamed composite sponge [J]. Journal of Textile Research, 2021, 42(08): 96-101.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd