纺织学报 ›› 2021, Vol. 42 ›› Issue (08): 8-16.doi: 10.13475/j.fzxb.20210301109

• 纺织科技新见解学术沙龙专栏:循环再生及生物可降解纤维 • 上一篇    下一篇

生物基异己糖醇聚酯的制备及其构效关系研究进展

王亚宁1,2, 周楚帆2, 乌婧1,3(), 王华平2,3   

  1. 1.东华大学 纺织产业关键技术协同创新中心, 上海 201620
    2.东华大学 材料科学与工程学院, 上海 201620
    3.东华大学 纤维改性材料国家重点实验室, 上海 201620
  • 收稿日期:2021-03-01 修回日期:2021-05-17 出版日期:2021-08-15 发布日期:2021-08-24
  • 通讯作者: 乌婧
  • 作者简介:王亚宁(1997—),女,博士生。主要研究方向为生物可降解高分子材料。
  • 基金资助:
    国家自然科学基金项目(51803026);国家自然科学基金项目(52073054)

Progress in preparation and structure-property relationship of bio-based polyesters of isohexides

WANG Yaning1,2, ZHOU Chufan2, WU Jing1,3(), WANG Huaping2,3   

  1. 1. Co-Innovation Center for Textile Industry, Donghua University, Shanghai 201620, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received:2021-03-01 Revised:2021-05-17 Published:2021-08-15 Online:2021-08-24
  • Contact: WU Jing

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摘要：

异己糖醇是一类碳水化合物衍生二元醇,具有高刚性、手性、亲水性和低毒等特性,在制备新型生物基、生物可降解高分子材料方面具有广阔的发展前景。围绕近年来研究较为充分的全脂肪型及半芳香型异己糖醇基均聚酯与共聚酯,综述了其合成、热学性能、力学性能、生物降解性能及潜在应用,探讨此类聚酯的高效聚合反应工艺及构效关系。异己糖醇结构单元的引入可有效提高聚合物的玻璃化转变温度,以及促进其水解和生物降解性能,在构建具有更高性能的环境友好型聚酯方面具有较高潜力,有望应用于工程塑料、纤维、生物医药等领域。此类生物基聚酯的大规模商业化需进一步开发更高效、温和的聚合反应工艺以攻克其热敏感和热降解问题。

关键词: 生物基材料, 生物可降解材料, 聚酯, 异己糖醇, 异山梨醇, 构效关系

Abstract:

As a family of diols derived from carbohydrates, isohexides are promising building blocks for preparation of new bio-based and biodegradable polymers due to their attractive properties including high rigidity, chirality, hydrophilicity and low toxicity. In this review, a few types of isohexide-based aliphatic and semi-aromatic homo- and co-polyesters extensively studied in recent years were systematically discussed in terms of their synthesis, thermal properties, physical properties, biodegradability and potential applications. Furthermore, the polymerization process for higher efficiency and the structure-property relationship of these polyesters were also examined. It can be concluded that the introduction of isohexides building blocks effectively increases the glass transition temperature of polymers and promote the ability of hydrolysis and biodegradation, thus offering great potential in the construction of environmentally friendly polyesters which are expected to be used in engineering plastics, fibers, biomedical fields, and so on. It is pointed out that the large-scale commercialization of such bio-based polyesters requires further development of more efficient and mild polymerization process to overcome the problems in heat sensitivity and thermal degradation.

Key words: bio-based material, biodegradable material, polyester, isohexide, isosorbide, structure-property relationship

中图分类号: 

  • TQ323

图1

异己糖醇的3种异构体"

图2

异己糖醇与脂肪族二酰氯制备聚酯的路线"

图3

异山梨醇与不同碳链长度的二酸制备聚酯的路线"

图4

异山梨醇基典型共聚酯的化学结构及其合成路线 注:PBIS为聚(丁二酸丁二醇酯-co-丁二酸异山梨醇酯); PBISI为异山梨醇基四元共聚酯; PEIT为聚对苯二甲酸乙二醇酯-co-对苯二甲酸异山梨醇酯;PBIT为聚对苯二甲酸丁二醇酯-co-对苯二甲酸异山梨醇酯; PCIT为聚对苯二甲酸环己烷 二甲醇酯-co-对苯二甲酸异山梨醇酯; PCIsFs为聚呋喃二甲酸环己烷二甲醇酯-co-呋喃二甲酸异山梨醇酯。"

图5

异山梨醇与丁二酸以及不同的二元醇制备共聚酯"

图6

PCIT和14% PEICT纳米纤维的扫描电镜照片"

图7

PCIT与蜂蜜和ZnO共混纳米纤维透射电镜照片"

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