用SiO2/TiO2复合气凝胶制备超疏水光催化防紫外线织物

doi:10.13475/j.fzxb.20180608807

纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 90-96.doi: 10.13475/j.fzxb.20180608807

用SiO₂/TiO₂复合气凝胶制备超疏水光催化防紫外线织物

盛宇¹^,², 徐丽慧¹^,²(), 孟云³, 沈勇¹, 王黎明¹, 潘虹¹

^1. 上海工程技术大学服装学院, 上海 201620
^2. 浙江省清洁染整技术研究重点实验室, 浙江绍兴 312000
^3. 深圳市计量质量检测研究院, 广东深圳 518000

收稿日期:2018-06-28 修回日期:2019-04-04 出版日期:2019-07-15 发布日期:2019-07-25
通讯作者: 徐丽慧
作者简介:盛宇 (1993-),男,硕士生。主要研究方向为无机纳米材料研究及其在功能纺织材料中的应用。
基金资助:
国家自然科学基金项目(51703123);浙江省清洁染整技术研究重点实验室开放基金项目(1801);上海工程技术大学人才行动计划腾飞计划(2018RC46-2018)

Preparation of superhydrophobic, photocatalytic and UV-blocking textiles based on SiO₂/TiO₂ composite aerogels

SHENG Yu¹^,², XU Lihui¹^,²(), MENG Yun³, SHEN Yong¹, WANG Liming¹, PAN Hong¹

^1. Fashion College, Shanghai University of Engineering Science, Shanghai 201620, China
^2. Zhejiang Key Laboratory of Clean Dyeing and Finishing Technology, Shaoxing, Zhejiang 312000, China
^3. Shenzhen Academy of Metrology & Quality Inspection, Shenzhen, Guangdong 518000, China;

Received:2018-06-28 Revised:2019-04-04 Online:2019-07-15 Published:2019-07-25
Contact: XU Lihui

摘要/Abstract

摘要：

为制备一种多功能纺织品,采用溶胶-凝胶法制备SiO₂/TiO₂复合气凝胶,并将聚二甲基硅氧烷(PDMS)与SiO₂/TiO₂复合气凝胶混合后制备PDMS/SiO₂-TiO₂复合材料,采用浸—轧—烘工艺将其处理到棉织物表面,同时借助扫描电子显微镜、X射线光电子能谱仪、热重分析仪、原子力显微镜等对处理后织物进行表征,分析其超疏水性、光催化性能与抗紫外线性能。结果表明:处理后棉织物表面具有PDMS/SiO₂-TiO₂复合材料所构筑的微纳米粗糙结构,PDMS/SiO₂-TiO₂复合材料已成功处理到棉织物上;处理后棉织物接触角为157.7°,紫外线防护系数值为122.47,光照4 h后对亚甲基蓝光催化降解率达到87.08%。

关键词: SiO₂/TiO₂复合气凝胶, 光催化, 防紫外线纺织品, 超疏水, 棉织物

Abstract:

In order to prepare a new multifunctional textile, SiO₂/TiO₂ composite aerogel was prepared by sol-gel method, and polydimethylsiloxane (PDMS)/SiO₂-TiO₂ composite material was obtained by mixing PDMS and SiO₂/TiO₂ composite aerogel. PDMS/SiO₂-TiO₂ composites were applied to coat onto the cotton fabrics by dip-pad-cure process to prepare multifunctional textiles. The scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analyzer, atomic force microscopy were adopted to characterize the treated fabrics, and photocatalysis, hydrophobicity and UV-blocking properties were analyzed. The surface of the cotton fabric after treatment has the micro-nano roughness structure constructed by PDMS/SiO₂-TiO₂ composite material. The PDMS/SiO₂-TiO₂ composite material is successfully coated on the surface of the finished cotton fabric. The treated cotton fabric has a water contact angle of 157.7°, the UV protection factor of 122.47, and the photocatalytic degradation ratio for methylene blue of 87.08% after 4 h illumination.

Key words: SiO₂/TiO₂ composite aerogel, photocatalytic, anti-ultraviolet fabric, super-hydrophobicity, cotton fabric

中图分类号:

TS19

盛宇, 徐丽慧, 孟云, 沈勇, 王黎明, 潘虹. 用SiO₂/TiO₂复合气凝胶制备超疏水光催化防紫外线织物[J]. 纺织学报, 2019, 40(07): 90-96.

SHENG Yu, XU Lihui, MENG Yun, SHEN Yong, WANG Liming, PAN Hong. Preparation of superhydrophobic, photocatalytic and UV-blocking textiles based on SiO₂/TiO₂ composite aerogels[J]. Journal of Textile Research, 2019, 40(07): 90-96.

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参考文献 12

[1]	魏道培.印度: 解码中国技术纺织品市场[J]. 中国纤检, 2015(11):57.
	WEI Daopei . India: Decoding China's technical textiles market[J]. China Fiber Inspection, 2015(11):57.
[2]	丁维莲, 李现荣, 张学欢 , 等. 超疏水材料表面的制备[J]. 广东化工, 2016(16):301-302.
	DING Weilian, LI Xianrong, ZHANG Xuehuan , et al. Preparation of super hydrophobic material surface[J]. Guangdong Chemical, 2016(16):301-302.
[3]	杜晗笑, 郑振荣, 曹学亮 , 等. 超疏水气凝胶涂层超高分子量聚乙烯织物的制备与表征[J]. 纺织学报, 2018,39(4):93-99.
	DU Hanxiao, ZHENG Zhenrong, CAO Xueliang , et al. Preparation and characterization of super hydrophobic aerogel coated ultra-high molecular weight polyethylene fabric[J]. Journal of Textile Research, 2018,39(4):93-99.
[4]	CHEN Weimin, LI Shuai, MOHAMMAD Feizbakhshan , et al. TiO₂-SiO₂ nanocomposite aerogel loaded in melamine-impregnated paper for multi-functionalization: formaldehyde degradation and smoke suppression[J]. Construction and Building Materials, 2018,161:381-388. doi: 10.1016/j.conbuildmat.2017.11.129
[5]	FRICKE J . SiO₂-aerogels: modifications and applications[J]. Journal of Non-Crystalline Solids, 1990,121(1-3):188-192. doi: 10.1016/0022-3093(90)90129-A
[6]	林明通, 徐俊伟, 敖文亮 . SiO₂气凝胶的应用研究进展[J]. 中国材料科技与设备, 2013 ( 2):4-7.
	LIN Mingtong, XU Junwei, AO Wenliang . SiO₂ aerogel research progress[J]. China Material Technology and Equipment, 2013 ( 2):4-7.
[7]	张玉会, 刘燕妮, 杨建明 , 等. SiO₂气凝胶复合保温材料的热湿性能研究[J]. 新型建筑材料, 2017(3):67-71.
	ZHANG Yuhui, LIU Yanni, YANG Jianming , et al. Study on thermal and moisture properties of SiO₂ aerogel composite thermal insulation material[J]. New Building Material, 2017(3):67-71.
[8]	吕鹏鹏, 赵海雷, 刘欣 , 等. 常压干燥制备SiO₂气凝胶的研究[J]. 材料工程, 2012 ( 4):22-26.
	LÜ Pengpeng, ZHAO Hailei, LIU Xin , et al. Study on preparation of SiO₂ aerogels by atmospheric drying[J]. Materials Engineering, 2012 ( 4):22-26.
[9]	HAO Junhua, WANG Zhengjia . Modeling Cassie-Baxter state on superhydrophobic surfaces[J]. Journal of Dispersion Science and Technology, 2016,37:1208-1213. doi: 10.1080/01932691.2015.1089407
[10]	徐航天, 屈庆 . 无机纳米抗紫外涂料的研究进展[J]. 现代涂料与涂装, 2014(2):16-21.
	XU Hangtian, QU Qing . Research progress of inorganicnano anti UV coatings[J]. Modern Paint and Finishing, 2014(2):16-21.
[11]	JENNY Schneider, MATSUOKA Masaya, TAKEUCHI Masato , et al. Understanding TiO₂ photocatalysis: mechanisms and materials[J]. Chemical Reviews, 2014,114(19):9919-9986. doi: 10.1021/cr5001892 pmid: 25234429
[12]	吕赛龙, 霍瑞亭, 贾国强 . 光催化自清洁纺织品的制备及其性能[J]. 纺织学报, 2018,39(5):87-91.
	LÜ Sailong, HUO Ruiting, JIA Guoqiang . Preparation and properties of photocatalytic self-cleaning textiles[J]. Journal of Textile Research, 2018,39(5):87-91.

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棉织物	平均透过率/%		UPF
棉织物	UVA	UVB	UPF
原织物	9.60	3.80	16.03
PDMS/SiO₂-TiO₂整理后棉织物	0.26	0.07	122.47

用SiO₂/TiO₂复合气凝胶制备超疏水光催化防紫外线织物

Preparation of superhydrophobic, photocatalytic and UV-blocking textiles based on SiO₂/TiO₂ composite aerogels

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