原子层沉积技术对纤维素膜功能化的影响

doi:10.13475/j.fzxb.20200407406

纺织学报 ›› 2020, Vol. 41 ›› Issue (12): 26-30.doi: 10.13475/j.fzxb.20200407406

原子层沉积技术对纤维素膜功能化的影响

黎俊妤¹, 蒋培清², 张文奇³, 李文斌¹()

1.武汉纺织大学湖北省纺织新材料与先进加工技术省部共建国家重点实验室培育基地, 湖北武汉 430200
2.惠州学院旭日广东服装学院, 广东惠州 516007
3.湖北三江航天红阳机电有限公司, 湖北孝感 432000

收稿日期:2020-04-28 修回日期:2020-09-16 出版日期:2020-12-15 发布日期:2020-12-23
通讯作者: 李文斌
作者简介:黎俊妤(1995—),女,硕士生。主要研究方向为功能纺织品。

Effect of atomic layer deposition technology on functionalization of cellulose membrane

LI Junyu¹, JIANG Peiqing², ZHANG Wenqi³, LI Wenbin¹()

1. State Key Laboratory of Textile New Materials and Advanced Processing Technology in Hubei Province, Wuhan Textile University, Wuhan, Hubei 430200, China
2. Glorious Sun Guangdong School of Fashion, Huizhou University, Huizhou, Guangdong 516007, China
3. Hubei Sanjiang Boats Science & Technology Co., Ltd., Xiaogan, Hubei 432000, China

Received:2020-04-28 Revised:2020-09-16 Online:2020-12-15 Published:2020-12-23
Contact: LI Wenbin

摘要/Abstract

摘要：

为扩大纤维素膜的使用范围,使其可应用于医用、建筑等领域,利用纳米氧化锌具有紫外线屏蔽、抗菌等特性,采用原子层沉积(ALD)技术在纤维素膜表面沉积纳米氧化锌,制备具有紫外线阻隔以及抗菌功能的纤维素膜,并探讨不同ALD温度和循环次数对纤维素膜性能的影响。借助紫外分光光度计、扫描电子显微镜、X射线衍射仪、热重分析仪等对纤维素膜的结构和性能进行分析。结果表明:随着ALD温度和循环次数的增加,纤维素膜的紫外线透过率由74.50%下降至1.46%; ALD功能化纤维素膜对金黄色葡萄球菌的抑菌率高达99.9%;经改性的纤维素膜表面附着了六方晶系纤锌矿结构的纳米氧化锌层,残碳率由16.61%增加至31.20%。

关键词: 纤维素膜, 原子层沉积技术, 纳米氧化锌, 紫外线阻隔, 抗菌性能

Abstract:

In order to expand the use of cellulose membranes into medical, construction and other fields, with the characteristics of ultraviolet shielding, antibacterial of nano-zinc oxide, atomic layer depos-ition technology (ALD) were used to deposit nano-zinc oxide on the surface of cellulose membrane. The cellulose membrane was prepared to offer UV-blocking and antibacterial functions, and the effects of different temperatures and cycle numbers on the membrane properties were discussed. The structure and performance of the cellulose membranes treated with ALD were analyzed using ultraviolet spectrophotometer, scanning electron microscopy, X-ray diffraction, thermogravimetric analysis and other analytical tools. The results show that as the temperature and the number of cycles increase, the UV transmittance of the cellulose membrane treated with ALD is reduced from 74.50% to 1.46%, and the antibacterial rate of ALD functionalized cellulose membrane against Staphylococcus aureus reaches 99.9%. In addition, on the surface of the treated cellulose membrane with nano-zinc oxide with hexagonal wurtzite structure, the residual carbon rate increases from 16.61% to 31.20%.

Key words: cellulose membrane, atomic layer deposition technology, nano-zinc oxide, UV-blocking, antibacterial property

中图分类号:

TS101

黎俊妤, 蒋培清, 张文奇, 李文斌. 原子层沉积技术对纤维素膜功能化的影响[J]. 纺织学报, 2020, 41(12): 26-30.

LI Junyu, JIANG Peiqing, ZHANG Wenqi, LI Wenbin. Effect of atomic layer deposition technology on functionalization of cellulose membrane[J]. Journal of Textile Research, 2020, 41(12): 26-30.

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样品编号	温度/ ℃	循环次数	稀释倍数	菌落数	抑菌率/%
A0	25	0	1 000	401	—
A1	60	10	100	161	96.0
A15	110	10	100	134	96.7
A5	60	50	10	12	99.9
A19	110	50	10	19	99.9

原子层沉积技术对纤维素膜功能化的影响

Effect of atomic layer deposition technology on functionalization of cellulose membrane

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参考文献 17

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样品编号	温度/ ℃	循环次数	样品编号	温度/ ℃	循环次数
A0	25	0	A18	110	40
A1	60	10	A19	110	50
A2	60	20	A20	110	100
A3	60	30	A21	110	200
A4	60	40	A22	130	10
A5	60	50	A23	130	20
A6	60	100	A24	130	30
A7	60	200	A25	130	40
A8	90	10	A26	130	50
A9	90	20	A27	130	100
A10	90	30	A28	130	200
A11	90	40	A29	160	10
A12	90	50	A30	160	20
A13	90	100	A31	160	30
A14	90	200	A32	160	40
A15	110	10	A33	160	50
A16	110	20	A34	160	100
A17	110	30	A35	160	200

样品编号	温度/ ℃	循环次数	样品编号	温度/ ℃	循环次数
A0	25	0	A18	110	40
A1	60	10	A19	110	50
A2	60	20	A20	110	100
A3	60	30	A21	110	200
A4	60	40	A22	130	10
A5	60	50	A23	130	20
A6	60	100	A24	130	30
A7	60	200	A25	130	40
A8	90	10	A26	130	50
A9	90	20	A27	130	100
A10	90	30	A28	130	200
A11	90	40	A29	160	10
A12	90	50	A30	160	20
A13	90	100	A31	160	30
A14	90	200	A32	160	40
A15	110	10	A33	160	50
A16	110	20	A34	160	100
A17	110	30	A35	160	200

样品编号	温度/ ℃	循环次数	样品编号	温度/ ℃	循环次数
A0	25	0	A18	110	40
A1	60	10	A19	110	50
A2	60	20	A20	110	100
A3	60	30	A21	110	200
A4	60	40	A22	130	10
A5	60	50	A23	130	20
A6	60	100	A24	130	30
A7	60	200	A25	130	40
A8	90	10	A26	130	50
A9	90	20	A27	130	100
A10	90	30	A28	130	200
A11	90	40	A29	160	10
A12	90	50	A30	160	20
A13	90	100	A31	160	30
A14	90	200	A32	160	40
A15	110	10	A33	160	50
A16	110	20	A34	160	100
A17	110	30	A35	160	200