Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (05): 97-101.doi: 10.13475/j.fzxb.20180501905

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Antistatic properties of UV-reduced graphene oxide acrylic fabrics

FAN Lihua, SONG Weihua, WANG Chaoxia()   

  1. Key Laboratory of Eco-Textiles(Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2018-05-08 Revised:2018-12-06 Online:2019-05-15 Published:2019-05-21
  • Contact: WANG Chaoxia E-mail:wchaoxia@sohu.com

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Abstract:

Aiming at the tendency of acrylic fabrics to generate static electricity during wearing, a conventional process was utilized to impregnate acrylic fabrics into graphene oxide (GO) solution. The acrylic fabrics were hot pressed followed by UV light irradiation to reduce graphene oxide on the surface for imparting acrylic fabrics to antistatic properties. The surface microscopic morphology of acrylic fibers was characterized by scanning electron microscopy. The influence of temperature on the color performances of acrylic fabrics was investigated. The antistatic properties of the fabrics were discussed based on the surface electrical resistivity of the acrylic fabrics. The results show that acrylic fabrics impregnated around 90 ℃ possesses a higher adsorption capacity. The final surface electrical resistivity of the acrylic fabrics after UV light reduction is 13 kΩ·cm and the square resistance is 1.9 kΩ/□, which meets antistatic performance standards. After washing, the electrical resistivity decreases to 29 kΩ·cm demonstrating excellent washing performance. The washing fastness is grade 4 and the rubbing fastness is grade 3.

Key words: acrylic fabric, graphene oxide, UV light, adsorption capacity, antistatic property

CLC Number: 

  • TS195.5

Tab.1

Influence of temperature on adsorption properties of graphene oxide on acrylic fabrics"

腈纶浸渍
温度/℃		 L* a* b* C* K/S值
室温 56.94 3.98 8.51 10.28 6.233
50 50.75 3.45 10.61 12.08 7.919
70 44.77 3.52 11.14 12.61 9.486
80 45.26 3.70 11.68 13.18 9.705
90 43.07 3.30 9.31 10.79 10.063
100 49.30 3.55 11.73 13.18 8.849

Tab.2

Influence of UV Light reduction on color performances of GO-acrylic fabrics"

试样 L* a* b* C* K/S值
未处理腈纶织物 93.12 3.99 -11.98 12.63 2.199
氧化石墨烯腈
纶织物		 43.07 3.30 9.31 10.79 10.063
还原氧化石墨烯腈纶织物 23.39 0.69 2.19 2.30 13.788

Fig.1

SEM images of untreated acrylic fabrics and samples before and after UV light reduction. (a) Untreated acrylic fabrics;(b)GO-Acrylic fabrics; (c) RGO-Acrylic fabrics"

Tab 3

Influence of UV light reduction on electrical resistivity of GO-acrylic fabrics"

腈纶试样 电阻率/(kΩ·cm) 方阻/
(kΩ·□-1)
未处理腈纶织物 1010 —
氧化石墨烯
腈纶织物		 1010 —
还原氧化石墨烯
腈纶织物		 13 1.9
[1] LI P, LIU Y, WANG L, et al. Modified polyacrylonitrile fiber as a renewable heterogeneous base catalyst for Henry reaction and Gewald reaction in water[J]. Journal of Applied Polymer Science, 2018,135(11):45992.
[2] 张克勤, 杜德壮. 石墨烯功能纤维[J]. 纺织学报, 2016,37(10):153-157.
ZHANG Keqin, DU Dezhuang. Functional fibers based on graphene[J]. Journal of Textile Research, 2016,37(10):153-157.
[3] 刘艳春, 白刚. 等离子体接枝处理对腈纶抗静电性的影响[J]. 纺织学报, 2010,31(6):17-20.
LIU Yanchun, BAI Gang. Effect of plasma-grafting treatment on antistatic property of polyacrylonitrile fiber[J]. Journal of Textile Research, 2010,31(6):17-20.
[4] 张保宏, 薛涛, 孟家光, 等. 腈纶的抗静电技术及性能评价[J]. 合成纤维工业, 2014,37(4):54-56.
ZHANG Baohong, XUE Tao, MENG Jiaguang, et al. Antistatic technology and performance evaluation of acrylic fiber[J]. China Synthetic Fiber Industry, 2014,37(4):54-56.
[5] 陆肖莉, 张玉莲. 纺织品抗静电技术及测试评价方法的发展[J]. 中国纤检, 2010(20):61-63.
LU Xiaoli, ZHANG Yulian. Development of antistatic technology and test evaluation methods for textiles[J].China Fiber Inspection, 2010(20):61-63.
[6] 张清华, 张殿波. 石墨烯与纤维的高性能化[J]. 纺织学报, 2016,37(10):145-152.
ZHANG Qinghua, ZHANG Dianbo. Graphene and enhanced fibers[J]. Journal of Textile Research, 2016,37(10):145-152.
[7] FUGETSU B, SANO E, YU H, et al. Graphene oxide as dyestuffs for the creation of electrically conductive fabrics[J]. Carbon, 2010,48(12):3340-3345.
[8] MOLINA J, FERNáNDEZ J, INéS J C, et al. Electrochemical characterization of reduced graphene oxide-coated polyester fabrics[J]. Electrochimica Acta, 2013,93(4):44-52.
[9] 章勇. 石墨烯的制备与改性及在抗静电涂层中的应用[D]. 上海:华东理工大学, 2013: 43-49.
ZHANG Yong. Preparation and modification of graphene and its application in antistatic coatings[D]. Shanghai: East China University of Science and Technology, 2013: 43-49.
[10] 许庆亮. 一种新型抗静电腈纶的生产[J]. 合成纤维, 2014,43(12):17-19.
XU Qingliang. Production of a novel antistatic acrylic fiber[J]. Synthetic Fiber in China, 2014,43(12):17-19.
[11] 蔡再生. 纤维化学与物理[M]. 北京: 中国纺织出版社, 2009: 275.
CAI Zaisheng. Fiber Chemistry and Physics[M]. Beijing: China Textile & Apparel Press, 2009: 275.
[12] CAI G, XU Z, YANG M, et al. Functionalization of cotton fabrics through thermal reduction of graphene oxide[J]. Applied Surface Science, 2016,393:441-448.
[13] 张开永. 纳米金属氧化物改性抗静电腈纶的制备[D]. 上海:东华大学, 2014: 1-10.
ZHANG Kaiyong. Preparation of nanometer metal oxide modified antistatic acrylic fiber[D]. Shanghai: Donghua University, 2014: 1-10.
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