Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (05): 99-104.doi: 10.13475/j.fzxb.20190705406

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and stability of self-crosslinking P(St-NMA) photonic crystals with structural colors on polyester fabrics

LIU Guojin1,2, HAN Pengshuai3, CHAI Liqin3, WU Yu3, LI Hui3, GAO Yafang1, ZHOU Lan3()   

  1. 1. Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    3. Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2019-07-17 Revised:2019-12-13 Online:2020-05-15 Published:2020-06-02
  • Contact: ZHOU Lan E-mail:lan_zhou330@163.com

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Abstract:

In order to improve the stability of photonic crystals with structural colors on textile substrates, the poly(styrene-N-methylol acrylamide) (P(St-NMA)) colloidal microspheres with self-crosslinking were used as structural units to fabricate photonic crystals on polyester fabrics by a digital printing technology. The morphology of P(St-NMA) microspheres was observed, the arrangement and structural color effects of prepared photonic crystals were deeply characterized, and the stability of the P(St-NMA) photonic crystals with structural colors on the substrate was tested and compared with pure PSt photonic crystals. The results show that the P(St-NMA) colloidal microspheres present a typical core-shell structure, in which the hydrophobic PSt actes as the core layer and the hydrophilic PNMA as the shell layer. The prepared P(St-NMA) photonic crystals present regular arrangement, bright structural colors and obvious iridescence. Compared with pure PSt photonic crystals, the stability of P(St-NMA) photonic crystals is significantly improved, and P(St-NMA) photonic crystals are not easy to fall off the substrate surface after folding and washing. The improvement of the stability is attributed to the self-crosslinking between adjacent microspheres, which improves the bonding force between each other and enhances the bonding fastness between the photonic crystal layers and the substrates some extent.

Key words: self-crosslinking, P(St-NMA) colloidal microspheres, photonic crystal, structureal colors, polyester fabric

CLC Number: 

  • TS193.2

Fig.1

Typical TEM image (a) and SEM image (b) of P(St-NMA) colloidal microspheres"

Fig.2

Typical SEM images of photonic crystals fabricated by P (St-NMA) with different diameters on polyester fabrics"

Fig.3

Typical video microscope images of photonic crystals fabricated by P (St-NMA) with different diameters on polyester fabrics(×50)"

Fig.4

TEM images of P (St-NMA) colloidal microspheres with different shell thicknesses(×150 000)"

Fig.5

Video microscope images of photonic crystal structure colors(×50)"

Fig.6

Photos of structural colors produced from P(St-NMA) photonic crystals on polyester fabrics"

Fig.7

Microsphere arrangement of PSt(a) and P(St-NMA) (b) photonic crystals on polyester fabrics before and after folding and bending"

Fig.8

Video microscope images of PSt photonic crystals washed under different ultrasound times"

Fig.9

Video microscope images of P(St-NMA) photonic crystals washed under different ultrasound times"

Fig.10

SEM images of PSt photonic crystals washed under different ultrasound times"

Fig.11

SEM images of P(St-NMA) photonic crystals washed under different ultrasound times"

Tab.1

Comparison of the stability of photonic crystals prepared by PSt and P(St-NMA) microspheres"

结构基元 色彩饱和度 虹彩效应 稳固性
PSt微球 高 存在 较差
P(St-NMA)微球 高 存在 良好

Fig.12

Schematic reaction of NMA with St (a) and self-crosslinking reaction of —OH in PNMA (b)"

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