Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (08): 49-56.doi: 10.13475/j.fzxb.20200904808

• Fiber Materials • Previous Articles     Next Articles

Preparation and energy storage properties of polyacrylonitrile-based Si/C/carbon nanotube composite carbon nanofiber membrane

ZHANG Yaru1,2, HU Yi1,2(), CHENG Zhongling1,2, XU Shilin1,2   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education,Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2020-09-21 Revised:2021-05-01 Online:2021-08-15 Published:2021-08-24
  • Contact: HU Yi E-mail:huyi-v@zstu.edu.cn

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Abstract:

In order to overcome volume expansion in energy storage process of silicon materials, electrospinning technology was used to prepare polyacrylonitrile (PAN)/Si/Fe composite nano-fiber(NFs) membrane, which was deposited on the composite NFs by chemical vapor deposition method for growth of carbon nanotubes (CNTs). Carbonization took place afterwards at 800 ℃ to obtain PAN-based Si/C/CNTs composite carbon nanofiber(CNFs)membrane. The structure and properties of composite CNFs membrane were characterized by scanning electron microscope, transmission electron microscope, X-ray diffractometer and thermogravimetric analyzer. The fabricated membrane was used in the negative electrode of lithium ions battery, and the corresponding electrochemical performance test was carried out. The results show that with the catalyst of 15% FeSO4 (compared to PAN) in spinning solution, a unique caterpillar structure composite CNFs membrane appears which effectively improves the electrochemical performance of the battery. It has an initial specific discharge capacity of 2 067.9 mA·h/g, and it still maintains a specific discharge capacity of 851.2 mA·h/g after 400 cycles, with a capacity decay rate per cycle being only 0.15%.

Key words: electrospinning, chemical vapor deposition method, carbon nanotube, composite carbon nanofiber, energy storage performance

CLC Number: 

  • TQ340.64

Fig.1

SEM images of composite CNFs membrane with different mass fraction of FeSO4"

Fig.2

SEM images of composite CNFs membrane prepared with different types of iron salts. (a) 15% FeCl2; (b) 15% ferrocene"

Fig.3

TEM images of Si/C/CNT composite CNFs membrane at low(a)and high(b)power"

Fig.4

Raman spectra of composite CNFs membrane"

Fig.5

SEM image(a) and C(b), O(c), Si(d) and Fe(e) element distribution images of Si/C/CNT composite CNFs membrane"

Fig.6

XPS spectra of Si/C/CNTs composite CNFs membrane. (a) XPS total spectrum; (b) C1s spectrum; (c) O1s spectrum"

Fig.7

Nitrogen desorption/adsorption isotherm curve(a) and pore size distribution curve(b) for composite CNFs membrane"

Fig.8

TG curve of Si/C/CNTs composite CNFs membrane"

Fig.9

XRD pattern of Si/C/CNTs composite CNFs membrane"

Fig.10

Electrochemical performance curves of composite CNFs membrane anode lithium ion battery.(a)Charge-discharge curve;(b)Cycle voltammetry curves;(c)Nyquist curves;(d)Comparison of discharge capacity of lithium ion battery"

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