Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (07): 17-21.doi: 10.13475/j.fzxb.20210404505

• Fiber Materials • Previous Articles     Next Articles

Preparation and properties of normal pressure-anionic dyeable polypropylene fiber based on polyionic liquid

LIANG Jiaojiao1,2, WANG Jingjing1,2, XIA Yumin1,2,3,4(), ZHU Xinyuan3, YAN Bing4, SUN Liming4, WANG Yanping1,2, HE Yong5, WANG Yimin1,2   

  1. 1. Engineering Research Center of Technical Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China
    4. Zhejiang Hongji Petrochemical Co., Ltd., Jiaxing, Zhejiang 314200, China
    5. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
  • Received:2021-04-16 Revised:2021-11-16 Online:2022-07-15 Published:2022-07-29
  • Contact: XIA Yumin E-mail:xym@dhu.edu.cn

RichHTML

7

PDF (PC)

78

Abstract:

In order to prepare anionic dyeable polypropylene fiber, a type of cationic polyionic liquid was designed and synthesized, and its compatibility with the polypropylene blend system was studied. The blended system was spun into yarns by melt spinning method, and its mechanical properties and dyeing properties were investigated. Results show that the blending system of polypropylene and polyionic liquid has good compatibility. The addition of polyionic liquid reduces the degree of crystallinity and orientation of polypropylene, which makes the modified polypropylene fiber more favorable to combine with the dye. Dyeing experiment on the modified fiber showed that the dyeing rate and the dyeing depth of the fiber reaches 17.0% and 5.450 3 respectively. The breaking strength of the modified fiber is 4.4 cN/dtex, which meets the requirements for textile processing.

Key words: polypropylene fiber, polyionic liquid, compatibility, blending spinning, normal pressure-anionic dyeablility

CLC Number: 

  • TQ342

Fig.1

NMR hydrogen spectra of PIL-Cl/DBS"

Fig.2

Optical microscope (a) and SEM (b) images of PP and PIL-Cl/DBS blends"

Fig.3

DSC curves of PP and PIL-Cl/DBS blends. (a) Heating curve; (b) Cooling curve"

Fig.4

Contact angle diagrams of PP(a),PP and PIL-Cl/DBS blends(b)"

Tab.1

Mechanical properties of PP fibers before and after modification"

纤维类型 断裂强度/(cN·dtex-1) 断裂伸长率/%
PP纤维 5.1 24.0
改性纤维1 5.1 16.9
改性纤维2 4.4 19.3

Tab.2

Crystallinity and orientation of PP fibers before and after modification%"

纤维类型 结晶度 取向度
PP纤维 49.5 91.9
改性纤维1 48.1 91.5
改性纤维2 47.5 91.3

Fig.5

Dyeing effect diagram of PP fibers before and after modification. (a)PP fibers;(b)Modified fiber 1; (c)Modified fiber 2"

Tab.3

Dyeing depth of modified PP fibers"

纤维类别 K/S值 L值 C值
改性纤维1 4.000 7 30.95 22.22
改性纤维2 5.450 3 43.13 24.25
[1] 冯刚, 蔡芳昌. 聚丙烯纤维染色改性方法研究进展[J]. 广东化工, 2012, 39(1): 44, 61.
FENG Gang, CAI Fangchang. Research progress of dyeing and modification methods of polypropylene fiber[J]. Guangdong Chemical Industry, 2012, 39(1): 44,61.
[2] 王紫田. 可染性丙纶技术综述[J]. 山东纺织科技, 2010, 51(3): 46-48.
WANG Zitian. Review of dyeable polypropylene fiber technology[J]. Shandong Textile Science & Technology, 2010, 51(3): 46-48.
[3] GUO Zhongfeng, LAN Weilun, DONG Mingyan, et al. Development of disperse dyes polypropylene fiber and process parameter optimization:part II:dyeable polypropylene fiber production and melt spinning process parameter optimization[J]. Textile Research Journal, 2018, 88(13): 1505-1516.
doi: 10.1177/0040517517703600
[4] MIKHAILOVSKAYA A P, SERENKO M S, KISELEV A M. Effect of quaternary ammonium salts on the properties and dyeability of polypropylene fiber[J]. Russian Journal of Applied Chemistry, 2014, 87(7): 977-981.
doi: 10.1134/S1070427214070210
[5] MIKHAILOVSKAYA A P, SERENKO M S. Dyeing polypropylene fiber with disperse dyes using quaternary ammonium salts[J]. Theoretical Foundations of Chemical Engineering, 2016, 50(4): 513-517.
doi: 10.1134/S0040579516040217
[6] 马敬红, 梁伯润, 许赤峰, 等. 酸性可染聚丙烯短纤维性能研究[J]. 合成纤维工业, 2000 (2): 30-32.
MA Jinghong, LIANG Borun, XU Chifeng, et al. Study on properties of acid dyeable polypropylene staple fiber[J]. China Synthetic Fiber Industry, 2000 (2) : 30-32.
[7] KUO C F J, LAN W L, CHEN S H, et al. Development of disperse dye polypropylene fiber and process parameter optimization: part I: development of dyeable polypropylene fiber and parameter optimiza-tion[J]. Textile Research Journal, 2018, 88(1): 3-13.
doi: 10.1177/0040517516673335
[8] 花秀兵. 聚苯乙烯/膨润土可染改性聚丙烯纤维及其共混体系的研究[D]. 上海: 东华大学, 2010: 7-17.
HUA Xiubing. Study on polystyrene/bentonite dyeable modified polypropylene fiber and its blend system[D]. Shanghai: Donghua University, 2010:7-17.
[9] KAMAZ Mohanad, SENGUPTA Arijit, et al. DEPAZ Sandrina Svetlana, Poly(ionic liquid) augmented membranes for π electron induced separation/fractionation of aromatics[J]. Journal of Membrane Science, 2019, 579:102-110.
doi: 10.1016/j.memsci.2019.01.044
[10] LUO Bin, XIA Yumin, ZHAO Hualei, et al. Acid-base indicators for non-polar solvents via anion-exchange of polymeric ionic liquids with anionic dyes[J]. Polymer Chemistry, 2015, 6(47): 8099-8104.
doi: 10.1039/C5PY01157D
[11] IQBAL Kashif, JAVID Amjed, REHMAN Abdur, et al. Single bath dyeing of modified nylon/cotton blended fabrics using direct/acid dyes[J]. Pigment & Resin Technology, 2020, 49(3): 165-170.
[12] WANG Jingjing, LIANG Yuan, ZHANG Zhenfei, et al. Thermoplastic starch plasticized by polymeric ionic liquid[J]. European Polymer Journal, 2021.DOI: 10.1061/j.eurpolymj.2021.110367.
doi: 10.1061/j.eurpolymj.2021.110367.
[1] LI Aiyuan, SHI Xinyu, YUE Wanfu, YOU Weiyun. Preparation and property of silk fibroin based hydrogel scaffolds [J]. Journal of Textile Research, 2022, 43(06): 44-48.
[2] WANG Shudong, DONG Qing, WANG Ke, MA Qian. Preparation and properties of polylactic acid nanofibrous membrane reinforced by reduced graphene oxide [J]. Journal of Textile Research, 2021, 42(12): 28-33.
[3] JIANG Yulin, WANG Hui, ZHANG Keqin. Research progress of silk fibroin-based hydrogel bioinks for 3D bio-printing [J]. Journal of Textile Research, 2021, 42(11): 1-8.
[4] LI Feng, YANG Jiahao, LAI Gengchang, WANG Jiannan, XU Jianmei. Research progress of polymer embolic microspheres [J]. Journal of Textile Research, 2021, 42(10): 180-189.
[5] YIN Juhui, GUO Jing, WANG Yan, CAO Zheng, GUAN Fucheng, LIU Shuxing. Preparation and properties of sodium alginate/krill protein scaffold materials [J]. Journal of Textile Research, 2021, 42(02): 53-59.
[6] WANG Shudong, MA Qian, WANG Ke, QU Caixin, QI Yu. Structure and biocompatibility of silk fibroin/gelatin blended hydrogels [J]. Journal of Textile Research, 2020, 41(11): 41-47.
[7] SUN Fanchen, GUO Jing, YU Yue, ZHANG Sen. Preparation and properties of polyhydroxy fatty acid ester/sodium alginate composite electrospun nanofibers [J]. Journal of Textile Research, 2020, 41(05): 15-19.
[8] DONG Ke, LI Siming, WU Guanzheng, HUANG Hongrong, LIN Zhongshi, XIAO Xueliang. Preparation and properties of carbon fiber/polyester electrocardiogram monitoring embroidery electrode [J]. Journal of Textile Research, 2020, 41(01): 56-62.
[9] LIU Yue, MO Linxiang, CHEN Feng. Compatibility and dyeing properties of blending black disperse dyes [J]. Journal of Textile Research, 2019, 40(12): 63-67.
[10] LIN Yongjia, YANG Dongchao, ZHANG Peihua, GU Yan. Preparation and properties of regenerated silk fibroin/acellular dermal matrix blended nanofiber membrane [J]. Journal of Textile Research, 2019, 40(07): 13-18.
[11] DONG Hao, ZHANG Liping, LIU Yining, WANG Lejun, LIU Yayun, FU Shaohai. Preparation and properties of modified carbon black for dope dyeing of polylactic acid fiber [J]. Journal of Textile Research, 2019, 40(05): 64-69.
[12] DONG Weiguo. Preparation and properties of glass fiber/polypropylene fiber reinforced thermoplastic composites [J]. Journal of Textile Research, 2019, 40(03): 71-75.
[13] . Design on pressure compatibility model of evenness roll [J]. Journal of Textile Research, 2018, 39(11): 158-162.
[14] . Preparation and properties of polypropylene air filter membrane by melt differential electrospinning [J]. Journal of Textile Research, 2018, 39(10): 12-17.
[15] . Surface modification of Iron oxide yellow and its application in ultra-high molecular weight polyethylene [J]. JOURNAL OF TEXTILE RESEARCH, 2018, 39(02): 86-90.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 33 -34 .
[2] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 35 -36 .
[3] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 107 .
[4] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 109 -620 .
[5] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(01): 1 -9 .
[6] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 101 -102 .
[7] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 103 -104 .
[8] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 105 -107 .
[9] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 108 -110 .
[10] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 111 -113 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd