Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (10): 8-14.doi: 10.13475/j.fzxb.20210608507

• Academic Salon Column for New Insight of Textile Science and Technology: Key Technology and Application of Dope-dyed Fiber • Previous Articles     Next Articles

Preparation of self-dispersing Phthalocyanine Blue 15:3 particles and its application in spun-dyed viscose fiber

SONG Weiguang1,2, WANG Dong1, DU Changsen2, LIANG Dong2, FU Shaohai1()   

  1. 1. Jiangsu Engineering Research Center for Digital Textile Inkjet Printing (Jiangnan University), Wuxi,Jiangsu 214122, China
    2. Suzhou Sunmun Technology Co., Ltd., Suzhou, Jiangsu 215337, China
  • Received:2021-06-30 Revised:2021-07-15 Online:2021-10-15 Published:2021-10-29
  • Contact: FU Shaohai E-mail:shaohaifu@hotmail.com

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Abstract:

Aiming at short storage time and high transportation cost of the color paste for spun-dyed viscose fibers, the self-dispersing Phthalocyanine Blue 15:3 pigment powder were prepared by the spray drying method. The effects of the spray drying parameters including air inlet temperature, feeding rate, pressure and air flow rate on the properties of self-dispersing pigment were discussed. In addition, transmission electron microscope (TEM) and scanning electron microscope (SEM) were employed to study the apparent morphology, and the dispersion state of self-dispersing pigments in viscose fiber was investigated. The results show that when the inlet air temperature is 165 ℃, the feeding rate is 10 mL/min, the pressure is 0.2 MPa, and the air flow rate is 2.95 m3/min, particle size of the self-dispersing Phthalocyanine Blue 15:3 pigment powder is 171 nm, and the water contact angle is 13°. The pigments show excellent self-dispersing properties, and the centrifugal, acid and alkali resistance, heat resistance and salt resistance stability are all above 80%. The self-dispersing Phthalocyanine Blue 15:3 deminstrates a good interface compatibility with the viscose spinning solution and is homogeneously dispersed in the spun-dyed viscose fiber. The color fastness against rubbing and washing reach grade 4.

Key words: self-dispersing pigment, Phthalocyanine Blue 15:3, spun-liquid dyed, viscose fiber, spray drying method

CLC Number: 

  • TS193

Fig.1

Preparation process of AX-20 PWPB"

Fig.2

Influence of inlet temperature(a), feed rate(b), air compressor pressure(c) and air flow rate(d) on AX-20 PWPB particle size of spray dryer"

Fig.3

Original PB (a) and AX-20 PWPB(b) TEM photos and particle size distribution"

Fig.4

Water contact angles of original PB and AX-20 PWPB"

Fig.5

Effect of ultrasound on particle size of AX-20 PWPB(a) and original PB(b) and their dispersion in water(c)"

Fig.6

Heat resistance stability(a), acid and alkali resistance stability(b), salt resistance(c), and centrifugal stability(d) of AX-20 PWPB pigment"

Fig.7

Distribution of AX-20 PWPB in viscose spinning solution"

Fig.8

SEM images of section of the spun-dyed viscose fiber with different AX-20 PWPB mass fraction"

"

质量分数/
%		 b值 耐摩擦色牢度 耐水洗色牢度
干 湿 沾色 变色
1 -30.20 4~5 4~5 4~5 4~5
2 -33.75 4~5 4~5 4~5 4~5
3 -36.86 4~5 4~5 4~5 4
4 -36.96 4~5 4 4~5 4
5 -37.32 4~5 4 4~5 4
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