Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (10): 34-40.doi: 10.13475/j.fzxb.20201205207

• Fiber Materials • Previous Articles     Next Articles

Preparation and properties of viscose fibers modified with star-shaped halogen-free flame retardants

HE Ju1, LIU Xiaohui1(), SU Xiaowei1, LIN Shenggen1, REN Yuanlin2   

  1. 1. School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
  • Received:2020-12-18 Revised:2021-06-01 Online:2021-10-15 Published:2021-10-29
  • Contact: LIU Xiaohui E-mail:liuxiaohui@tiangong.edu.cn

RichHTML

16

PDF (PC)

73

Abstract:

Aiming at the potential safety hazard caused by the flammability of viscose fibers, phosphonitrilic chloride trimer containing a ring structure was selected as a functional monomer to design a star-shaped halogen-free flame retardant that combines phosphorus, nitrogen, silicon ternary flame retardant elements. The flame retardant was added to the viscose, and then the flame retardant modified viscose fibers was prepared through wetting spinning. The structures and properties of the modified viscose fibers were characterized by means of Fourier infrared spectroscopy, X-ray photoelectron spectroscopy, thermogravimetric analyzer, and thermogravimetric-mass spectrometry system. The results show that the flame retardancy of the modified viscose fibers was improved while the fibers maintaining the durability. In nitrogen atmosphere, its char residue rate at 800 ℃ increased from 12.5% to 31.2% compared with the unmodified viscose fibers. During the combustion process of the modified fibers, the release of combustible gas was significantly reduced and abundant expanded carbon layer was produced. The flame retardant operated in condensed phase and gas phase.

Key words: viscose fiber, blending modification, wetting spinning, flame retardant, phosphonitrilic chloride trimer, thermal stability, flame retardant mechanism

CLC Number: 

  • TS102.6

Fig.1

Preparation process of flame retardant"

Fig.2

1H NMR spectra of flame retardant"

Fig.3

FT-IR spectra of viscose fibers and flame retardant viscose fibers"

Fig.4

XPS analyses of viscose fibers, flame retardant viscose fibers before and after washed"

Fig.5

SEM images of viscose fibers (a), flame retardant viscose fibers (b) and char residues of flame retardant viscose fibers after combustion(c)"

Fig.6

TG (a) and DTG (b) curves of viscose fibers, flame retardant viscose fibers befoe and washed fibers in N2 atmosphere"

Fig.7

TG(a) and DTG(b) curves of viscose fibers, flame retardant viscose fibers before and washed fibers in air atmosphere"

Fig.8

Vertical flammability diagram of viscose fibers(a)and flame retardant viscose fibers(b)"

Fig.9

TG-MS analyses of viscose fibers and flame retardant viscose fibers"

Fig.10

Raman spectrum of flame retardant viscose fibers after combustion"

[1] LI Ping, WANG Bin, LIU Yanyan, et al. Fully bio-based coating from chitosan and phytate for fire-safety and antibacterial cotton fabrics[J]. Carbohydrate Polymers, 2020, 237:116173.
doi: S0144-8617(20)30347-7 pmid: 32241447
[2] MARTA G C, JYOTI B, NANDITA S, et al. Manufacturing and characterization of regenerated cellulose/curcumin based sustainable composites fibers spun from environmentally benign solvents[J]. Industrial Crops and Products, 2018, 111:536-543.
doi: 10.1016/j.indcrop.2017.09.041
[3] LIU Yang, JIANG Zeming, MIAO Jiaojiao, et al. Properties of flame-retardant cellulose fibers with ionic liquid[J]. Fibers and Polymers, 2017, 18(5):915-921.
doi: 10.1007/s12221-017-6922-4
[4] WANG Lihuan, REN Yuanlin, WANG Xiuli, et al. Fire retardant viscose fiber fabric produced by graft polymerization of phosphorus and nitrogen-containing monomer[J]. Cellulose, 2016, 23(4):2689-2700.
doi: 10.1007/s10570-016-0970-6
[5] ALONGI J, CARLETTO R A, BLASIO A D, et al. DNA: a novel, green, natural flame retardant and suppressant for cotton[J]. Journal of Materials Chemistry A, 2013, 1(15):4779-4785.
doi: 10.1039/c3ta00107e
[6] 王欣, 李青山, 狄友波, 等. 阻燃粘胶纤维的研究进展[J]. 高分子通报, 2012(1):96-102.
WANG Xin, LI Qingshan, DI Youbo, et al. Research progress of flame retardant viscose fiber[J]. Polymer Bulletin, 2012(1):96-102.
[7] ZHANG Xiansheng, XIA Yanzhi, YAN Xiong, et al. Efficient suppression of flammability in flame retardant viscose fiber through incorporating with alginate fiber[J]. Materials Letters, 2018, 215:106-109.
doi: 10.1016/j.matlet.2017.12.077
[8] CHEN Li, WANG Yuzhong. A review on flame retardant technology in China: part 1: development of flame retardants[J]. Polymers for Advanced Technologies, 2010, 21(1):1-26.
[9] CHENG Xianwei, GUAN Jinping, KIEKENS P, et al. Preparation and evaluation of an eco-friendly, reactive, and phytic acid-based flame retardant for wool[J]. Reactive and Functional Polymers, 2019, 134:58-66.
doi: 10.1016/j.reactfunctpolym.2018.11.006
[10] LIU Xiaohui, DING Chen, PENG Bo, et al. Synjournal and application of a new, facile, and efficient sorbitol-based finishing agent for durable and flame retardant lyocell fibers[J]. Cellulose, 2020, 27(6):3427-3442.
doi: 10.1007/s10570-019-02894-z
[11] ZHAO Bin, KOLIBABA T J, LAZAR S, et al. Facile two-step phosphazine-based network coating for flame retardant cotton[J]. Cellulose, 2020, 27(7):4123-4132.
doi: 10.1007/s10570-020-03047-3
[12] 全凤玉. 阻燃粘胶的制备及性能研究[D]. 青岛: 青岛大学, 2003: 38-42.
QUAN Fengyu. Research on the preparation and performance of flame retardant viscose[D]. Qingdao: Qingdao University, 2003: 38-42.
[13] BO Caiyi, SHI Zhongyu, HU Lihong, et al. Cardanol derived P, Si and N based precursors to develop flame retardant phenolic foam[J]. Scientific Reports, 2020, 10(1):12080.
doi: 10.1038/s41598-020-69088-7
[14] LIU Xiaohui, ZHANG Qiuyan, PENG Bo, et al. Flame retardant cellulosic fabrics via layer-by-layer self-assembly double coating with egg white protein and phytic acid[J]. Journal of Cleaner Production, 2020, 243:118641.
doi: 10.1016/j.jclepro.2019.118641
[15] ZHU Ping, SUI Shuying, WANG Bing, et al. A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY-GC-MS[J]. Journal of Analytical and Applied Pyrolysis, 2004, 71:645-655.
doi: 10.1016/j.jaap.2003.09.005
[16] LI Ximei, ZHANG Keke, SHI Ran, et al. Enhanced flame-retardant properties of cellulose fibers by incorporation of acid-resistant magnesium-oxide microcapsules[J]. Carbohydrate Polymers, 2017, 176:246-256.
doi: S0144-8617(17)30971-2 pmid: 28927605
[17] IAH B, ZHOU Yuyang, YUEN R K K, et al. Microporous boron based intumescent macrocycle flame retardant for poly(lactic acid) with excellent uv protection[J]. Chemical Engineering Journal, 2020, 402:126209.
doi: 10.1016/j.cej.2020.126209
[1] LIU Shuping, LI Liang, LIU Rangtong, HU Zedong, GENG Changjun. Flame retardant finishing of cotton fabric with tri-aminopropyl triethoxysilane [J]. Journal of Textile Research, 2021, 42(10): 107-114.
[2] SONG Weiguang, WANG Dong, DU Changsen, LIANG Dong, FU Shaohai. Preparation of self-dispersing Phthalocyanine Blue 15:3 particles and its application in spun-dyed viscose fiber [J]. Journal of Textile Research, 2021, 42(10): 8-14.
[3] LIU Suo, WU Dingsheng, LI Man, ZHAO Lingling, FENG Quan. Preparation of spunlaced viscose/polyaniline composite fiber membrane and its adsorption performance [J]. Journal of Textile Research, 2021, 42(08): 122-127.
[4] ZHANG Chao, JIANG Zhiming, ZHU Shaotong, ZHANG Chenxi, ZHU Ping. Application of hyperbranched phosphoramide in flame retardant finishing of viscose fabrics [J]. Journal of Textile Research, 2021, 42(07): 39-45.
[5] ZHANG Jiaojiao, LI Yuyang, LIU Yun, DONG Chaohong, ZHU Ping. Flame retardant and antibacterial treatments for cotton-viscose blended fabrics [J]. Journal of Textile Research, 2021, 42(07): 31-38.
[6] LIU Ke, CHEN Shuang, XIAO Ru. Preparation and properties of synergistic flame retardant copolyamide 6 fiber with phosphaphenanthrene group [J]. Journal of Textile Research, 2021, 42(07): 11-18.
[7] XU Kai, TIAN Xing, CAO Ying, HE Yaqi, XIA Yanzhi, QUAN Fengyu. Preparation and property of flame retardant polyester/calcium alginate fiber composites [J]. Journal of Textile Research, 2021, 42(07): 19-24.
[8] LIN Shenggen, LIU Xiaohui, SU Xiaowei, HE Ju, REN Yuanlin. Preparation and properties of Lyocell fibers and fabrics modified with new phytic acid based flame retardant [J]. Journal of Textile Research, 2021, 42(07): 25-30.
[9] GU Weiwen, WANG Wenqing, WEI Lifei, SUN Chenying, HAO Dan, WEI Jianfei, WANG Rui. Influence of carbon dots on properties of flame retardant poly(ethylene terephthalate) [J]. Journal of Textile Research, 2021, 42(07): 1-10.
[10] SUN Chenying, WANG Wenqing, JIN Gaoling, WANG Rui. Research advances in thermoplastic polymers for flame retardant and anti-dripping behavior [J]. Journal of Textile Research, 2021, 42(06): 171-179.
[11] WEN Yufeng, MA Xiaopu, SHENG Fangyuan, ZHU Zhiguo. Preparation of microencapsulated intumescent flame retardant and its use in polylactic acid [J]. Journal of Textile Research, 2021, 42(06): 71-77.
[12] LUO Xiaolei, LI Ziyan, MA Ya'nan, LIU Lin, KRUCINSKA Izabella, YAO Juming. Progress in ecological flame retardant technology for textiles [J]. Journal of Textile Research, 2021, 42(05): 193-202.
[13] WANG Ruifeng, LI Min, TIAN Anli, WANG Chunxia, FU Shaohai. Relationship between Disperse Yellow 6GSL crystal form and thermal stability of its dispersions [J]. Journal of Textile Research, 2021, 42(05): 96-102.
[14] NI Jie, YANG Jianping, YU Chongwen. Effect of ratio of strands twist factor to single yarn twist factor on properties of viscose plied yarns [J]. Journal of Textile Research, 2021, 42(05): 46-50.
[15] YANG Tingting, GAO Yuanbo, ZHENG Yi, WANG Xueli, HE Yong. Thermal degradation kinetics and pyrolysis products of bio-based polyamide 56 fiber [J]. Journal of Textile Research, 2021, 42(04): 1-7.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd