Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (06): 127-132.doi: 10.13475/j.fzxb.20210906906

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Testing method for permethrin content in cotton fabrics based on use of ultraviolet spectroscopy

WANG Zongqian1(), CHENG Lüzhu1, JIN Xianhua2, XIA Liping2   

  1. 1. School of Textile and Garment, Anhui Polytechnic University, Wuhu, Anhui 241000, China
    2. Chemical Test Center of Chuanhua Zhilian Co., Ltd., Hangzhou, Zhejiang 311215, China
  • Received:2021-09-22 Revised:2022-01-10 Online:2022-06-15 Published:2022-07-15

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Abstract:

To establish a more efficient method for detecting the content of permethrin in textiles, cotton fabrics containing different concentrations of permethrin were fabricated by padding process, and a comparative analysis of the permethrin-finished fabrics was presented in detail, using micromorphology, spectral characteristics and the loading of permethrin, scanning electron microscopy, ultraviolet-visible (UV-Vis) spectrometer with integrating sphere and the conventional gas chromatography. Further, the indices such as testing time, sample size and the testing cost were compared and evaluated. A strong absorption characteristic peak at 280 nm was observed, corresponings to the ultraviolet characteristic absorption of permethrin molecules. The value of absorbency is proportional to the loading of permethrin within the as-prepared fabric, which is consistent with the permethrin loading within the same fabric tested by using gas chromatography. The relative error and the value of variation detected by using UV-Vis spectroscopy are similar to the results achieved using gas chromatography. However, the UV-Vis spectroscopy testing method has obvious advantages of high efficiency and low cost.

Key words: permethrin, ultraviolet-visible spectrum, gas chromatography, pure cotton fabric

CLC Number: 

  • TS195.5

Fig.1

Diagram of permethrin finishing cotton fabric"

Fig.2

Gas chromatographic spectrum and standard curve of permethrin standard. (a) Gas chromatographic spectrum; (b) Standard curve"

Fig.3

SEM images of different concentrations permethrin treated cotton fabric. (a) Original cotton;(b) 0.5 g/L; (c) 1.0 g/L; (d) 2.0 g/L; (e) 2.5 g/L; (f) 3.0 g/L (e) 2.5 g/L; (f) 3.0 g/L"

Fig.4

Peak area and content of permethrin in finished cotton fabric"

Fig.5

UV-Vis spectra of cotton fabric before and after permethrin treatment"

Fig.6

UV spectra of cotton fabric before and after permethrin treatment"

Fig.7

Fitting curve between permethrin content and spectral intensity in finished cotton fabric"

Tab.1

Measurement accuracy and other indicators of permethrin content using different test methods"

测试
方法		 样品
编号		 平均相
对误差
值×100		 离散系
数CV
值/%		 单次测
试耗
时/min		 单次测
试所需
量/g		 测试
成本
紫外光
谱法		 1 4.2 3.7 ≤ 2 0.1 低
2 3.9 2.9
3 2.5 2.2
气相色
谱法		 1 2.9 2.9 ≥ 70 5.0 高
2 4.0 3.4
3 3.0 2.9
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