纺织学报 ›› 2019, Vol. 40 ›› Issue (01): 84-90.doi: 10.13475/j.fzxb.20180100607

• 染整与化学品 • 上一篇    下一篇

聚磺酸甜菜碱的合成及在棉织物抗菌整理中应用

周莉1,2, 王鸿博1,2(), 杜金梅1,2, 傅佳佳1,2, 王文聪1,2   

  1. 1.江南大学 江苏省功能纺织品工程技术研究中心, 江苏 无锡 214122
    2.生态纺织教育部重点实验室(江南大学), 江苏 无锡 214122
  • 收稿日期:2018-01-02 修回日期:2018-08-20 出版日期:2019-01-15 发布日期:2019-01-18
  • 通讯作者: 王鸿博
  • 作者简介:周莉(1993—),女,硕士生。主要研究方向为功能纺织材料。
  • 基金资助:
    江苏省产学研前瞻性研究项目(BY2016022-23);江苏省先进纺织工程技术中心项目(XJFZ/2015/1);中央高校基本科研业务费专项资金资助项目(JUSRP51622A)

Synthesis of polysulfopropylbetaine and its application inantibacterial cotton fabric

ZHOU Li1,2, WANG Hongbo1,2(), DU Jinmei1,2, FU Jiajia1,2, WANG Wencong1,2   

  1. 1. Jiangsu Engineering Technology Research Center of Functional Textiles, Jiangnan University, Wuxi, Jiangsu 214122, China
    2. Key Laboratory of Eco-Textiles(Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2018-01-02 Revised:2018-08-20 Online:2019-01-15 Published:2019-01-18
  • Contact: WANG Hongbo

RichHTML

3

PDF (PC)

102

摘要：

为实现棉织物的高效持久抗菌功能,制备了一种聚磺酸甜菜碱(PSPB)抗菌整理剂并将其应用于棉织物的抗菌整理。通过单因素分析法,探讨了PSPB质量浓度、浴比、浸泡时间、烘焙温度与烘焙时间对棉织物抑菌圈大小的影响,得到抗菌整理的优化工艺;采用活菌计数法对经优化工艺整理的棉织物进行抗菌性能及耐洗牢度测试。结果表明,抗菌整理的优化工艺条件为:PSPB质量浓度54 g/L,浴比1∶30,浸泡时间50 min,烘焙温度170 ℃,烘焙时间150 s。红外光谱与扫描电镜表征证实PSPB成功合成且成功接枝到棉纤维表面。整理后织物对大肠杆菌与金黄色葡萄球菌的抑菌率分别为99.87%、99.99%,且具有优异的耐洗性能。织物断裂强力及白度测试结果表明,PSPB抗菌棉织物的强力与白度均满足服用要求。

关键词: 甜菜碱, 棉织物, 抗菌整理, 接枝

Abstract:

In order to realize the efficient and durable antibacterial activities of cotton textiles, polysulfopropylbetaine (PSPB) antibacterial agents were prepared and applied in the functional finishing of cotton fabrics. The influence of finishing agent concentration, bath ratio, soaking time, baking time and baking temperature on the inhibition zone of cotton fabrics were carried out. The optimal conditions are 54 g/L of finishing agent concentration, 1∶30 of bath ratio, 50 min of soaking time, 150 s of baking time and 170 ℃ of baking temperature. Additionally, counting viable bacteria method was adopted to test the antibacterial properties and fastness to washing of cotton fabrics finished under the optimum reaction conditions. Also, it was proved that PSPB is synthesized and grafted successfully onto the surface of cellulose by characterization of infrared spectrometer and scanning electro microscopy. It is shown that the cotton fabrics finished by PSPB possesses excellent washability, and exhibits good antibacterial activity against both gram-negative bacteria Escherichia coli and gram-positive bacteria Staphylococcus aureus, with 99.87% and 99.99%, respectively, in antibacterial ratio. In terms of tests on the breaking strength and whiteness, no significant influence exists on cotton fabrics finished with PSPB and both properties accord with wearing needs.

Key words: betaine, antibacterial agent, cotton fabric, antibacterial finishing, grafting

中图分类号: 

  • TS195.5

图1

SPB与PSPB的合成路线"

图2

PSPB质量浓度对整理棉织物抑菌圈的影响"

图3

浴比对整理棉织物抑菌圈的影响"

图4

浸泡时间对整理织物抑菌圈的影响"

图5

烘焙温度对整理棉织物抑菌圈的影响"

表1

烘焙温度对整理棉织物强力和白度的影响"

烘焙
温度/℃		 断裂强力/N 白度/%
经向 纬向
原样 784.4 383.9 72.35
160 722.3 348.2 69.33
170 693.1 331.7 64.70
180 617.5 292.4 52.31

图6

烘焙时间对整理棉织物抑菌圈的影响"

图7

原棉织物与PSPB整理棉织物的SEM照片(×3 000)"

图8

PSPB、原棉织物与PSPB整理棉织物的红外谱图"

图9

最优工艺整理棉织物未洗涤和洗涤30次对E.coli/S.aureus的抑菌率"

图10

整理前后棉织物对E.coli/S.aureus的抗菌效果图 (a) Raw cotton fabric (E.coli); (b) Finished cotton fabric before washing (E.coli); (c) Finished cotton fabric after 30 times of washing (E.coli); (d) Raw cotton fabric (S.aureus); (e) Finished cotton fabric before washing (S.aureus); (f) Finished cotton fabric after 30 times of washing (S.aureus)"

表2

最优工艺整理棉织物的服用性能"

试样 经向断裂强力 纬向断裂强力 白度
强力/N 强力保留率/% 强力/N 强力保留率/% 白度/% 白度保留率/%
原棉织物 784.4 — 383.9 — 72.35 —
最优工艺整理棉织物 690.4 88.02 333.1 86.77 64.82 89.59
[1] 周莉, 王鸿博, 傅佳佳, 等. 应用电子束辐照技术的棉织物抗菌整理工艺优化[J]. 纺织学报, 2017,38(10):81-87.
ZHOU Li, WANG Hongbo, FU Jiajia, et al. Optimization on antibacterial finishing process of cotton fabricbased on electron beam irradiation[J]. Journal of Textile Research, 2017,38(10):81-87.
doi: 10.1177/004051756803800110
[2] SIMONCIC B, TOMSIC B. Structures of novel antimicrobial agents for textiles: a review[J]. Textile Research Journal, 2010,80(14):1721-1737.
doi: 10.1177/0040517510363193
[3] LIU Y, JIANG Z, LI J, et al. Antibacterial functionalization of cotton fabrics by electric-beam irradiation[J]. Journal of Applied Polymer Science, 2015,132(23):1-7.
[4] CHEN S, CHEN S, JIANG S, et al. Environmentally friendly antibacterial cotton textiles finished with siloxane sulfopropylbetaine[J]. Applied Materials & Interfaces, 2011,3(4):1154-1162.
doi: 10.1021/am101275d pmid: 21417413
[5] GRIGORAS A G, RACOVITA S, VASILIU S, et al. Dilute solution properties of some polycarboxybetaines with antibacterial activity[J]. Journal of Polymer Research, 2012,19(11):1-8.
doi: 10.1007/s10965-012-0001-8
[6] ZOU H, CHEN N, SHI M, et al. The metabolism and biotechnological application of betaine in microorganism[J]. Applied Microbiology and Biotechnology, 2016,100(9):3865-3876.
pmid: 27005411
[7] CHEN S, CHEN S, JIANG S, et al. Study of zwitterionic sulfopropylbetaine containing reactive siloxanes forapplication in antibacterial materials[J]. Colloids and Surfaces B:Biointerfaces, 2011,85(3):323-329.
doi: 10.1016/j.colsurfb.2011.03.004
[8] CHEN S, CHEN S, JIANG S, et al. Synjournal andcharacterization of siloxane sulfobetaine antimicrobia-lagents[J]. Surface Science, 2011,605(11):25-28.
[9] ZHANG Z, CHENG G, CARR L R, et al. The hydrolysis of cationic polycarboxybetaine esters to zwitterionic polycarboxybetaines withcontrolled properties[J]. Biomaterials, 2008,29(36):4719-4725.
doi: 10.1016/j.biomaterials.2008.08.030 pmid: 18819709
[10] CHEN S, YUAN L, LI Q, et al. Durable antibacterial and nonfouling cotton textiles with enhanced comfort via zwitterionic sulfopropylbetaine coating[J]. Small, 2016,12(26):3516-3521.
doi: 10.1002/smll.201600587 pmid: 27213986
[11] HE L, GAO C, LI S, et al. Non-leaching and durable antibacterial textiles finished with reactive zwitterionic sulfobetaine[J]. Journal of Industrial & Engineering Chemistry, 2017,46(4):373-378.
[12] 张冬梅. 抗菌拒水拒油多功能织物整理剂的制备及应用[D]. 杭州:浙江大学, 2012: 65.
ZHNAG Dongmei. Preparation and application of antibacterial water and oil repellent multifunctional finishing agent for fabric[D]. Hangzhou:Zhejiang University, 2012: 65.
[13] 封勤华. 载银硅丙乳液的制备及对棉针织物抗菌研究[D]. 苏州:苏州大学, 2011: 38.
FENG Qinhua. Synthesis of polyacrylate antimicrobial emulsion-Ag+ and the study of antibacterial finishing to cotton knitted fabric[D]. Suzhou:Soochow University, 2011: 38.
[14] 刘殷, 任学宏. 卤胺类单体接枝棉织物的抗菌整理工艺[J]. 纺织学报, 2013,34(2):129-135.
LIU Yin, REN Xuehong. Antibacterial finishing of cotton by grafting N-halamine monomers[J]. Journal of Textile Research, 2013,34(2):129-135.
[1] 王阳, 程春祖, 姜丽娜, 任元林, 郭迎宾. 紫外光接枝/ 溶胶-凝胶技术制备耐久性阻燃腈纶织物[J]. 纺织学报, 2020, 41(10): 107-115.
[2] 王博, 凡力华, 原韵, 殷允杰, 王潮霞. 可拉伸聚吡咯/ 棉针织物的制备及其储电性能[J]. 纺织学报, 2020, 41(10): 101-106.
[3] 刘国金, 石峰, 陈新祥, 张国庆, 周岚. 聚氨酯/ 相变蜡蓄热调温功能整理剂的制备及其在棉织物上的应用[J]. 纺织学报, 2020, 41(07): 129-134.
[4] 成世杰, 王晨洋, 张宏伟, 左丹英. 硼氮掺杂碳点对棉织物防紫外线性能的影响[J]. 纺织学报, 2020, 41(06): 93-98.
[5] 周青青, 陈嘉毅, 祁珍明, 陈为健, 邵建中. 阻燃抗菌棉织物的制备及其性能表征[J]. 纺织学报, 2020, 41(05): 112-120.
[6] 谭淋, 施亦东, 周文雅. 棉织物的硅溶胶疏水整理[J]. 纺织学报, 2020, 41(04): 106-111.
[7] 赵兵, 黄小萃, 祁宁, 钟洲, 车明国, 葛亮亮. 基于共价结合的纳米银抗菌棉织物研究进展[J]. 纺织学报, 2020, 41(03): 188-196.
[8] 高思梦, 王鸿博, 杜金梅, 王文聪. 甜菜碱聚合物的合成及其在棉织物抗菌整理中的应用[J]. 纺织学报, 2020, 41(02): 89-94.
[9] 高雪, 李政, 巩继贤, 李秋瑾, 李凤艳, 张健飞. 新型纺织用生物基抗菌整理剂的研究进展[J]. 纺织学报, 2020, 41(02): 187-192.
[10] 易领, 张何, 傅昕, 李雯. 石墨烯基锆钛复合材料改性棉织物的制备及其远红外发射性能 [J]. 纺织学报, 2020, 41(01): 102-109.
[11] 李育洲, 张雨凡, 周青青, 陈国强, 邢铁玲. 二氧化锰/ 石墨烯/ 棉织物复合电极的制及其电化学性能 [J]. 纺织学报, 2020, 41(01): 96-101.
[12] 陈莹, 周爽, 韦恬静, 方浩霞, 李宇菲. 聚吡咯复合织物的软模板法制备及其性能[J]. 纺织学报, 2019, 40(12): 93-97.
[13] 崔一帆, 侯巍, 周千熙, 闫俊, 路艳华, 何婷婷. 丝胶温敏凝胶对棉织物性能的影响[J]. 纺织学报, 2019, 40(12): 74-78.
[14] 孙玉发, 周向东. 棉用新型含磷氮阻燃剂的合成及其应用[J]. 纺织学报, 2019, 40(12): 79-85.
[15] 王访鹤, 王锐, 魏丽菲, 王照颖, 张安莹, 王德义. 层层自组装阻燃改性聚酯织物的制备及其性能[J]. 纺织学报, 2019, 40(11): 106-112.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发