纺织学报 ›› 2022, Vol. 43 ›› Issue (05): 32-37.doi: 10.13475/j.fzxb.20211206406

• 特约专栏:第十一届中国纺织学术年会专家观点 • 上一篇    下一篇

聚苯乙烯/铁-单宁酸配合物微球在棉织物上的结构生色

朱小威, 韦天琛, 李亦江, 邢铁玲(), 陈国强   

  1. 苏州大学 纺织与服装工程学院, 江苏 苏州 215021
  • 收稿日期:2021-12-28 修回日期:2022-02-27 出版日期:2022-05-15 发布日期:2022-05-30
  • 通讯作者: 邢铁玲
  • 作者简介:朱小威(1996—),女,博士生。主要研究方向为纺织品结构生色。
  • 基金资助:
    国家自然科学基金项目(51973144);国家自然科学基金项目(51741301);江苏高校优势学科建设工程资助项目(苏政办发[2018]87号);国家级大学生创新创业训练计划项目(202010285045)

Structural coloration of polystyrene/iron-tannin acid complex nanospheres on cotton fabrics

ZHU Xiaowei, WEI Tianchen, LI Yijiang, XING Tieling(), CHEN Guoqiang   

  1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
  • Received:2021-12-28 Revised:2022-02-27 Published:2022-05-15 Online:2022-05-30
  • Contact: XING Tieling

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摘要：

针对目前基于多巴胺制备结构色织物的过程耗时及成本高的问题,采取单宁酸替代多巴胺快速实现结构色效果,制备了聚苯乙烯/铁-单宁酸配合物(PS/TA-Fe3+)微球,并通过重力沉积法在棉织物表面构建无规密堆积的非晶胶体阵列。采用马尔文纳米粒度分析仪、场发射电子显微镜、透射电子显微镜和显微角分辨光谱仪对聚苯乙烯(PS)微球、PS/TA-Fe3+微球和结构色织物进行了表征,探究了适宜的单宁酸和Fe3+用量,表征了结构色织物表面PS/TA-Fe3+微球的排列、结构生色效果及PS/TA-Fe3+涂层的结构稳定性。结果表明:当单宁酸用量为10%、单宁酸与Fe3+的量比为10:1时,制备的PS/TA-Fe3+微球粒径均匀、单分散性较好,结构色织物颜色柔和明亮,不具备角度依赖性,且具有良好的耐洗涤和耐摩擦性能。

关键词: 结构生色, 结构色织物, 聚苯乙烯/铁-单宁酸配合物微球, 非晶胶体阵列, 无规密堆积结构

Abstract:

It is known that dopamine structurally colored fabrics is expensive and time-consuming. To address this problem, tannic acid was used in this research to replace dopamine for quickly achieving the structural color effect. PS/iron-tannin acid complex (PS/TA-Fe3+) nanospheres was prepared, which was used to construct random close-packed amorphous photonic arrays on the surface of cotton fabrics by gravity deposition. Polystyrene (PS) microspheres, PS/TA-Fe3+ nanospheres and structurally colored fabrics was characterized by Malvern nanoparticle size analyzer, field emission electron microscope, transmission electron microscope and angle-resolved spectrometer. The appropriate addition of tannins acid and Fe3+ were explored, and the arrangement of PS/TA-Fe3+ nanospheres on the surface of structurally colored fabrics, the structural colors and structural stability of PS/TA-Fe3+ coatings were characterized. The results show that when the amount of tannic acid is 10% and the molar ratio of tannic acid and Fe3+ is 10:1, the prepared PS/TA-Fe3+ microspheres appear to have uniform particle size and good mono-dispersity. The prepared fabric displayed soft, bright and angle-independent structural color, demonstrating good washing and rubbing durability.

Key words: structural color, structurally colored fabric, polystyrene/iron-tannin acid complex nanospheres, amorphous colloidal arrays, random close-packed structure

中图分类号: 

  • TS193

表1

不同单宁酸质量分数制备的PS/TA-Fe3+微球的粒径和PDI值"

单宁酸质量分数/% Dh/nm Da/nm PDI值
0 214 190 0.029
5 231 208 0.041
10 245 221 0.059
15 257 231 0.068
20 254 233 0.073
25 256 228 0.096
30 247 227 0.144

图1

不同单宁酸质量分数的PS/TA-Fe3+微球结构色织物的光学照片"

图2

不同单宁酸质量分数的PS/TA-Fe3+微球结构色织物的反射率曲线"

表2

不同Fe3+用量制备的PS/TA-Fe3+微球的粒径和PDI值"

单宁酸与Fe3+量比 Dh/nm Da/nm PDI值
0 214 190 0.029
20:1 239 216 0.065
10:1 245 221 0.059
20:3 247 223 0.082
5:1 251 225 0.068
4:1 249 222 0.074
10:3 247 225 0.079

图3

不同Fe3+用量的PS/TA-Fe3+微球结构色织物的光学照片"

图4

不同Fe3+用量的PS/TA-Fe3+微球结构色织物的反射率曲线"

图5

不同核粒径的PS/TA-Fe3+微球结构色织物照片"

图6

不同核粒径的PS/TA-Fe3+微球结构色织物的SEM照片"

图7

核粒径250 nm制备的PS/TA-Fe3+微球的TEM照片"

图8

观察角0°~90°变化时织物结构色的变化"

图9

不同核粒径的PS/TA-Fe3+微球结构色织物的反射率光谱"

图10

观察角0°~50°变化时织物结构色的反射率光谱"

图11

不同洗涤周期后结构色织物的反射光谱和洗液的透过率图谱"

图12

结构色织物摩擦前和摩擦后的光学图像与SEM 照片"

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