活性染料结构对彩色聚合物纳米球性能的影响

doi:10.13475/j.fzxb.20211104106

纺织学报 ›› 2022, Vol. 43 ›› Issue (12): 96-101.doi: 10.13475/j.fzxb.20211104106

活性染料结构对彩色聚合物纳米球性能的影响

张帅¹, 房宽峻¹^,²^,³^,⁴^,⁵(), 刘秀明¹, 乔曦冉¹

1.天津工业大学纺织科学与工程学院, 天津 300387
2.青岛大学纺织服装学院, 山东青岛 266071
3.生态纺织省部共建协同创新中心, 山东青岛 266071
4.生物多糖纤维成形与生态纺织国家重点实验室, 山东青岛 266071
5.国家先进印染技术创新中心, 山东泰安 271000

收稿日期:2021-11-08 修回日期:2022-09-13 出版日期:2022-12-15 发布日期:2023-01-06
通讯作者: 房宽峻
作者简介:张帅(1993—),男,博士生。主要研究方向为纺织品清洁染整技术。
基金资助:
国家重点研发计划项目(2017YFB0309800);山东省重大科技创新工程项目(2019TSLH0108)

Effect of reactive dye structure on performance of colored polymer nanospheres

ZHANG Shuai¹, FANG Kuanjun¹^,²^,³^,⁴^,⁵(), LIU Xiuming¹, QIAO Xiran¹

1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
2. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
3. Collaborative Innovation Center for Eco-Textiles of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
4. State Key Laboratory for Biofibers and Eco-textiles, Qingdao, Shandong 266071, China
5. National Engineering Research Center for Dyeing and Finishing of Textiles, Taian, Shandong 271000, China

Received:2021-11-08 Revised:2022-09-13 Published:2022-12-15 Online:2023-01-06
Contact: FANG Kuanjun

摘要/Abstract

摘要：

为提高彩色聚合物纳米球的染料负载量及着色性能,选取含不同数量磺酸基的活性染料和阳离子聚合物纳米球,制备了不同的彩色聚合物纳米球。通过平衡透析法,借助透射电子显微镜和纳米粒径/电位分析测试仪,探讨了含有不同数量磺酸基活性染料的浓度对彩色聚合物纳米球的染料吸附量、水合粒径及Zeta电位的影响。结果表明:相同染料浓度下,含有磺酸基越多的活性染料在阳离子纳米球上的吸附量越大;当磺酸基数量相同时,疏水性越强的活性染料在阳离子纳米球上的吸附量越大; 彩色聚合物纳米球的染料吸附量随着染料浓度增加而增加;Zeta电位的绝对值随染料浓度呈现先减小后增大的趋势,平均水合粒径呈现先增大后减小的趋势。

关键词: 活性染料, 染料结构, 吸附量, Zeta电位, 水合粒径, 彩色聚合物纳米球, 纤维染色

Abstract:

In order to improve the dye loading and coloring properties of the colored polymer nanospheres, polymer nanospheres with different colors were prepared by cationic composite nanospheres and reactive dyes which contain different amounts of sulfonic acid groups. The effects of the concentrations of sulfonic acid-based reactive dyes on the dye adsorption, particle size and zeta potential of the colored polymer nanospheres were investigated by equilibrium dialysis, transmission electron microscopy and nanoparticle size/Zeta potential analyzer. The results show that the more sulfonic acid groups were on the cationic nanospheres the greater was the adsorption of reactive dyes at the same dye concentration. When the number of sulfonic acid groups was the same, the more hydrophobic the reactive dyes were, the greater the adsorption amount on the cationic nanospheres. In addition, the amount of dye adsorbed by the color polymer nanospheres increased with increasing dye concentration. The absolute value of Zeta potential decreased followed by an increase, while the average hydrated particle size increased first and then decreased.

Key words: reactive dye, dye structure, adsorption quantity, Zeta potential, hydrated particle size, colored polymer nanosphere, fiber dyeing

中图分类号:

TQ31

张帅, 房宽峻, 刘秀明, 乔曦冉. 活性染料结构对彩色聚合物纳米球性能的影响[J]. 纺织学报, 2022, 43(12): 96-101.

ZHANG Shuai, FANG Kuanjun, LIU Xiuming, QIAO Xiran. Effect of reactive dye structure on performance of colored polymer nanospheres[J]. Journal of Textile Research, 2022, 43(12): 96-101.

图/表 9

图1

图2

图3

图4

图5

图6

表1

图7

图8

参考文献 16

[1]	LI Y C, FAN Q D, WANG X, et al. Structural coloration: shear-induced assembly of liquid colloidal crystals for large-scale structural coloration of tex-tiles[J]. Advanced Functional Materials, 2021, 31(19): 1-9.
[2]	LING J, YANG Z N, DENG C, et al. Photoluminescent nanoparticles in water with tunable emission for coating and ink-jet printing[J]. Journal of Materials Chemistry C, 2015, 3:3666-3675. doi: 10.1039/C5TC00318K
[3]	SONG Y W, FANG K J, BUKHARI M N, et al. Disperse dye/poly (styrene-methacrylic acid) nanospheres with high coloration performance for textiles[J]. Journal of Cleaner Production, 2020, 263: 1-15.
[4]	FANG K J, XIE R Y, LIU X M, et al. Reactive dye/ poly (styrene-co-butyl acrylate-co-trimethyl (vinylbenzyl) ammonium chloride) nanospheres with high coloration performance for cleaner dyeing of cotton fabrics[J]. Cellulose, 2019, 26(9):5807-5819. doi: 10.1007/s10570-019-02498-7
[5]	SONG Y W, FANG K J, BUKHARI M N, et al. Green and efficient inkjet printing of cotton fabrics using reactive dye@copolymer nanospheres[J]. ACS Applied Materials & Interfaces, 2020, 12(40):281-295.
[6]	YANG Y, LI M, FU S H. Use of highly-stable and covalently bonded polymer colorant on binder-free pigment printing of citric acid treated cotton fabric[J]. Cellulose, 2021, 28(3): 1843-1856. doi: 10.1007/s10570-020-03644-2
[7]	鲁鹏, 洪思思, 林旭, 等. 活性染料/聚苯乙烯复合胶体微球的制备及其在桑蚕丝织物上的结构生色[J]. 纺织学报, 2021, 42 (1): 90-95.
	LU Peng, HONG Sisi, LIN Xu, et al. Preparation of reactive dye/polystyrene composite colloidal microspheres and their structural coloring on silk fabrics[J]. Journal of Textile Research, 2021, 42(1): 90-95.
[8]	王东伟, 房宽峻, 刘秀明, 等. 彩色聚合物微球的制备及其在纺织品印染中应用的研究进展[J]. 纺织学报, 2019, 40(3): 175-182.
	WANG Dongwei, FANG Kuanjun, LIU Xiuming, et al. Preparation of colored polymer microspheres and research progress thereof in textile dyeing and prin-ting[J]. Journal of Textile Research, 2019, 40(3): 175-182.
[9]	王东伟, 房宽峻, 刘秀明, 等. 胺化活性红195/聚合物微球的制备及其在棉织物染色中的应用[J]. 纺织学报, 2022, 43(4): 90-96.
	WANG Dongwei, FANG Kuanjun, LIU Xiuming, et al. Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics[J]. Journal of Textile Research, 2022, 43(4): 90-96.
[10]	郭子婧, 刘秀明, 房宽峻, 等. 染料/聚合物复合共聚物微球的制备[J]. 纺织学报, 2017, 38(7): 80-84.
	GUO Zijing, LIU Xiuming, FANG Kuanjun, et al. Preparation of reactive dye/polymer composite copolymer microspheres[J]. Journal of Textile Research, 2017, 38(7): 80-84.
[11]	石进荣. 活性黑5染料/聚合物微球的制备与染色应用[D]. 天津: 天津工业大学, 2018:50-53.
	SHI Jinrong. Preparation and dyeing application of Reactive Black 5 dye/ polymer microspheres[D]. Tianjin:Tiangong University, 2018:50-53.
[12]	BURKINSHAW S M. Physico-chemical aspects of textile coloration[M]. New York: John Wiley & Sons, 2016:65-79.
[13]	徐保律, 吴伟, 钟毅, 等. 有机溶剂对液体活性染料分散和水解稳定性影响的模拟研究[J]. 纺织学报, 2021, 42(2): 113-121.
	XU Baolü, WU Wei, ZHONG Yi, et al. Simulation study on effect of organic solvents on dispersion and hydrolytic stability of liquid reactive dyes[J]. Journal of Textile Research, 2021, 42(2): 113-121.
[14]	张炜, 毛庆楷, 朱鹏, 等. 乙醇/水体系中改性蚕丝织物的活性染料染色动力学和热力学[J]. 纺织学报, 2020, 41(6): 86-92.
	ZHANG Wei, MAO Qingkai, ZHU Peng, et al. Kinetic and thermodynamic of reactive dye study on silk fabric modification in ethanol/water system[J]. Journal of Textile Research, 2020, 41(6): 86-92.
[15]	WU W, WANG C Y, XU H, et al. Study of the aggregation behaviour of three primary reactive dyes via molecular dynamics simulations[J]. Molecular Simulation, 2020(2):1-11.
[16]	ZHANG K, XIE R Y, FANG K J, et al. Effects of reactive dye structures on surface tensions and viscosities of dye solutions[J]. Journal of Molecular Liquids, 2019, 287: 1-20.

相关文章 15

[1]	乔曦冉, 房宽峻, 刘秀明, 巩继贤, 张帅, 张敏. 羟乙基甲基纤维素改性对棉和锦纶织物表面性质的差异性影响[J]. 纺织学报, 2022, 43(11): 127-132.
[2]	邵敏, 王丽君, 李美琪, 刘今强, 邵建中. 非水介质-微水体系中活性染料的水解和键合性能[J]. 纺织学报, 2022, 43(11): 94-103.
[3]	杨文博, 张傲洁, 刘幽燕, 李青云. 聚氨酯泡沫固定化生物体系对活性蓝4的吸附脱色[J]. 纺织学报, 2022, 43(08): 132-139.
[4]	刘宇, 谢汝义, 宋亚伟, 齐元章, 王辉, 房宽峻. 涤/棉交织物一浴法轧染工艺[J]. 纺织学报, 2022, 43(05): 18-25.
[5]	王东伟, 房宽峻, 刘秀明, 张鑫卿, 安芳芳. 胺化活性红195/聚合物微球的制备及其在棉织物染色中的应用[J]. 纺织学报, 2022, 43(04): 90-96.
[6]	裴刘军, 施文华, 张红娟, 刘今强, 王际平. 非水介质活性染料染色关键技术体系及其产业化研究进展[J]. 纺织学报, 2022, 43(01): 122-130.
[7]	鲜永芳, 王红梅, 吴明华, 王莉莉. 少/无氨氮助剂在活性染料深色印花中的应用[J]. 纺织学报, 2021, 42(11): 89-96.
[8]	陈小文, 吴伟, 钟毅, 徐红, 毛志平. 棉织物的活性染料低含水率焙蒸固色工艺[J]. 纺织学报, 2021, 42(07): 115-122.
[9]	徐保律, 吴伟, 钟毅, 徐红, 毛志平. 有机溶剂对液体活性染料分散和水解稳定性影响的模拟研究[J]. 纺织学报, 2021, 42(02): 113-121.
[10]	何雪梅, 冒海燕, 蔡露. 壳聚糖基杂化气凝胶对活性染料的吸附性能[J]. 纺织学报, 2021, 42(02): 148-155.
[11]	鲁鹏, 洪思思, 林旭, 李慧, 刘国金, 周岚, 邵建中, 柴丽琴. 活性染料/聚苯乙烯复合胶体微球的制备及其在桑蚕丝织物上的结构生色[J]. 纺织学报, 2021, 42(01): 90-95.
[12]	李庆, 管斌斌, 王雅, 刘天卉, 张洛红, 樊增禄. 光敏剂敏化Cu-有机骨架对活性深蓝K-R的高效光催化降解[J]. 纺织学报, 2020, 41(10): 87-93.
[13]	占镠祥, 李婉, 王高军, 赵先丽, 王妮, 李毓陵. 微波处理在蛋白质纤维加工中的应用研究进展[J]. 纺织学报, 2020, 41(08): 128-134.
[14]	丁永生, 代亚敏, 钟毅, 徐红, 毛志平, 张琳萍, 陈支泽. 棉纱线在活性染料皮克林乳液体系中的染色动力学[J]. 纺织学报, 2020, 41(07): 101-108.
[15]	张炜, 毛庆楷, 朱鹏, 柴雄, 李惠军. 乙醇/水体系中改性蚕丝织物的活性染料染色动力学和热力学[J]. 纺织学报, 2020, 41(06): 86-92.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

染料名称	染料相对分子质量	磺酸基数目	单位磺酸基所承载的相对分子质量
活性黄95	797.07	3	265.69
活性红218	852.15	3	284.05
活性蓝49	882.17	3	294.06

活性染料结构对彩色聚合物纳米球性能的影响

Effect of reactive dye structure on performance of colored polymer nanospheres

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 16

相关文章 15

Metrics

本文评价

推荐阅读 0