纺织学报 ›› 2025, Vol. 46 ›› Issue (05): 59-69.doi: 10.13475/j.fzxb.20241104702

• 特约专栏: 智能纤维与织物器件 • 上一篇    下一篇

纤维状水系锌离子电池的研究进展与展望

韩力杰, 刘樊(), 张其冲   

  1. 中国科学院苏州纳米技术与纳米仿生研究所 多功能材料与轻巧系统重点实验室, 江苏 苏州 215123
  • 收稿日期:2024-11-20 修回日期:2025-02-13 出版日期:2025-05-15 发布日期:2025-06-18
  • 通讯作者: 刘樊(1996—),男,特别研究助理,博士。研究方向为多功能纤维状器件与织物。E-mail: fliu2021@sinano.ac.cn。
  • 作者简介:韩力杰(1995—),男,博士生。主要研究方向为纤维状水系功能纤维与织物。
  • 基金资助:
    国家自然科学基金项目(T2422028);国家自然科学基金项目(52473270);中国博士后科学基金项目(2024M763485)

Research progress and prospects of fiber-shaped aqueous zinc-ion batteries

HAN Lijie, LIU Fan(), ZHANG Qichong   

  1. Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, Jiangsu 215123, China
  • Received:2024-11-20 Revised:2025-02-13 Published:2025-05-15 Online:2025-06-18

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摘要：

纤维状锌离子电池(FAZIBs)在推动智能纤维材料及智能可穿戴纺织品的发展中具有重要作用。为推动其在智能可穿戴设备中的高效应用,系统梳理了FAZIBs的基本工作原理、研究现状及未来发展趋势。首先,阐述了FAZIBs的储锌机制,并对FAZIBs的材料选择进行了深入讨论,包括锰基、钒基、普鲁士蓝类似物及有机材料,同时分析了这些材料对电池性能的直接影响;介绍了纤维电极的3种核心制备技术:原位生长技术、表面涂覆技术和湿法纺丝技术。同时,系统性地描述了FAZIBs的3种典型器件结构:平行结构、缠绕结构和同轴结构,并分析了这些结构对电池性能、稳定性和可穿戴性的影响。最后,针对FAZIBs在智能可穿戴设备中的应用挑战及未来发展方向,明确了多功能化、可扩展性和大规模生产等关键问题,并提出了未来的研究重点,包括提升能量密度、延长电池寿命以及增强器件稳定性,以促进FAZIBs在智能可穿戴纺织品领域的广泛应用。

关键词: 纤维状水系锌离子电池, 可穿戴设备, 智能纺织品, 电极材料, 器件结构

Abstract:

Significance Fiber-shaped aqueous zinc-ion batteries (FAZIBs) are crucial for the advancement of smart fiber materials and wearable devices. Their flexibility and safety make them ideal candidates for integration into textiles necessitating energy storage solutions. Zinc, being abundant and non-toxic, offers an environmentally friendly alternative to conventional lithium batteries. FAZIBs successfully address the limitations of conventional batteries, particularly with respect to flexibility and integration capabilities. As the market for wearable devices expands, there is an increasing demand for compact and flexible energy storage systems. The development of FAZIBs not only propels energy storage research forward but also unlocks new opportunities for smart textiles. Their durability in various conditions, including bending and extreme temperatures, gives them a significant advantage for practical applications. Consequently, FAZIBs demonstrate substantial potential for future use in wearable electronics and smart fabrics.
Progress The development of FAZIBs has advanced significantly in recent years, driven by innovations in materials science and fabrication techniques. A critical area of progress has been the optimization of zinc storage mechanisms within the fiber-based architecture. Various material selections, including manganese-based compounds, vanadium-based materials, Prussian blue analogs, and organic substances, have demonstrated potential in enhancing battery performance. These materials affect important performance parameters such as energy density, cycling stability, and charge/discharge rates. Additionally, the choice of electrode fabrication technique has emerged as a vital factor that has undergone substantial development. Techniques such as in-situ growth, surface coating, and wet spinning facilitate improved control over the structure and performance of fiber electrodes, thereby enhancing battery efficiency. Furthermore, advancements in device configurations, parallel, twisted, and coaxial, have contributed to increased stability, scalability, and integration into wearable devices. The progress achieved in these areas brings FAZIBs closer to commercial viability.
Conclusion and Prospect Despite the significant progress in FAZIBs development, challenges remain to be addressed for their widespread application in smart wearable textiles. Key challenges include enhancing energy density, extending battery life, and improving the stability and scalability of the devices. While current materials show promising performance, the need for higher energy density and longer-lasting batteries remains a critical focus for researchers. Furthermore, the development of large-scale production methods for FAZIBs is essential to facilitate their commercial viability. Looking to the future, the priority will be to improve the efficiency of both the materials and fabrication techniques. A focus on sustainable, high-performance materials and cost-effective manufacturing processes will be essential in driving FAZIBs toward practical use in wearable devices. As these challenges are addressed, FAZIBs will likely play an integral role in the next generation of smart textiles, contributing to the creation of fully integrated, functional, and energy-efficient wearable technology.

Key words: fiber-shaped aqueous zinc-ion battery, wearable device, smart textile, electrode material, device structure

中图分类号: 

  • TQ152

图1

FAZIBs储能机制"

图2

纤维电极制备技术"

图3

FAZIBs的研究进展"

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