Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (06): 93-98.doi: 10.13475/j.fzxb.20190900606

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics

CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying()   

  1. State Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, Hubei 430020, China
  • Received:2019-09-02 Revised:2020-02-28 Online:2020-06-15 Published:2020-06-28
  • Contact: ZUO Danying E-mail:zdy@wtu.edu.cn

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Abstract:

In order to improve the UV-resistant ability of cotton fabrics, boron-nitrogen-doped carbon dots (BN-CDs) were synthesized by a one-step hydrothermal method with citric acid, ethylenediamine and borax as raw materials. BN-CDs aqueous solution, BN-CDs/PVA aqueous solution and BN-CDs/waterborne polyurethane aqueous solution were sprayed on the surface of cotton fabric, respectively, and then the cotton fabric was rolled and dried. The results show that the prepared BN-CD is a graphite-like nanocrystal having a rich hydroxyl group and amine group on the surface, which make BN-CDs soluble in water. BN-CDs has a strong absorption peak in the ultraviolet region, and could emit bright blue fluorescence which is independent of excitation wavelengths. The finished cotton fabrics show high UV protection factors (UPF), BN-CDs/WPU finishing has the optimal effect. After 10 times washing, the UPF value remained at around 48, achieving the excellent protection level. The surface morphology of the cotton fabric is basically unchanged, and the hand feel was good, and meeting the ultraviolet protection requirement of the cotton fabrics.

Key words: boron nitrogen doping, carbon dot, cotton fabric, UV resistance, UV protection value, water washing performance

CLC Number: 

  • TS195.5

Fig.1

FT-IR spectrum of BN-CDs"

Fig.2

TEM image of BN-CDs"

Fig.3

UV-vis absorption spectra of BN-CDs and its photoluminescence (PL) excitation"

Fig.4

Irradiation pattern of BN-CDs under 365 nm UV lamp"

Fig.5

PL emission spectra of BN-CDs excited by different wavelengths"

Fig.6

Infrared spectrum of cotton. (a) Cotton fabrics finished with different solutions; (b) Cotton fabrics finished with different solutions after washing for 10 times"

Tab.1

UV protection factor of cotton fabric samples after finishing and different washing times"

编号 初始棉布 整理后 洗1次 洗2次 洗5次 洗10次
F1 31.2 130.5 39.5 44.0 35.3 36.3
F2 31.4 170.2 124.7 103.0 91.1 61.7
F3 31.2 97.1 53.0 49.2 48.4 50.1

Fig.7

Mass change rate of cotton fabric with washing times after finishing"

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