Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (07): 109-116.doi: 10.13475/j.fzxb.20190903908

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of magnetic-graphene oxide/poly(allylamine hydrochloride) microcapsules for adsorption of dyes

ZHAO Zhiqi1,2, LI Qiujin1,2, SUN Yuejing1,2, GONG Jixian1,2, LI Zheng1,2, ZHANG Jianfei1,2,3()   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tiangong University, Tianjin 300387, China
    3. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, Shandong 266071, China
  • Received:2019-09-12 Revised:2020-03-23 Online:2020-07-15 Published:2020-07-23
  • Contact: ZHANG Jianfei E-mail:zhangjianfei1960@126.com

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Abstract:

Facing the problem that printing and dyeing wastewater pollutes environment, this paper reports on hybrid magnetic microcapsules with Fe3O4-graphene oxide (Fe3O4-GO) and poly(allylamine hydrochloride) (PAH) for purifying and cleaning the wastewater during dyeing processes. These microcapsules were made through layer-by-layer (LBL) self-assembly due to the opposite charges of Fe3O4-GO and PAH. The structure and morphology of Fe3O4-GO and (PAH/Fe3O4-GO)n were characterized. Cationic methylene blue was then used to study the adsorption behaviour and mechanism of magnetic microcapsules. When methylene blue dye (0.2-3.0 mg/mL) was absorbed for 20 minutes by microcapsules, the adsorption reached maximum. Moreover, the absorption reaches maximum value at pH of 12 with an adsorption rate of 96.5%. The pseudo-second-order adsorption kinetic and Langmuir adsorption isothermal model are more suitable for describing the adsorption process of methylene blue on magnetic (PAH/Fe3O4-GO)2 microcapsules, with the theoretical maximum adsorption of 219.996 mg/g.

Key words: graphene oxide, magnetic microcapsules, dyeing wastewater, methylene blue, adsorption

CLC Number: 

  • TS195.5

Fig.1

Schematic illustration of LBL assembly of (PAH/Fe3O4-GO)n"

Fig.2

Images of Fe3O4-GO. (a) Optical microscope image; (b) TEM image"

Fig.3

Optical microscope images of (PAH/Fe3O4-GO)n"

Fig.4

Separation of (PAH/Fe3O4-GO)n microcapsules from solution by magnetic field"

Fig.5

Fourier transform infrared spectrum of Fe3O4-GO and (PAH/Fe3O4-GO)n"

Fig.6

Effect of adsorbent mass on adsorption capacity"

Fig.7

Adsorption of (PAH/Fe3O4-GO)2 to MB at different initial concentration and time"

Fig.8

Effect of pH value on (PAH/Fe3O4-GO)2 absorption to MB"

Fig.9

Adsorption of (PAH/Fe3O4-GO)2 microcapsules on different concentrations of MB"

Fig.10

Pseudo-first-order(a) and pseudo-second-order (b) kinetic for adsorption of MB by (PAH/Fe3O4-GO)2 microcapsules"

Tab.1

Kinetic model parameters for adsorption of MB by (PAH/Fe3O4-GO)2"

MB质量
浓度/
(mg·mL-1)		 吸附量
测量值/
(mg·g-1)		 准一级动力学 准二级动力学
Qe/(mg·g-1) k1/min-1 R2 Qe/(mg·g-1) k2/(g·mg-1·min-1) R2
1.0 62.995 8 35.644 2 0.025 3 0.603 4 62.640 2 0.015 9 0.999 9
2.5 86.533 7 51.214 7 0.018 3 0.700 7 86.533 0 0.011 6 0.999 8

Fig.11

Langmuir and Freundlich adsorption isotherms of MB on (PAH/Fe3O4-GO)2 microcapsules"

Tab.2

Adsorption isotherm parameter for adsorption of MB by (PAH/Fe3O4-GO)2"

Langmuir模型 Freundlich模型
Qmax/
(mg·g-1)		 KL R2 1/n KF R2
219.996 0.422 12 0.958 21 0.849 29 5.126 48 0.947 94

Tab.3

Effect of elution times on desorption rate of (PAH/Fe3O4-GO)2"

洗脱次数 脱附率/%
1 52
2 53
3 54
4 54
[1] KONG L, GAN X, AHMAD A L B, et al. Design and synjournal of magnetic nanoparticles augmented microcapsule with catalytic and magnetic bifunctionalities for dye removal[J]. Chemical Engineering Journal, 2012,197:350-358.
doi: 10.1016/j.cej.2012.05.019
[2] 朱士凤, 曲丽君, 田明伟, 等. 涤纶织物的氧化石墨烯功能整理及其防熔滴性能[J]. 纺织学报, 2017,38(2):141-145.
ZHU Shifeng, QU Lijun, TIAN Mingwei, et al. Function finishing and anti-dripping property of polyethylene terephthalate fabric coated with graphene oxide[J]. Journal of Textile Research, 2017,38(2):141-145.
[3] ZHANG M, JIA Y, LI H, et al. A facile method to synjournale reduced graphene oxide /carbon nanotube hybrid fibers as binder-free electrodes for supercapacitors[J]. Synthetic Metals, 2017,232:66-71.
doi: 10.1016/j.synthmet.2017.07.010
[4] 张梅, 贾紫璇, 孙小娟, 等. 石墨烯纤维的湿法纺制及其性能[J]. 纺织学报, 2018,39(1):1-5.
ZHANG Mei, JIA Zixuan, SUN Xiaojuan, et al. Preparation and properties of wet-spinning graphene fibers[J]. Journal of Textile Research, 2018,39(1):1-5.
[5] THEBO K H, QIAN X, ZHANG Q, et al. Highly stable graphene-oxide-based membranes with superior permeability[J]. Nature Communications, 2018,9(1):1486.
doi: 10.1038/s41467-018-03919-0 pmid: 29662053
[6] MIAO X, YUE X, SHEN X, et al. Nitrogen-doped carbon dot-modified Ag3PO4/GO photocatalyst with excellent visible-light-driven photocatalytic performance and mechanism insight[J]. Catalysis Science & Technology, 2018,8(2):632-641.
[7] HSIEH S, TING J. Characterization and photocatalytic performance of ternary Cu-doped ZnO/Graphene materials[J]. Applied Surface Science, 2018,427(A):465-475.
[8] LIU G, JIN W, XU N. Graphene-based membranes[J]. Chemical Society Reviews, 2015,44(15):5016-5030.
pmid: 25980986
[9] YEH C N, RAIDONGIA K, SHAO J, et al. On the origin of the stability of graphene oxide membranes in water[J]. Nature Chemistry, 2014,7(2):166-170.
doi: 10.1038/nchem.2145 pmid: 25615671
[10] HILLEWAERE X K D, TEIXEIRA R F A, NGUYEN L T T, et al. Autonomous self-healing of epoxy thermosets with thiol-isocyanate chemistry[J]. Advanced Functional Materials, 2015,24(35):5575-5583.
[11] CHEN T, SELIG M J, LEE M C, et al. Encapsulation of copigmented anthocyanins within polysaccharide microcapsules built upon removable CaCO3 templates[J]. Food Hydrocolloids, 2018,84:200-209.
[12] 张维, 李秋瑾, 张健飞. 层层组装微胶囊的制备及其缓释性能[J]. 纺织学报, 2015,36(3):58-62.
ZHANG Wei, LI Qiujin, ZHANG Jianfei. Preparation and controlled release of microcapsules via layer-by layer assembly[J]. Journal of Textile Research, 2015,36(3):58-62.
[13] 刘菲, 李秋瑾, 巩继贤, 等. 层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用[J]. 纺织学报, 2019,40(2):114-118.
LIU Fei, LI Qiujin, GONG Jixian, et al. Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel[J]. Journal of Textile Research, 2019,40(2):114-118.
[14] LUO W, ZHU L, WANG N, et al. Efficient removal of organic pollutants with magnetic nanoscaled BiFeO3 as a reusable hetero-geneous fenton-like catalyst[J]. Environmental Science & Technology, 2010,44(5):1786.
doi: 10.1021/es903390g pmid: 20131791
[15] CHEN L, HUI N, YU C, et al. Amide pectin: a carrier material for colon-targeted controlled drug release[J]. Journal of Applied Polymer Science, 2016,133(29):43697.
[16] HUIZAR-FELIX A M, CRUZ-SILVA R, BARANDIARAN J M, et al. Magnetic properties of thermally reduced graphene oxide decorated with PtNi nanoparticles[J]. Journal of Alloys & Compounds, 2016,678:541-548.
[17] 徐春霞, 降帅, 韩阜益, 等. 纤维素纳米纤丝气凝胶制备及其对亚甲基蓝的吸附性能[J]. 纺织学报, 2019,40(10):20-25.
XU Chunxia, JIANG Shuai, HAN Fuyi, et al. Preparation of cellulose nanofibrils aerogel and its adsorption of methylene blue[J]. Journal of Textile Research, 2019,40(10):20-25.
[18] 张磊, 郝露, 徐山青. 废旧织物制备活性炭对亚甲基蓝的吸附动力学[J]. 纺织学报, 2016,37(12):76-80.
ZHANG Lei, HAO Lu, XU Shanqing. Adsorption kinetics of waste fabrics based activated carbon to methylene blue[J]. Journal of Textile Research, 2016,37(12):76-80.
doi: 10.1177/004051756703700203
[19] CHEN X, YE N. A graphene oxide surface-molecularly imprinted polymer as a dispersive solid-phase extraction adsorbent for the determination of cefadroxil in water samples[J]. RSC Advances, 2017,7(54):34077-34085.
doi: 10.1039/C7RA02985C
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