Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (03): 181-189.doi: 10.13475/j.fzxb.20200601410

Special Issue: Flame Retardant Fibers and Textiles

• Comprehensive Review • Previous Articles     Next Articles

Research progress of applications of photo-induced surface modification technique in flame retardant fabrics

ZHOU Yingyu1, WANG Rui1,2, JIN Gaoling3, WANG Wenqing1,2   

  1. 1. School of Material Design & Engineeing, Beijing Institute of Fashion Technology, Beijing 100029, China
    2. Key Laboratory of Clothing Materials R&D and Assessment, Beijing Institute of Fashion Technology,Beijing 100029, China
    3. China Chemical Fibers Association, Beijing 100020, China
  • Received:2020-06-05 Revised:2020-11-27 Online:2021-03-15 Published:2021-03-17

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Abstract:

In order to improve the durability and washable resistance of flame retardant textiles, and to balance between the flame retardant modification and green finishing, environmental protection, photo-induced surface modification for flame retardancy is one of the effective methods. The reaction mechanism of photo-induced surface modification, the flame retardant mechanism of coating and the finishing method for substrate surfaces were systematically described. Photo-induced flame retardancy treatment for cotton, polyester, polyamide, and polyacrylonitrile fabrics were mainly introduced, and the existing problems of flame retardant modification were analyzed. This review indicates that future developments of flame-retardant surface treatments for textiles need be concentrated on expanding photo-inducing light sources, especially natural light with low energy and bio-safety. The photo-controlled polymerization technology is expected to become an important technical method for facilitating the design and controlled growth of flame retardant coatings on fabric surfaces,so as to promote the wider application of the photo-induced surface treatment technology for functional flame-retardant fabrics.

Key words: photo-induced reaction, controlled polymerization, flame retardant mechanism, flame retardant finishing, surface modification, flame retardant fabric, functional textiles

CLC Number: 

  • TQ342

Fig.1

Schematic diagram of “Grafting to”"

Fig.2

Schematic diagram of “Grafting from”"

Tab.1

Different flame retardant coatings were prepared by photoinduced reaction on the surface of sample"

基材 阻燃添加剂 作用方式 阻燃效果(较原样品增加或降低的百分数)/% 参考文献
热释放速率峰值 总热释放量 LOI值
棉 CH、DNA 接枝-单体 -38 -45 — [50]
棉 PDHA 接枝-聚合 -65 -74 2 [33]
棉 ETMM树脂、AN、TAIC 交联 -78 -71 85 [38]
蚕丝 DEMEP 接枝共聚 — — 25 [51]
PA66 DOPO-DAAM 接枝-单体 -22 — 55 [52]
CO/PET Am 接枝-聚合物 — — 66 [53]
PAN GMA、水合肼、磷酸 接枝-聚合物 -60 -38 90 [19]
PET APP、MMEP 聚合 — — 55 [54]
木板 CO-SH、TTC、DA 交联 -10 -73 27 [55]
GRE VPA 交联 -98 -95 — [40]
RPU BHAAPE、MAAR、PUA 交联 — — 36 [39]
EVA 酪蛋白、DNA 交联 -26 -4 — [56]
PMMA PA、TGICA、TAEP 交联 — — 27 [57]
PC PUA、二氧化硅、支化聚乙烯亚胺 交联 — — 24 [58]
木板 TAP、DMAA、PETMP、PET3A 交联 — — 15 [59]
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