Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (11): 89-96.doi: 10.13475/j.fzxb.20201101409

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of low/non-ammonia additives in reactive deep printing

XIAN Yongfang, WANG Hongmei, WU Minghua, WANG Lili()   

  1. Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2020-11-06 Revised:2021-08-12 Online:2021-11-15 Published:2021-11-29
  • Contact: WANG Lili E-mail:liliwang@zstu.edu.cn

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Abstract:

In order to develop the low/non-ammonia additives with high color performances in reactive deep printing, this research started by comparing the hygroscopicity, ability to swell, and ability to solubilize reactive dyes of different printing additives, and the internal relationships between the structures of additives and the above properties were explored. The additives with the above-mentioned properties were compounded for reactive deep printing on cotton fabrics. The results showed that among different types of additives, glycerol demonstrated the best hygroscopicity, 1,4-butanediol showed the best swellability to cotton fiber, and the amides exhibited the best solubility to Reactive Turquoise K-GL. When the mass ratio of glycerol and 1,4-butanediol was 2∶8, the color performances of the non-ammonia nitrogen compound on the reactive turquoise deep printing of cotton fabrics were much higher than those of the commercial alternative 391-H and slightly higher than using urea as additive. Good printing performances with reactive red, orange, blue and black dyes were achieved, enabling the reduction of the ammonia-nitrogen content in the printing wastewater.

Key words: reactive dyes, printing, urea substitute, printing additive, cotton fabric, ammonia-nitrogen

CLC Number: 

  • TS194.4

Fig.1

Moisture absorption performances of sodium alginate film in different steaming time"

Fig.2

Hygroscopicity of different printing additives in sodium alginate film during steaming"

Fig.3

Images of cotton fibers before and after swelling in different printing additives solutions"

Tab.1

Swelling properties of cotton fibers in different printing additives solutions"

助剂 相对分子质量 D ¯ 2/μm CV2值/% S/%
1,2-丙二醇 76.09 20.19 1.586 31.69
1,4-丁二醇 90.12 21.61 2.560 40.98
三乙二醇 150.17 19.14 1.256 24.86
丙三醇 92.09 20.03 4.402 30.65
木糖醇 152.16 20.02 3.587 30.57
尿素 60.06 20.63 3.868 34.59
乙酰胺 59.07 19.70 2.239 28.53
己内酰胺 113.16 19.90 3.398 29.78
3-氨基丙醇 75.11 20.29 1.676 32.34
PEG-200 200.00 20.94 3.328 36.59

Fig.4

Solubility of different auxiliaries to Reactive Turquoise K-GL"

Fig.5

Infrared spectra of urea and Reactive Turquoise K-GL"

Fig.6

Infrared spectra of glycerol and Reactive Turquoise K-GL"

Fig.7

Infrared spectra of 1,4-butanediol and Reactive Turquoise K-GL"

Fig.8

Color performances of low/non-ammonia compounds in Reactive Turquoise K-GL deep printing of cotton fabrics. (a)Ternary low-ammonia compounds; (b) Binary non-ammonia compounds"

Tab.2

Color performances of printed cotton fabrics using urea and GB28 with different reactive dyes"

活性染料 印花助剂 K/S值 渗透率/% 色泽不匀度/%
艳红K-2BP 尿素 22.2 38.0 0.9
GB28 21.2 47.6 2.9
橙K-7R 尿素 21.8 44.8 0.6
GB28 20.3 33.6 1.6
艳蓝P-3R 尿素 11.7 45.5 3.2
GB28 9.7 56.2 2.9
黑WNN 尿素 21.6 45.1 1.1
GB28 21.7 37.0 0.7

Fig.9

Fine patterns of cotton fabrics using urea (a) and GB28 (b) with different reactive dyes"

Tab.3

Color fastness of printed cotton fabrics"

活性染料 印花助剂 耐摩擦色牢度 耐皂洗色牢度
干 湿 沾色 变色
艳红K-2BP 尿素 5 5 5 5
GB28 5 5 4~5 5
橙K-7R 尿素 5 5 4~5 4~5
GB28 4~5 4~5 4 4~5
艳蓝P-3R 尿素 4~5 4~5 4~5 4~5
GB28 4~5 4~5 4~5 4~5
黑WNN 尿素 5 5 5 5
GB28 5 5 4~5 5
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