Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (01): 172-177.doi: 10.13475/j.fzxb.20210910706

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and performance of cotton based Ti3C2Tx oil-water separation membrane

GAO Qiang, WANG Xiao(), GUO Yajie, CHEN Ru, WEI Ju   

  1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian, Liaoning 116034, China
  • Received:2021-09-27 Revised:2021-11-02 Online:2022-01-15 Published:2022-01-28
  • Contact: WANG Xiao E-mail:wangxiao@dlpu.edu.cn

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Abstract:

In order to develop cotton based oil-water separation materials with simple process, reusable and high oil-water separation efficiency, and to achieve utilization of waste cotton fabrics with low energy consumption and high added value, hydrophilic flexible MXene nano sheet was applied to cotton fabrics by ultrasonic spraying. With the swelling effect of ionic liquid on the cotton fiber, the surface roughness of cotton fabrics were increased, the fixed loading rate of MXene on cotton fabrics were further improved, and the oil-water separation membrane was prepared. The surface morphology and wettability of oil/water separation membrane were analyzed by scanning electron microscope and contact angle tester. The oil/water separation efficiency, flux, acid and alkali resistance and recyclability of oil/water separation membrane of MXene were tested to evaluate its performance stability in application. The results showed that the separation efficiency of MXene oil/water separation membrane based on cotton fabrics reached 99.1% and remained 98.6% after 10 repeated tests. The separation efficiency has no obvious change in the range of pH 1~13, the contact angle of water in the air is 30°, maintaining 80.1% of the strength of the original cotton fabric.

Key words: waste textiles, oil-water separation membrane, cotton fabric, two dimensional transition metal carbide(Ti3C2Tx), composite membrane, hydrophilicity

CLC Number: 

  • TS106.5

Fig.1

SEM images of cotton fabric and MXene separation membrane. (a) Cotton fabric(×150);(b) MXene separation membrane (×150);(c) Long time treatment of cotton fabric with ionic liquid(×150);(d) Cotton fabric (×10 000); (e) MXene separation membrane (×10 000)"

Fig.2

Relationship between separation efficiency, membrane flux and ionic liquid treatment temperature"

Fig.3

Relationship between separation efficiency,membrane flux and ionic liquid treatment time"

Fig.4

Comparison of oil-water separation efficiency"

Fig.5

Contact angle of cotton fabric and MXene separation membrane. (a)Water contact angle of cotton fabric in air; (b)Water contact angle of MXene separation membrane in air;(c)Oil contact angle of cotton fabric in water; (d)Oil contact angle of MXene separation membrane in water"

Fig.6

Effect of cycle times on oil/water separation efficiency and membrane flux"

Fig.7

Effect of pH value on separation efficiency and membrane flux"

Tab.1

Tensile breaking properties of cotton fabric and separation membrane"

试样 断裂强
力/N		 断裂伸
长率/%		 断裂时
间/s
原棉织物 326 8.7 5.25
MXene油水分离膜 264 27.9 16.76
酸处理后MXene油水分离膜 218 10.5 6.31
碱处理后MXene油水分离膜 246 19.4 11.64
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