纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 97-102.doi: 10.13475/j.fzxb.20180705406

• 染整与化学品 • 上一篇    下一篇

碱处理对涤纶/光敏树脂复合材料力学性能的影响

宋星, 祝成炎, 蔡冯杰, 吕智宁, 田伟()   

  1. 浙江理工大学 材料与纺织学院、 丝绸学院, 浙江 杭州 310018
  • 收稿日期:2018-07-20 修回日期:2019-03-30 出版日期:2019-07-15 发布日期:2019-07-25
  • 通讯作者: 田伟
  • 作者简介:宋星(1992-),男,硕士生。主要研究方向为基于3D打印技术的纤维增强复合材料的制备。

Influence of alkali treatment on mechanical properties of polyester/photosensitive resin composites

SONG Xing, ZHU Chengyan, CAI Fengjie, LÜ Zhining, TIAN Wei()   

  1. Silk Institute, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2018-07-20 Revised:2019-03-30 Online:2019-07-15 Published:2019-07-25
  • Contact: TIAN Wei

摘要:

针对光敏树脂经3D打印成型后试样力学性能较差问题,采用涤纶长丝增强光敏树脂的方法,使用光固化3D打印设备将涤纶长丝和光敏树脂复合成型制备涤纶增强复合材料。为获得较好的增强效果,对涤纶进行碱处理,研究了碱处理各条件下涤纶的减量率与纤维形貌和力学性能的关系,以及其对复合材料力学性能的影响。结果表明:随着减量率的增加,涤纶的形貌及力学性能改变越明显;当涤纶减量率为16.2%时,纤维表面出现连续纵向沟壑,力学强度下降6%,纤维的增强效果最好;经过改性处理的涤纶增强复合材料的拉伸强度和弯曲强度分别达到78 MPa和471 MPa,相比于未处理的纤维增强复合材料分别提升了66%和336%。

关键词: 涤纶, 光敏树脂, 3D打印, 复合材料, 碱处理, 拉伸强度, 弯曲强度

Abstract: Aim

ing at the problem of poor mechanical properties of photosensitive resin after 3D printing, the method using polyester filament to reinforce photosensitive resin was adopted to fabricate polyester reinforced composite material by composite molding of polyester filament and photosensitive resin using stereo lithography appearance equipment. In order to obtain better reinforcement effect, the polyester fiber was treated with alkali. The relationship between the alkali reduction ratio of polyester and the morphology and mechanical properties of the polyester under various alkali treatment conditions was analyzed, and its influence on the mechanical properties of the composite was measured. The results show that the morphology and mechanical properties of the fiber change more obviously with the increase of alkali reduction ratio. When the polyester alkali reduction ratio is 16.2%, continuous longitudinal gully appears on the fiber surface, and the fiber mechanical strength decreases by 6%, and the fiber reinforcing effect is the best. The tensile strength and flexural strength of the modified polyester fiber reinforced composites reach 78 MPa and 471 MPa, respectively, and the tensile strength and flexural strength increase by 66% and 336%, compared with the untreated fiber reinforced composite, respectively.

Key words: polyester fiber, photosensiltive resin, 3D printing, composite material, alkali treatment, tensile strength, flexural strength

中图分类号: 

  • TS195.5

表 1

涤纶长丝碱处理条件"

样品编号 碱质量分数/% 处理温度/℃ 处理时间/h
1# 5 70 1.5
2# 10 70 1.5
3# 15 70 1.5
4# 20 70 1.5
5# 25 70 1.5
6# 10 25 1.0
7# 10 40 1.0
8# 10 55 1.0
9# 10 70 1.0
10# 10 85 1.0
11# 5 70 0.5
12# 5 70 1.0
13# 5 70 1.5
14# 5 70 2.0
15# 5 70 2.5

图1

纤维增强光敏树脂复合材料3D打印工艺原理图"

图2

碱处理对涤纶形貌的影响"

表2

不同碱处理条件下涤纶纤维的减量率"

样品编号 减量率/% 样品编号 减量率/%
1# 4.3 9# 12.7
2# 6.1 10# 15.3
3# 10.1 11# 2.3
4# 16.2 12# 3.2
5# 25.7 13# 4.5
6# 6.1 14# 6.3
7# 8.2 15# 8.6
8# 9.6

图3

碱处理对涤纶力学性能的影响"

图4

碱质量分数对试样力学性能的影响"

图5

涤纶纤维增强光敏树脂复合材料SEM截面照片"

图6

碱处理温度对试样力学性能的影响"

图7

碱处理时间对试样力学性能的影响"

[1] 王延庆, 沈竞兴, 吴海全 . 3D打印材料应用和研究现状[J]. 航空材料学报, 2016,36(4):89-98.
WANG Yanqing, SHEN Jingxing, WU Haiquan . Application and research status of alternative materials for 3D printing technology[J]. Journal of Aeronautical Materials, 2016,36(4):89-98.
[2] 杜宇雷, 孙菲菲, 原光 , 等. 3D打印材料的发展现状[J]. 徐州工程学院学报(自然科学版), 2014,29(1):20-24.
DU Yulei, SUN Feifei, YUAN Guang , et al. Current status of materials for three-dimensional printing[J]. Journal of Xuzhou Institute of Technology(Natural Sciences Edition), 2014,29(1):20-24.
[3] 王蕾 . 3D打印材料光敏树脂的改性研究[D]. 武汉:武汉纺织大学, 2015: 9-10.
WANG Lei . Study on modification of 3D printing photosensitive resins[D]. Wuhan:Wuhan Textile University, 2015: 9-10.
[4] 权利军 . 纤维增强3D打印复合材料的制备及力学性能[D]. 杭州:浙江理工大学, 2016: 7-18.
QUAN Lijun . Preparation and mechanical properties of fiber reinforced 3D printing composites [D].Hangzhou: Zhejiang Sci-Tech University, 2016: 7-18.
[5] 翟媛萍 . 光固化快速成型材料的研究与应用[D]. 南京:南京理工大学, 2004: 7.
ZHAI Yuanping . Study and application of material in stereolithography[D]. Nanjing:Nanjing University of Science and Technology, 2004: 7.
[6] 钱波, 王明义, 刘志远 , 等. 3D打印光敏树脂的性能研究[J]. 高校化学工程学报, 2017,31(1):191-196.
QIAN Bo, WANG Mingyi, LIU Zhiyuan , et al. Research photosensitive resins for 3D printing[J]. Journal of Chemical Engineering of Chinese Universities, 2017,31(1):191-196.
[7] 丰洪微, 范哲超 . 光固化3D打印成型树脂改性与性能研究[J]. 铸造技术, 2018,39(1):166-169.
FENG Hongwei, FAN Zhechao . Modification and properties of light cured 3D printing molding resin[J]. Foundry Technology, 2008,39(1):166-169.
[8] 张济邦 . 涤纶纤维碱处理试验方法和机理探讨[J]. 宁波化工, 2003(1):41-46.
ZHANG Jibang . Experimental method and mechanism of polyester fiber alkali treatment[J]. Ningbo Chemical Industry, 2003(1):41-46.
[9] 普丹丹, 傅雅琴 . 涤纶工业丝表面改性技术研究进展[J]. 纺织科技进展, 2015(7):13-25.
PU Dandan, FU Yaqin . Research progress on surface modification technology of polyester industrial fila-ment[J]. Progress in Textile Science & Technology, 2015(7):13-25.
[10] 申晓 . 涤纶纤维表面改性处理及其复合材料性能研究[D]. 杭州:浙江理工大学, 2018: 49.
SHEN Xiao . Study on surface modification of polyester fiber and its composites performance[D]. Hangzhou: Zhejiang Sci-Tech University, 2018: 49.
[11] 郭淮政 . 化学反应速率影响因素的归纳与浅析[J]. 化工管理, 2018(5):151-157.
GUO Huaizheng . Summary and analysis of factors influencing chemical reaction rate[J]. Chemical Enterprise Management, 2018(5):151-157.
[1] 王秋萍, 张瑞萍, 李成红, 张葛成. 导电涤纶非织造布的制备及其性能[J]. 纺织学报, 2020, 41(10): 116-121.
[2] 封端佩, 商元元, 李俊. 三维四向和五向编织复合材料冲击断裂行为的多尺度模拟[J]. 纺织学报, 2020, 41(10): 67-73.
[3] 李亮, 刘静芳, 胡泽栋, 耿长军, 刘让同. 涤纶织物的氧化石墨烯负载及其抗静电性能[J]. 纺织学报, 2020, 41(09): 102-107.
[4] 马飞飞. 离散树脂成型复合材料的防刺与服用性能[J]. 纺织学报, 2020, 41(07): 67-71.
[5] 马莹, 何田田, 陈翔, 禄盛, 王友棋. 基于数字单元法的三维正交织物微观几何结构建模[J]. 纺织学报, 2020, 41(07): 59-66.
[6] 李莉萍, 吴道义, 战奕凯, 何敏. 电泳沉积碳纳米管和氧化石墨烯修饰碳纤维表面的研究进展[J]. 纺织学报, 2020, 41(06): 168-173.
[7] 刘国金, 韩朋帅, 柴丽琴, 吴钰, 李慧, 高雅芳, 周岚. 涤纶织物上自交联型P( St-NMA) 光子晶体的构筑及其结构稳固性[J]. 纺织学报, 2020, 41(05): 99-104.
[8] 陈立富, 于伟东. 人造金刚石填充聚酰亚胺树脂基复合材料防刺性能[J]. 纺织学报, 2020, 41(05): 38-44.
[9] 梁双强, 陈革, 周其洪. 开孔三维编织复合材料的压缩性能[J]. 纺织学报, 2020, 41(05): 79-84.
[10] 李鹏, 万振凯, 贾敏瑞. 基于碳纳米管纱线扭电能的复合材料损伤监测[J]. 纺织学报, 2020, 41(04): 58-63.
[11] 王晓菲, 万爱兰. 紫外线辐照聚吡咯/ 银导电涤纶织物的制备[J]. 纺织学报, 2020, 41(04): 112-116.
[12] 谭淋, 施亦东, 周文雅. 棉织物的硅溶胶疏水整理[J]. 纺织学报, 2020, 41(04): 106-111.
[13] 王建坤, 蒋晓东, 郭晶, 杨连贺. 功能化氧化石墨烯吸附材料的研究进展[J]. 纺织学报, 2020, 41(04): 167-173.
[14] 张恒宇, 张宪胜, 肖红, 施楣梧. 二维碳化物在柔性电磁吸波领域的研究进展[J]. 纺织学报, 2020, 41(03): 182-187.
[15] 王翔华, 成 玲, 张一帆, 彭海锋, 黄志文, 刘晓志. 三维机织复合材料板簧式起落架结构设计及其有限元分析[J]. 纺织学报, 2020, 41(03): 68-77.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!