纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 115-122.doi: 10.13475/j.fzxb.20200907608

• 染整与化学品 • 上一篇    下一篇

棉织物的活性染料低含水率焙蒸固色工艺

陈小文1,2, 吴伟1,2, 钟毅1,2,3, 徐红1,2,3, 毛志平1,2,3,4()   

  1. 1.东华大学 生态纺织教育部重点实验室, 上海 201620
    2.东华大学 化学化工与生物工程学院, 上海 201620
    3.东华大学 纺织科技创新中心, 上海 201620
    4.上海安诺其集团股份有限公司, 上海 201799
  • 收稿日期:2020-09-29 修回日期:2021-01-14 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 毛志平
  • 作者简介:陈小文(1996—),女,硕士生。主要研究方向为纺织品清洁染整技术。
  • 基金资助:
    国家重点研发计划项目(2017YFB0309700)

Low-moisture content baking and steaming color fixation process for cotton fabrics padded with reactive dyes

CHEN Xiaowen1,2, WU Wei1,2, ZHONG Yi1,2,3, XU Hong1,2,3, MAO Zhiping1,2,3,4()   

  1. 1. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
    3. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
    4. Shanghai ANOKY Group Co., Ltd., Shanghai 201799, China
  • Received:2020-09-29 Revised:2021-01-14 Published:2021-07-15 Online:2021-07-22
  • Contact: MAO Zhiping

RichHTML

11

PDF (PC)

46

摘要：

针对棉织物传统轧烘轧蒸染色工艺存在的能耗高、活性染料易水解、废水含盐量高和排放量大等问题,提出了利用密封装置固色的棉织物低含水率焙蒸固色工艺。通过测定密封装置中织物表面温度的变化曲线,探讨含水率对织物升温以及织物染色性能的影响,研究棉织物低含水率焙蒸固色理论。探究焙蒸温度、焙蒸时间、代用碱和Na2SO4质量浓度对棉织物低含水率焙蒸固色的影响,并且对低含水率焙蒸固色工艺与轧烘轧蒸工艺染色织物的染色效果进行了比较。结果表明:染料用量相同时,经低含水率焙蒸固色工艺染色织物的K/S值均比经轧烘轧蒸工艺染色织物的K/S值高,采用这2种工艺染色的织物耐摩擦色牢度相差较小,这为提升棉织物轧染工艺的染色性能提供了新方法。

关键词: 低含水率, 焙蒸固色, 活性染料, 棉织物, 代用碱, 轧烘轧蒸

Abstract:

To solve the problems of high energy consumption, hydrolysis of reactive dyes, high salinity and high discharge of wastewater in the conventional pad-dry-pad-steam process of cotton fabrics, a low-moisture content baking and steaming color fixation process for cotton fabrics was proposed using a sealed device. The changes of the fabric surface temperature in the sealing device were investigated,and the effects of moisture content on fabric heating and dyeing performance were discussed for theoretical analysis of low-moisture content baking and steaming color fixation for cotton fabrics. To determine the optimal technique, the effects of cotton fabrics baking and steaming temperature and time, and concentrations of substitute alkali and Na2SO4 were explored. Compared with the pad-dry-pad-steam process, the K/S value of the fabric dyed by low-moisture content baking and steaming color fixation process demonstrated an improvement. However, the rubbing fastness of cotton fabrics by the two processes was similar. Incorporating the sealing device in the pad-dye process offers a new method for improving reactive dye properties of cotton fabrics.

Key words: low-moisture content, baking and steaming color fixation, reactive dye, cotton fabric, substitute alkali, pad-dry-pad-steam

中图分类号: 

  • TS193.5

图1

密封装置示意图 注:Ⅰ为织物;Ⅱ为硅胶板;Ⅲ为钢板。"

图2

密封装置中棉织物的温度变化曲线"

图3

不同含水率棉织物在密封装置中的温度变化曲线"

图4

含水率对染色织物K/S值和染料固色率的影响 "

图5

温度对染色织物K/S值和染料固色率的影响 "

图6

时间对染色织物K/S值和染料固色率的影响 "

图7

代用碱质量浓度对染色织物K/S值和染料固色率的影响 "

图8

Na2SO4质量浓度对染色织物K/S值和染料固色率的影响 "

表1

经不同工艺染色织物的K/S值 "

染料质量浓度/
(g·L-1) 		活性红243染色织物K/S值 活性红198染色织物K/S值 活性红278染色织物K/S值
焙蒸固色
(代用碱) 		焙蒸固色
(混合碱) 		轧烘轧蒸 焙蒸固色
(代用碱) 		焙蒸固色
(混合碱) 		轧烘轧蒸 焙蒸固色
(代用碱) 		焙蒸固色
(混合碱) 		轧烘轧蒸
5 5.82 6.01 3.32 9.44 4.91 2.82 8.75 8.36 6.01
10 9.88 8.68 6.65 14.06 8.75 6.53 13.80 13.06 10.77
20 11.95 11.85 11.49 18.02 15.06 11.98 17.32 16.39 14.59
30 14.43 13.89 12.95 20.38 18.19 14.49 19.81 18.82 16.98
40 15.65 15.27 14.01 21.59 20.41 16.59 20.54 20.07 18.17
50 16.95 16.08 15.94 21.86 21.76 18.03 21.67 20.93 19.31
60 17.90 17.70 16.16 22.19 21.96 18.82 22.21 21.24 20.24

表2

经不同工艺染色织物的耐摩擦色牢度"

染色
工艺 		染料质量浓度/
(g·L-1) 		耐干摩擦色牢度/级 耐湿摩擦色牢度/级
红243 红198 红278 红243 红198 红278
焙蒸固色
(代用碱) 		10 4~5 5 5 4 4~5 4~5
30 4~5 5 4~5 3 4 4
50 4 4~5 3~4 3 3~4 3~4
焙蒸固色
(混合碱) 		10 5 5 5 4 4~5 4~5
30 5 5 4~5 4 4 3~4
50 5 5 3~4 3~4 3~4 3
轧烘轧蒸 10 5 5 4~5 4~5 4~5 4~5
30 5 5 4 4 4 3~4
50 4~5 5 4 3~4 3~4 3~4
[1] 舒大武. 基于常压饱和蒸汽介质的纤维素织物活性染料湿短蒸染色[D]. 天津: 天津工业大学, 2019: 10-11.
SHU Dawu. Wet short steaming dyeing of cellulose fabric with reactive dyes based on atmospheric pressure saturated steam medium[D]. Tianjin: Tiangong University, 2019: 10-11.
[2] WANG Lili, MA Wei, ZHANG Shufen, et al. Preparation of cationic cotton with two-bath pad-bake process and its application in salt-free dyeing[J]. Carbohydrate Polymers, 2009, 78(3):602-608.
doi: 10.1016/j.carbpol.2009.05.022
[3] 吴春燕. 纺织印染行业常见节能减排措施探讨[J]. 资源节约与环保, 2020(7):9.
WU Chunyan. Discussion on common energy saving and emission reduction measures in textile printing and dyeing industry[J]. Resource Conservation and Environmental Protection, 2020(7):9.
[4] FARIAS L. Progress in chemical foam technology for dyeing applications[J]. AATCC Review, 2013, 13(2):36-41.
[5] MAO Xiaodong, ZHONG Yi, XU Hong, et al. A novel low add-on technology of dyeing cotton fabric with reactive dyestuff[J]. Textile Research Journal, 2018, 88(12):1345-1355.
doi: 10.1177/0040517517700195
[6] ZHANG Xinqing, FANG Kuanjun, ZHANG Jianfei, et al. A vacuum-dehydration aided pad-steam process for improving reactive dyeing of cotton fabric[J]. Journal of Cleaner Production, 2017, 168(12):1193-1200.
doi: 10.1016/j.jclepro.2017.09.112
[7] 李琼, 刘忠延, 刘天强. 烘丝机筒体进出端密封材料选用[J]. 设备管理与维修, 2012(2):54-55.
LI Qiong, LIU Zhongyan, LIU Tianqiang. Selection of sealing material for inlet and outlet of dryer cylinder[J]. Plant Maintenance Engineering, 2012(2):54-55.
[8] 陈林, 王建庆. 活性染料固色率的酸溶解法和尿素剥色法测定[J]. 印染, 2015, 41(1):9-12.
CHEN Lin, WANG Jianqing. Determination of fixation of reactive dyes by acid dissolution method and urea stripping method[J]. China Dyeing & Finishing, 2015, 41(1):9-12.
[9] 王天靖, 臧少玉, 毛志平, 等. ECO型活性染料对棉织物的湿焙连续染色[J]. 纺织学报, 2010, 31(9):62-67.
WANG Tianjing, ZANG Shaoyu, MAO Zhiping, et al. Continuous dyeing of cotton with ECO reactive dyes followed by shortened wet-steaming process[J]. Journal of Textile Research, 2010, 31(9):62-67.
[10] 宋心远. 纤维素纤维纺织品活性染料轧染理论和工艺:二[J]. 印染, 2007(24):42-46,51.
SONG Xinyuan. Theories and processes of pad dyeing of cellulosic textiles with reactive dyestuffs: Ⅱ[J]. China Dyeing & Finishing, 2007(24):42-46,51.
[11] MAO Zhiping, YU Hong, WANG Yuanfeng, et al. States of water and pore size distribution of cotton fibers with different moisture ratios[J]. Industrial & Engineering Chemistry Research, 2014, 53(21):8927-8934.
doi: 10.1021/ie501071h
[12] WANG Huan, KONG Han, ZHENG Jie, et al. Systematically exploring molecular aggregation and its impact on surface tension and viscosity in high concentration solutions[J]. Molecules, 2020, 25(7):1-9.
doi: 10.3390/molecules25010001
[13] GORENEK M. Dye-fibre bond stabilities of some reactive dyes on cotton[J]. Dyes and Pigments, 1999, 40(2):225-233.
doi: 10.1016/S0143-7208(98)00052-7
[14] 张鑫卿, 张健飞, 房宽峻, 等. 应用活性蓝19的棉织物低含水率-湿蒸染色工艺[J]. 纺织学报, 2017, 38(2):129-133.
ZHANG Xinqing, ZHANG Jianfei, FANG Kuanjun, et al. Low-water content wet-steaming fixation of cotton fabric padded with reactive blue 19[J]. Journal of Textile Research, 2017, 38(2):129-133.
[15] 田恬, 冒亚红, 管宇. 安诺素ECO型活性染料对纯棉绒类织物的染色工艺[J]. 纺织学报, 2011, 32(2):79-83.
TIAN Tian, MAO Yahong, GUAN Yu. Dyeing process of Anozol ECO reactive dyes on cotton pile fabrics[J]. Journal of Textile Research, 2011, 32(2):79-83.
[16] 吴伟, 陈小文, 钟毅, 等. 硫酸钠在低带液轧-焙-蒸活性染料染色中的作用[J]. 纺织学报, 2020, 41(5):85-93.
WU Wei, CHEN Xiaowen, ZHONG Yi, et al. Role of sodium sulfate in low add-on pad-cure-steam reactive dyeing process[J]. Journal of Textile Research, 2020, 41(5):85-93.
[17] QI Haisong, CHANG Chunyu, ZHANG Lina. Effects of temperature and molecular weight on dissolution of cellulose in NaOH/urea aqueous solution[J]. Cellulose, 2008, 15(6):779-787.
doi: 10.1007/s10570-008-9230-8
[1] 郭恒, 黄宏博, 姚金波, 姜会钰, 夏治刚, 王运利. 家庭洗涤对免烫棉织物性能的影响[J]. 纺织学报, 2021, 42(07): 129-136.
[2] 张华, 张杰, 高燕. 液氨处理对锦纶/棉混纺织物性能的影响[J]. 纺织学报, 2021, 42(06): 128-132.
[3] 赵永芳, 钱建华, 孙丽颖, 彭慧敏, 梅敏. 银纳米线改性棉织物的制备及其性能[J]. 纺织学报, 2021, 42(05): 115-121.
[4] 马亚男, 沈军炎, 骆晓蕾, 张聪, 尚小磊, 刘琳, KRUCINSKA Izabella, 姚菊明. 高效无卤阻燃棉织物的制备及其结构与性能[J]. 纺织学报, 2021, 42(03): 122-129.
[5] 武守营, 张琳萍, 徐红, 钟毅, 毛志平. 金属配合物催化棉织物低温漂白研究进展[J]. 纺织学报, 2021, 42(03): 27-35.
[6] 郝尚, 谢源, 翁佳丽, 张维, 姚继明. 溶解刻蚀辅助构建棉织物超疏水表面[J]. 纺织学报, 2021, 42(02): 168-173.
[7] 徐保律, 吴伟, 钟毅, 徐红, 毛志平. 有机溶剂对液体活性染料分散和水解稳定性影响的模拟研究[J]. 纺织学报, 2021, 42(02): 113-121.
[8] 何雪梅, 冒海燕, 蔡露. 壳聚糖基杂化气凝胶对活性染料的吸附性能[J]. 纺织学报, 2021, 42(02): 148-155.
[9] 蔡露, 康佳良, 吕存, 何雪梅. 自交联氟化聚丙烯酸酯乳液的制备及其应用性能[J]. 纺织学报, 2021, 42(02): 161-167.
[10] 侯文双, 闵洁, 纪峰, 张建祥, 苏梦, 何瑞娴. 织物紧度和抗皱整理工艺对纯棉机织物折皱回复性的影响[J]. 纺织学报, 2021, 42(01): 118-124.
[11] 鲁鹏, 洪思思, 林旭, 李慧, 刘国金, 周岚, 邵建中, 柴丽琴. 活性染料/聚苯乙烯复合胶体微球的制备及其在桑蚕丝织物上的结构生色[J]. 纺织学报, 2021, 42(01): 90-95.
[12] 曾凡鑫, 秦宗益, 沈玥莹, 陈园余, 胡铄. 自熄性棉织物的喷涂辅助层层自组装法制备及其阻燃性能[J]. 纺织学报, 2021, 42(01): 103-111.
[13] 张艳艳, 詹璐瑶, 王培, 耿俊昭, 付飞亚, 刘向东. 用无机纳米粒子制备耐久性抗菌棉织物的研究进展[J]. 纺织学报, 2020, 41(11): 174-180.
[14] 王博, 凡力华, 原韵, 殷允杰, 王潮霞. 可拉伸聚吡咯/棉针织物的制备及其储电性能[J]. 纺织学报, 2020, 41(10): 101-106.
[15] 李庆, 管斌斌, 王雅, 刘天卉, 张洛红, 樊增禄. 光敏剂敏化Cu-有机骨架对活性深蓝K-R的高效光催化降解[J]. 纺织学报, 2020, 41(10): 87-93.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发