Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (04): 90-96.doi: 10.13475/j.fzxb.20210202807

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics

WANG Dongwei1,2, FANG Kuanjun1,3,4(), LIU Xiuming1, ZHANG Xinqing5, AN Fangfang1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    3. State Key Laboratory for Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China
    4. Eco-Textiles Collaborative Innovation Center of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
    5. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
  • Received:2021-02-09 Revised:2022-01-11 Online:2022-04-15 Published:2022-04-20
  • Contact: FANG Kuanjun E-mail:13808980221@163.com

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Abstract:

In view of the problems that hydrolysis of reactive dyes leads to low utilization and environmental pollution, nanospheres were prepared by using ethylenediamine modified Reactive Red 195/polymer. The influence of initial bath pH value, mass fraction of ethylenediamine, temperature and time on the size and Zeta potential of amino-modified Reactive Red 195/polymer nanospheres were discussed, and the K/S values and color parameters of the cationic cotton fabrics dyed with the amino-modified Reactive Red 195/polymer nanospheres under the optimal conditions were investigated. The results show that the amino-modified Reactive Red 195/polymer nanospheres with an average hydration diameter of 96.5 nm, polydispersity index of 0.075 and Zeta potential of -33.7 mV were fabricated after modified with ethylenediamine under the conditions of the initial pH value 11, the mass fraction of ethylenediamine 40%, 60 ℃ for 120 min. The K/S value of the cationic cotton fabric dyed with the amino-modified Reactive Red 195/polymer nanospheres reaches up to 9.3, which is 3.1 times higher than the K/S value of the cotton fabric dyed with same dosage of Reactive Red 195, with improvement of color saturation. The rubbing and washing color fastness of dyed cotton fabrics are both equal to or higher than grade 4.

Key words: reactive dye, colored polymer nanosphere, cationic modification, cotton fabric dyeing

CLC Number: 

  • TS193.2

Fig.1

Effect of pH value on size and Zeta potential of amino-modified color polymer nanospheres"

Fig.2

Effect of ethylenediamine mass fraction on size and Zeta potential of amino-modified color polymer nanospheres"

Fig.3

Effect of temperature on size and Zeta potential of amino-modified color polymer nanospheres"

Tab.1

Effect of time on size and Zeta potential of amino-modified color polymer nanospheres"

改性时间/min 粒径/nm Zeta电位/mV
120 99.0 -34.1
240 97.7 -37.4

Fig.4

FT-IR spectra of ploymer nanospheres"

Fig.5

XPS spectra of ploymer nanospheres"

Tab.2

Analysis of polymer nanosphere surface elements"

聚合物微球 结合能/eV 元素含量/% 元素含量比
C1s O1s N1s C1s O1s N1s O与C含量比 N与C含量比
彩色微球 284.8 531.2 400.1 73.14 18.81 2.72 0.26 0.04
胺化彩色微球 78.54 13.57 4.36 0.17 0.06

Tab.3

Color values of dyed cotton fabrics"

色素 染料用量/
%(o.w.f)		 K/S
值		 L* a* b* C* h0
胺化彩
色微球		 0.5 1.9 62.7 42.5 -9.2 43.5 347.8
0.9 5.3 51.9 53.5 -7.0 54.0 352.6
1.4 9.3 46.9 57.9 -4.6 58.1 355.5
活性
染料		 0.5 1.3 67.1 40.0 -10.0 41.2 346.0
0.9 2.2 61.7 46.2 -10.3 47.3 347.4
1.4 3.0 58.4 49.5 -9.8 50.5 348.8

Fig.6

SEM images of cationic cotton fibers dyed with amino-modified color nanospheres at different magnification"

Tab.4

Color fastness of dyed cotton fabrics"

色素 染料用量/
%(o.w.f)		 耐摩擦色牢度/级 耐皂洗色牢度/级
干 湿 棉沾 毛沾 变色
胺化彩
色微球		 0.5 4 ~ 5 4 5 5 4 ~ 5
0.9 4 ~ 5 4 5 5 4 ~ 5
1.4 4 ~ 5 4 5 5 4
活性
染料		 0.5 5 4 ~ 5 5 5 4 ~ 5
0.9 4 ~ 5 4 5 5 4 ~ 5
1.4 4 ~ 5 4 5 5 4 ~ 5
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