Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 83-88.doi: 10.13475/j.fzxb.20210206706

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of ozone plasma pretreatment on dyeing properties of aramid fibers

GUO Yafei, LIANG Gaoyong, WANG Meihui, HAO Xinmin()   

  1. Systems Engineering Institute, Academy of Military Sciences, Beijing 100010, China
  • Received:2021-02-26 Revised:2022-07-18 Online:2022-10-15 Published:2022-10-28
  • Contact: HAO Xinmin E-mail:xminhao@126.com

RichHTML

11

PDF (PC)

57

Abstract:

In order to solve the problem that aramid fiber is difficult to dye and print by conventional process, the aramid fabric was pretreated by ozone plasma and then modified by resin. The influence of plasma pretreatment on the surface elements and morphology of resin modified aramid fiber was studied, and the dyeing effect of modified aramid fabric with disperse dyes was explored. It was found that ozone plasma pretreatment introduced abundant active groups and constructed rough interface, which significantly improved the uniform dispersion of resin, and the bonding strength between resin and fabric increased by 104%. At the same time, the dye uptake (98.6%) and apparent dyeing depth (2.7) of aramid fabric were greatly improved. The color fastness of the dyed fabric has been effectively improved, and the color fastness to friction can meet the requirements of clothing fabrics. The modification of aramid fiber with resin pretreated by ozone plasma has certain reference significance for improving the dyeing properties of aramid fibers.

Key words: aramid fiber, dyeing, plasma, pretreatment, resin modification

CLC Number: 

  • TS193

Fig.1

Dyeing process curve"

Fig.2

SEM images of aramid fabric. (a)Fabric before pretreatment(×500); (b)Fabric after pretreatment(×500); (c)Fabric before pretreatment(×5 000); (d)Fabric after pretreatment(×5 000)"

Tab.1

Content of elements on surface of aramid fabric%"

试样 C N O
预处理前 75.13 3.38 21.49
预处理后 59.57 5.15 35.28

Fig.3

Electronic energy spectra of aramid fiber sample. (a) Full spectra; (b) N1s spectra;(c) C1s spectra; (d) O1s spectra"

Fig.4

Effect of ozone plasma treatment time on quality (a) and capillary effect (b)of aramid fabric"

Fig.5

SEM images of fabrics modified by polyurethane resin. (a)Aramid fabric before pretreatment(×3 000);(b) Aramid fabric after pretreatment(×2 000)"

Tab.2

Dyeing properties of different fabrics before and after modification"

试样 上染率/% 反射率/% K/S值 耐摩擦色牢度/级 耐皂洗色
牢度/级		 耐光色
牢度/级
干摩 湿摩 变色 棉沾
未处理 52.1 43.3 0.4 3 4 4 3~4 3
臭氧等离子体预处理 55.6 41.4 0.6 4 4~5 4 3~4 3
臭氧等离子体预处理+环氧树脂改性 98.3 22.0 2.7 5 4~5 4 3~4 3
臭氧等离子体预处理+聚氨酯改性 98.6 21.5 2.4 5 4~5 4 3~4 3~4
[1] 尉霞, 逯凯美, 董晓宁. 间位芳纶织物的导汗排湿整理[J]. 纺织学报, 2018, 39(5): 80-86.
WEI Xia, LU Kaimei, DONG Xiaoning. Moisture absorption and sweat transport finishing of meta-aramid fabrics[J]. Journal of Textile Research, 2018, 39(5): 80-86.
[2] 牟浩蕾, 解江, 裴惠, 等. 芳纶织物及其包容环的弹道冲击与数值模拟[J]. 纺织学报, 2021, 42(11): 56-64.
MOU Haolei, XIE Jiang, PEI Hui, et al. Ballistic impact tests and numerical simulation of aramid fabric and containment ring[J]. Journal of Textile Research, 2021, 42(11): 56-64.
[3] MOHAMMAD T I, FRANCESCO A, ADA F, et al. Use of N-methylformanilide as swelling agent for meta-aramidfibers dyeing: kinetics and equilibrium adsorption of Basic Blue 41[J]. Dyes and Pigments, 2015, 113: 554-561.
doi: 10.1016/j.dyepig.2014.08.029
[4] 林琳, 于俊荣, 陈蕾, 等. 未干聚对苯二甲酰对苯二胺纤维的染色工艺[J]. 纺织学报, 2015, 36(8): 84-88.
LIN Lin, YU Junrong, CHEN Lei, et al. Dyeing process of undried poly(p-phenyleneterephthamide) fibers[J]. Journal of Textile Research, 2015, 36(8): 84-88.
[5] 王懽, 李少萍, 张建春. 芳纶1313染色性能研究[J]. 纺织学报, 2002, 23(1): 15-17.
WANG Huan, LI Shaoping, ZHANG Jianchun. Study on dyeing property of aramid 1313[J]. Journal of Textile Research, 2002, 23(1): 15-17.
[6] ZHANG Cong, JIANG Yaoxing, SUN Jianping, et al. Investigation of the influence of supercritical carbon dioxide treatment onmeta-aramid fiber: thermal decomposition behavior and kinetics[J]. Journal of CO2 Utilization, 2020, 37: 85-96.
[7] 宋欢. 间位芳纶树脂合成及纺丝[D]. 长沙: 国防科学技术大学, 2016: 1-2.
SONG Huan. Synthesis and spinning of meta-aramid resin[D]. Changsha: National University of Defense Technology, 2016: 1-2.
[8] SHENG Dan, DENG Bo, CAO Genyang, et al. Improved dyeing of poly-m-phenyleneisophthalamide using cationic dyebased on macro-cation dyeing mechanism[J]. Dyes and Pigments, 2019, 163: 111-117.
doi: 10.1016/j.dyepig.2018.11.053
[9] 梁冰. 可染间位芳纶的制备及性能研究[D]. 上海: 东华大学, 2018: 2-4.
LIANG Bing. Study on preparation and properties of dyeable PMIA fiber[D]. Shanghai: Donghua University, 2018: 2-4.
[10] 司帅. 芳纶纤维的表面改性及其性能研究[D]. 武汉: 武汉理工大学, 2015: 18-19.
SI Shuai. The study of surface modification of aramid fiber and its properties[D]. Wuhan: Wuhan University of Technology, 2015: 18-19.
[11] EUNMI K, JAEHONG C. Dyeing properties and color fastness of 100% meta-aramid fiber[J]. Fibers and Polymers, 2011, 12: 484-490.
doi: 10.1007/s12221-011-0484-7
[12] LI Na, ZHANG Xingke, YU Junrong, et al. Synthesis and characterization of easily colored meta-aramid copolymer containing ether bonds[J]. Chinese Journal of Polymer Science, 2019, 37:227-234.
doi: 10.1007/s10118-019-2200-9
[13] DONG Yuanyuan, JANG Jinho. The enhanced cationic dyeability of ultraviolet/ozone-treated meta-aramid fabrics[J]. Coloration Technology, 2011, 127(3):173-178.
doi: 10.1111/j.1478-4408.2011.00295.x
[14] 郭亚飞, 梁高勇, 张旭东, 等. 树脂表面改性国产间位芳纶的染色工艺和性能研究[J]. 印染, 2021(5): 27-30.
GUO Yafei, LIANG Gaoyong, ZHANG Xudong, et al. Dyeing behaviors of domestic meta aramid fiber surface modified by resin[J]. China Dyeing & Finishing, 2021(5): 27-30.
[15] 郭亚飞, 梁高勇, 郝新敏, 等. 一种芳纶纤维布的染色性能改进方法: 202110149255.4[P]. 2021-02-01.
GUO Yafei, LIANG Gaoyong, HAO Xinmin, et al. An improved method for dyeing properties of aramid fiber cloth: 202110149255.4[P]. 2021-02-01.
[1] ZHENG Linjuan, YU Jia, YIN Chong, LIANG Zhijie, MAO Qinghui. Preparation and photocatalytic properties of cotton fabrics loaded with polymetallic organic framework material [J]. Journal of Textile Research, 2022, 43(10): 106-111.
[2] ZHOU Xiaoju, HU Zhenglong, REN Yiming, XIE Landong. Fabrication and photocatalyic performance of Bi2MoO6 modified TiO2 nanorod array photocatalyst [J]. Journal of Textile Research, 2022, 43(10): 97-105.
[3] FU Zheng, LI Min, HE Yingting, WANG Chunxia, FU Shaohai. Preparation of nanoscale capsulated disperse dyes and their washing-free dyeing performance [J]. Journal of Textile Research, 2022, 43(09): 129-136.
[4] WU Le, ZHANG Qian, YANG Wanran, XU Zhaoyue, WANG Weiguan, HOU Xi. Research on operation-maintenance-patrol-inspection system of yarn package dyeing latch locking robot based on augmented reality technology [J]. Journal of Textile Research, 2022, 43(09): 34-40.
[5] WANG Jing, LOU Yaya, WANG Chunmei. Preparation and decolorization of iron-based metal\|organic framework/activated carbon fiber composites [J]. Journal of Textile Research, 2022, 43(08): 126-131.
[6] SUN Ying, LI Duanxin, YU Yang, CHEN Jialin, FAN Wanyue. Degumming of hemp fibers using Fenton method and fiber properties [J]. Journal of Textile Research, 2022, 43(08): 95-100.
[7] ZHANG Yaning, ZHANG Hui, SONG Yueyue, LI Wenming, LI Wenjun, YAO Jiale. Preparation of discarded mask-based ZIF-8/Ag/TiO2 composite and its photocatalytic property for dye degradation [J]. Journal of Textile Research, 2022, 43(07): 111-120.
[8] GAO Luxi, LÜ Xuechuan, ZHANG Chi, SONG Hanlin, GAO Xiaohan. Synthesis and decolorizing performance of modified flocculant for treating dyeing wastewater [J]. Journal of Textile Research, 2022, 43(07): 121-128.
[9] CHEN Peng, LIAO Shihao, SHEN Lanping, WANG Xuan, WANG Peng. Dyeing properties of polylactic acid/polyketone fibers with disperse dye [J]. Journal of Textile Research, 2022, 43(05): 12-17.
[10] LIU Yu, XIE Ruyi, SONG Yawei, QI Yuanzhang, WANG Hui, FANG Kuanjun. One-bath pad dyeing technology for polyester/cotton fabric [J]. Journal of Textile Research, 2022, 43(05): 18-25.
[11] WANG Dongwei, FANG Kuanjun, LIU Xiuming, ZHANG Xinqing, AN Fangfang. Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics [J]. Journal of Textile Research, 2022, 43(04): 90-96.
[12] WANG Ju, ZHANG Liping, WANG Xiaochun, YANG Mengyang. Preparation of highly hydrophobic dyes and their dyeing of ultra-high molecular weight polyethylene fabric [J]. Journal of Textile Research, 2022, 43(04): 97-101.
[13] HE Yang, ZHANG Ruiping, HE Yong, FAN Aimin. Dyeing properties of laser modified polyester fabrics with disperse dyes [J]. Journal of Textile Research, 2022, 43(04): 102-109.
[14] HE Yingting, LI Min, FU Shaohai. Preparation and reduction-oxidation process of indigo dispersant [J]. Journal of Textile Research, 2022, 43(04): 84-89.
[15] HE Yingting, LI Min, WANG Ruifeng, WANG Chunxia, FU Shaohai. Dyeing process for polyester fabrics with continuous pad dyeing method [J]. Journal of Textile Research, 2022, 43(03): 110-115.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd