Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (05): 12-17.doi: 10.13475/j.fzxb.20211206506

• Invited Column: Expert Opinion of the 11th China Textile Academic Conferenc • Previous Articles     Next Articles

Dyeing properties of polylactic acid/polyketone fibers with disperse dye

CHEN Peng1(), LIAO Shihao1,2,3, SHEN Lanping2, WANG Xuan3, WANG Peng1   

  1. 1. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201,China
    2. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shanxi 710048, China
    3. School of Textiles, Zhejiang Fashion Institute of Technology, Ningbo, Zhejiang 315211, China
  • Received:2021-12-30 Revised:2022-02-21 Online:2022-05-15 Published:2022-05-30

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Abstract:

To improve dyeing performance of polylactic acid (PLA) fibers, Disperse Blue 79 was used to dye polylactic acid/polyketone (PLA/PK) blend fibers. The influence of dyeing temperature, time, pH value and other factors were investigated, with the dyeing kinetics and thermodynamic behavior analyzed. The optimal processing parameters were identified, which are dyeing temperature of 110 ℃, holding time of 40 min, and pH value of 5. With increased PK content, the K/S value of the blend fibers increases significantly and the color fastness to rubbing and soaping remains over level 3,the equilibrium adsorption amount of Disperse Blue 79 dye on the blend fiber increases, the half dyeing time decreases, and the diffusion coefficient increases, further confirming the improved dyeing properties of the blend fiber. The adsorption isotherms of Disperse Blue 79 dye to PLA fiber and blended fibers are calculated by fitting, showing a composite curve of Nernst and Langmuir.

Key words: polylactic acid fiber, polylactic acid/polyketone blend fiber, disperse dye, kinetics, dyeing, thermodynamics

CLC Number: 

  • TS190.6

Fig.1

Fiber dyeing process curve"

Fig.2

Effect of dyeing temperature on K/S value of PLA/PK blend fibers"

Fig.3

Effect of time on K/S value of PLA/PK blend fibers"

Fig.4

Effect of pH value on the K/S value of PLA/PK blend fibers"

Tab.1

"

纤维
编号		 耐摩擦色牢度 耐皂洗色牢度
干 湿 变色 沾色
B0 4~5 4~5 4~5 4
B1 4~5 4~5 3 4
B2 4~5 4~5 3 4~5
B4 5 4~5 3~4 4~5

Fig.5

Dyeing curve of Disperse Blue 79 on PLA/PK blend fibers"

Fig.6

DSC curves of PLA/PK blend fibers"

Fig.7

Quasi-second-order kinetic linear fitting curve of PLA/PK blend fibers dyed with Disperse Blue 79"

Tab.2

Dyeing kinetic parameters of PLA/PK blend fibers with Disperse Blue 79"

纤维编号 拟合方程 线性拟合度R2 平衡吸附量/(mg·g-1) 染色速率常数/(min·g·mg-1) 半染时间/min
B0 y=0.055 3x+0.906 4 0.994 6 18.083 0.003 4 16.265
B4 y=0.042 7x+0.648 4 0.991 2 23.43 0.002 8 15.247

Fig.8

Micrograph of B0(a), B4(b) and radius of fiber(c)"

Fig.9

Adsorption isotherm of Disperse Blue 79 on fibers at 110 ℃"

Fig.10

Adsorption model of Disperse Blue 79 on fibers"

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