纺织基柔性染料敏化太阳能电池的研究进展

doi:10.13475/j.fzxb.20210301910

Abstract

Abstract:

Solar energy is one of the effective solutions for the energy problem. Flexible solar cells can solve the power supply problem for wearable devices, and at the same time can facilitate the integration with clothing. In order to comprehensively explore the application prospects of textile-based flexible dye-sensitized solar cells, the development status, composition structure, working mechanism and performance evaluation of dye-sensitized solar cells were reviewed, focusing on the research results of flexible fibrous batteries and textile-based planar batteries, and on analysis of the characteristics of electrode preparation and battery assembly methods. The review also pointed out the unresolved problems in the textile field, and also summarized the development process in textile-based flexible dye-sensitized solar cell electrolytes and sensitizing dyes. It is concluded that the prospect of the development of textile-based flexible dye-sensitized solar cells was put forward.

Key words: dye-sensitized solar cells, textile-based, electrode material, fabric coating, fiber

CLC Number:

TM914.4

HAN Yijun, XU Jun, CHANG Qiqi, ZHANG Cheng. Research progress in textile-based flexible dye-sensitized solar cells[J].Journal of Textile Research, 2022, 43(05): 185-194.

Figures/Tables 5

Fig.1

Fig.2

Fig.3

Tab.1

Summary of photovoltaic parameters of flexible fibrous dye-sensitized solar cells"

电池形态	电池材料组成	电极材料制备方法	短路电流/ (mA·cm^-2)	开路电压/V	影响因子F	光电转化效率/%	参考文献
线状	钛丝/TiO₂/N719/I^-- $I 3 -$ /铂丝	涂覆法	11.06	0.734	0.672	5.41	[13]
	碳纳米管丝/TiO₂/N719/I^-- $I 3 -$ /碳纳米管丝	化学浴沉积法	—	—	—	7.6	[15]
	碳纳米管丝/N719/I^-- $I 3 -$ /碳纳米管/聚偏氟乙烯丝	化学气相沉积法	9.84	0.69	0.57	3.90	[18]
	碳纳米管丝/TiO₂/N719/I^-- $I 3 -$ /碳纳米管丝	涂覆法	—	—	—	2.94	[19]
网状	钛丝/TiO₂/N719/I^-- $I 3 -$ /多壁碳纳米管丝	化学气相沉积法	16.0	0.71	0.61	7.13	[20]
缎纹网状	不锈钢丝/ZnO/N719/固体电解质/Pt/不锈钢丝	水热合成法	20.2	0.45	0.28	2.57	[17]

Tab.1

Tab.2

Summary of photovoltaic parameters of dye-sensitized solar cells on flexible fabric substrates"

电池形态	电池材料组成	电极材料制备方法	短路电流/ (mA·cm^-2)	开路电压/V	影响因子FF	光电转化效率/%	参考文献
全柔平面	玻璃纤维织物/PA层/Ti/TiO₂/染料/电解质/聚萘二甲酸乙二醇酯/Pt/ITO	丝网印刷高温烧结	5.7	0.71	0.541	1.8	[24]
	机织涤纶/棉(65/35)面料/导电银浆/Ruthenizer 535-bisTBA染料敏化剂/I^-- $I 3 -$ /石墨/ITO	丝网印刷低温工艺	9.6	0.67	0.50	3.24	[27]
	玻璃纤维织物/导电银浆/TiO₂/Ruthenizer 535-bisTBA染料敏化剂/I^-- $I 3 -$ /石墨/ITO	丝网印刷低温工艺	10.24	0.73	0.54	4.04	[27]
	镀锡铜丝制成的金属微丝纺织品/TiO₂/N3/I^-- $I 3 -$ /Pt/聚乙烯薄膜	涂覆法高温烧结	0.84	0.41	0.57	0.20	[28]
	不锈钢(SUS304)金属织物/TiO₂/N719/I^-- $I 3 -$ /Pt/活性碳粉/不锈钢金属网	丝网印刷热处理	—	—	—	2.63	[29]
	不锈钢(SUS304)金属织物/TiO₂/N719/I^-- $I 3 -$ /Pt/活性碳粉/不锈钢金属网	浮动印刷热处理	6.32	0.792	0.67	4.16	[30]
	304不锈钢网/TiO₂/N719/ I^-- $I 3 -$ /Pt/不锈钢网/丝绸	电镀沉积	19.70	0.69	0.43	5.8	[31]
半柔平面	标准涤纶/棉(65/35)织物/导电银浆/TiO₂/N719/I^-- $I 3 -$ /Pt/FTO	丝网印刷低温工艺	36.56	0.3	0.25	2.78	[26]
	纸质基材/Ni/ZnO/N719/I^-- $I 3 -$ /Pt/FTO	刮涂法	6.70	0.56	0.33	1.21	[33]
	FTO/TiO₂/N719/I^-- $I 3 -$ /氧化石墨烯/棉织物	涂覆法	9.08	0.64	0.429 7	2.52	[32]
	FTO/TiO₂/D719/I^-- $I 3 -$ /多壁碳纳米管涂层/涤纶织物	流延法空气干燥	11.92	0.688	0.693 9	5.69	[33]
	FTO/TiO₂/N719/I^-- $I 3 -$ /活性炭掺杂多壁碳纳米管/涤纶机织物	刮涂法空气干燥	12.03	0.766	0.790 3	7.29	[34]
	FTO/TiO₂/N719/凝胶电解质/多壁碳纳米管/介孔活性炭/棉织物	刮涂法	12.3	0.72	0.685	6.06	[35]
	FTO/TiO₂/N719/凝胶电解质/多壁碳纳米管/介孔活性炭/涤纶织物	刮涂法	12.4	0.72	0.701 9	6.26	[35]
	FTO/TiO₂/N719/凝胶电解质/多壁碳纳米管/介孔活性炭/亚麻面料	刮涂法	12.7	0.73	0.626 2	5.80	[35]
	FTO/TiO₂/N719/I^-- $I 3 -$ /活性炭/石墨烯/莱赛尔织物/聚对苯二甲酸乙二醇酯	涂覆法	15.5	0.73	0.628	7.09	[36]
	FTO/TiO₂/N719/I^-- $I 3 -$ /聚吡咯/镀镍织物	涂覆法	7.85	0.74	0.66	3.83	[40]
	FTO/TiO₂/N719/I^-- $I 3 -$ /聚苯胺/碳纤维织物	涂覆法	12.1	0.675	0.47	3.81	[41]
硬质平面	FTO/ TiO₂/Dye/I^-- $I 3 -$ /石墨烯/棉织物/FTO	涂覆法	14.75	0.66	0.709 2	6.93	[37]
硬质平面	FTO/ZnO/N719/I^-- $I 3 -$ /活性炭布/FTO	原子沉积	14.03	0.7499	0.655	6.88	[39]

Tab.2

References 48

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