Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (04): 68-73.doi: 10.13475/j.fzxb.20201205106

• Textile Engineering • Previous Articles     Next Articles

Effect of silane coupling agent modification on properties of glass fiber fabric reinforced polyphenylene sulfide composites

SHAO Lingda, HUANG Jinbo, JIN Xiaoke, TIAN Wei, ZHU Chengyan()   

  1. Key Laboratory for Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2020-12-18 Revised:2022-01-19 Online:2022-04-15 Published:2022-04-20
  • Contact: ZHU Chengyan E-mail:cyzhu@zstu.edu.cn

RichHTML

27

PDF (PC)

122

Abstract:

To solve the problem of poor toughness of polyphenylene sulfide, glass fiber reinforced polyphenylene sulfide composites were prepared by mixing glass fiber fabrics with polyphenylene sulfide through hot pressing. In order to obtain better interfacial bonding properties, silane coupling agent KH560 was used to modify the surface of glass fiber. By means of scanning electron microscope, pendulum impact tester and universal tester, the changes of surface morphology of glass fiber treated with different concentrations of silane coupling agent KH560 and its effect on the mechanical properties of the composites were studied. The results show that when the mass fraction of the silane coupling agent KH560 is 2%, the glass fiber and the polyphenylene sulfide matrix achieves the best bonding, and the tensile strength, flexural strength and impact strength of the modified glass fiber reinforced composite reach 51.9 MPa, 78 MPa and 39.6 kJ/m2 respectively, representing increases of 57.8%, 51.8% and 48.3% compared with untreated.

Key words: glass fiber, polyphenylene sulfide, silane coupling agent, composite, modification, mechanical property

CLC Number: 

  • TS15

Fig.1

Hot pressing diagram"

Fig.2

Effect of silane coupling agent KH560 treatment on morphology of glass fiber fabric"

Fig.3

Mechanism schematic of reaction between silane coupling agent KH560 and glass fiber fabric. (a)Hydrolysis of silane coupling agent; (b)Polycondensation to form oligomeric siloxane;(c)Water lose of oligosiloxane and glass fiber fabric to form covalent bond"

Tab.1

Fabric weight gain rate treated with different mass fraction of silane coupling agent KH560%"

KH560质量分数 质量增加率
0
1 0.37
2 0.52
3 0.85
4 0.93

Fig.4

Tensile strength of fabric treated with different mass fraction of silane coupling agent KH560"

Fig.5

SEM cross-sectional images of glass fiber fabric reinforced polyphenylene sulfide composite"

Fig.6

Mechanism of reaction between silane coupling agent and polyphenylene sulfide"

Fig.7

Effect of KH560 mass fraction on mechanical properties of composites. (a)Tensile properties; (b)Impact properties;(c)Bending properties"

[1] CHEN G, MOHANTY A K, MISRA M. Progress in research and applications of polyphenylene sulfide blends and composites with carbons[J]. Composites Part B: Engineering, 2020, 209(434): 108553.
doi: 10.1016/j.compositesb.2020.108553
[2] 刘强飞, 吴韶华, 杨吉震, 等. 芳纶纳米纤维改性聚四氟乙烯/聚苯硫醚针刺毡的制备及其性能[J]. 纺织学报, 2021, 42(10): 47-52.
LIU Qiangfei, WU Shaohua, YANG Jizhen, et al. Preparation and properties of polytetrafluoroethylene/phenylene sulfide needled felt modified by aramid nanofiber[J]. Journal of Textile Research, 2021, 42(10): 47-52.
[3] LOHR C, BECK B, HENNING F, et al. Mechanical properties of foamed long glass fiber reinforced polyphenylene sulfide integral sandwich structures manufactured by direct thermoplastic foam injection molding[J]. Composite Structures, 2019, 220: 371-385.
doi: 10.1016/j.compstruct.2019.03.056
[4] XIA Y, SUN Y H, AN Y L, et al. Preparation and properties of polyphenylene sulfide composite enhanced by CNTs/carbon fibers[J]. Chemistry and Adhesion, 2015, 37(1): 11-14.
[5] ZHAO L, HUANG Z, XIONG S, et al. Polyphenylene sulfide composite laminate from flexible nonwovens and carbon fiber fabrics prepared by thermal lamination and thermal treatment[J]. Polymer Bulletin, 2019, 76(11): 5633-3648.
doi: 10.1007/s00289-018-2667-5
[6] IVANOV V B, SOLINA E V, SAMORYADOV A V. The effect of irradiation conditions on photodegradation of a impact resistant polyphenylene sulfide-based composite[J]. Polymer Science Series D, 2020, 13(3): 353-357.
doi: 10.1134/S1995421220030089
[7] 杨桂生, 刘明昌. 一种聚苯硫醚/尼龙合金材料及其制备方法: 201310097914.X[P]. 2014-10-01.
YANG Guisheng, LIU Mingchang. A polyphenylene sulfide/nylon alloy material and its preparation method: 201310097914.X[P]. 2014-10-01.
[8] PANNEERSELVAM K, ARAVINDAN S, HAQ A N. Study on resistance welding of glass fiber reinforced thermoplastic composites[J]. Materials & Design, 2012, 41(10): 453-459.
doi: 10.1016/j.matdes.2012.05.025
[9] 李方舟. 短切玻纤增强聚苯硫醚复合材料的制备与性能研究[D]. 青岛:青岛科技大学, 2017: 4-8.
LI Fangzhou. Preparation and properties of chopped glass fiber reinforced polyphenylene sulfide compo-sites[D]. Qingdao: Qingdao University of Science and Technology, 2017: 4-8.
[10] 常青. 聚苯硫醚树脂合成的实验研究[D]. 兰州:兰州大学, 2016: 5-8.
CHANG Qing. Experimental study on the synthesis of polyphenylene sulfide resin[D]. Lanzhou: Lanzhou University, 2016: 5-8.
[11] 宋星, 金肖克, 祝成炎, 等. 玻璃纤维/光敏树脂复合材料的3D打印及其力学性能[J]. 纺织学报, 2021, 42(1): 73-77.
SONG Xing, JIN Xiaoke, ZHU Chengyan, et al. 3D printing and mechanical properties of glass fiber/photosensitive resin composites[J]. Journal of Textile Research, 2021, 42(1): 73-77.
[12] LUO G, LI W, LIANG W, et al. Coupling effects of glass fiber treatment and matrix modification on the interfacial microstructures and the enhanced mechanical properties of glass fiber/polypropylene composites[J]. Composites Part B: Engineering, 2017, 111(1): 1-39.
doi: 10.1016/j.compositesb.2016.11.054
[13] 邵灵达, 申晓, 金肖克, 等. 涤纶纤维表面复合改性对其亲水性的影响[J]. 丝绸, 2020, 57(2): 19-24.
SHAO Lingda, SHEN Xiao, JIN Xiaoke, et al. Effect of surface modification of polyester fiber on its properties[J]. Journal of Silk, 2020, 57(2): 19-24.
[14] XING J, XU Z, NI Q Q, et al. Preparation and characterization of polyphenylene sulfide/graphene nanoplatelets composite fibers with enhanced oxidation resistance[J]. High Performance Polymers, 2019, 32(4): 394-405.
doi: 10.1177/0954008319867748
[15] 宋雪旸, 张岩, 徐成功, 等. 碳纤维/聚丙烯/聚乳酸增强复合材料的力学性能[J]. 纺织学报, 2021, 42(11): 84-88.
SONG Xueyang, ZHANG Yan, XU Chenggong, et al. Mechanical properties of carbon fiber/polypropylene/polylactic acid reinforced composites[J]. Journal of Textile Research, 2021, 42(11): 84-88.
[16] HU J, LI F, WANG B, et al. A two-step combination strategy for significantly enhancing the interfacial adhesion of CF/PPS composites: the liquid-phase oxidation followed by grafting of silane coupling agent[J]. Composites Part B: Engineering, 2020, 191(1): 1-12.
[17] 杨杰. 聚苯硫醚树脂及其应用[M]. 北京: 化学工业出版社, 2005: 100-113.
YANG Jie. Polyphenylene sulfide resin and its application[M]. Beijing: Chemical Industry Press, 2005: 100-113.
[1] WANG Dongwei, FANG Kuanjun, LIU Xiuming, ZHANG Xinqing, AN Fangfang. Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics [J]. Journal of Textile Research, 2022, 43(04): 90-96.
[2] HE Yang, ZHANG Ruiping, HE Yong, FAN Aimin. Dyeing properties of laser modified polyester fabrics with disperse dyes [J]. Journal of Textile Research, 2022, 43(04): 102-109.
[3] LU Qianqian, TANG Junxiong, LIU Yuanjun, ZHAO Xiaoming. Research progress in preparation of carbon nanotubes based wave absorbing composites and its applications in textile field [J]. Journal of Textile Research, 2022, 43(04): 187-193.
[4] YE Wei, YU Jin, LONG Xiaoyun, SUN Qilong, MA Yan. Electromagnetic wave absorption performance of loofah-based carbon materials [J]. Journal of Textile Research, 2022, 43(04): 33-39.
[5] QIAO Yansha, MAO Ying, XU Danyao, LI Yan, LI Shaojie, WANG Lu, TANG Jianxiong. Research progress in warp-knitted meshes for tackling complications after hernia repair [J]. Journal of Textile Research, 2022, 43(03): 1-7.
[6] XIE Kaifang, LUO Fengxiang, BAO Xinjun, ZHOU Hengshu, XU Guangbiao. Preparation and performance of composite coated polyester harness cord with high wearability [J]. Journal of Textile Research, 2022, 43(03): 123-131.
[7] FANG Meiqi, WANG Qian, LI Yan, LI Chaojing, LI Hao, WANG Lu. Design and in-vitro mechanical property analyses of sling for female stress urinary incontinence [J]. Journal of Textile Research, 2022, 43(03): 38-43.
[8] ZHANG Tao, WANG Fuping, CHEN Guobao, WU Jiyu, PANG Yani, CHEN Zhongmin. Preparation and performance of chitosan-based antibacterial gel [J]. Journal of Textile Research, 2022, 43(03): 71-77.
[9] GU Yuanhui, ZHOU Hongtao, ZHANG Diantang, LIU Jingyan, WANG Shudong. Torsional mechanical properties and failure mechanism of braided carbon fiber reinforced composite tubes [J]. Journal of Textile Research, 2022, 43(03): 95-102.
[10] CHEN Yong, WU Jing, WANG Chaosheng, PAN Xiaohu, LI Naixiang, DAI Junming, WANG Huaping. Preparation and environmental degradation behavior of biodegradable poly (butylene adipate-co-terephthalate) fiber [J]. Journal of Textile Research, 2022, 43(02): 37-43.
[11] JIN Wenjie, CHENG Xianwei, GUAN Jinping, CHEN Guoqiang. Sulfanilamide finishing to polyamide 6 fabrics for flame retardant and anti-dripping performance [J]. Journal of Textile Research, 2022, 43(02): 171-175.
[12] GUO Zijiao, LI Yue, ZHANG Rui, LU Zan. Preparation and properties of polyaniline/Ti3C2Tx/carbon nanotube composite fiber-based electrodes [J]. Journal of Textile Research, 2022, 43(02): 74-80.
[13] LI Zhenzhen, ZHI Chao, YU Lingjie, ZHU Hai, DU Mingjuan. Preparation and properties of waste cotton regenerative aerogel/warp-knitted spacer fabric composites [J]. Journal of Textile Research, 2022, 43(01): 167-171.
[14] QIANG Rong, FENG Shuaibo, LI Wanying, YIN Linzhi, MA Qian, CHEN Bowen, CHEN Yi. Biomass-derived magnetic carbon composites towards microwave absorption [J]. Journal of Textile Research, 2022, 43(01): 21-27.
[15] MIN Xiaobao, PAN Zhijuan. Quality and performance of biomass fiber/pineapple leaf fiber multi-component blended yarn [J]. Journal of Textile Research, 2022, 43(01): 74-79.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd