Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (12): 96-101.doi: 10.13475/j.fzxb.20211104106

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of reactive dye structure on performance of colored polymer nanospheres

ZHANG Shuai1, FANG Kuanjun1,2,3,4,5(), LIU Xiuming1, QIAO Xiran1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
    3. Collaborative Innovation Center for Eco-Textiles of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
    4. State Key Laboratory for Biofibers and Eco-textiles, Qingdao, Shandong 266071, China
    5. National Engineering Research Center for Dyeing and Finishing of Textiles, Taian, Shandong 271000, China
  • Received:2021-11-08 Revised:2022-09-13 Online:2022-12-15 Published:2023-01-06
  • Contact: FANG Kuanjun E-mail:13808980221@163.com

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Abstract:

In order to improve the dye loading and coloring properties of the colored polymer nanospheres, polymer nanospheres with different colors were prepared by cationic composite nanospheres and reactive dyes which contain different amounts of sulfonic acid groups. The effects of the concentrations of sulfonic acid-based reactive dyes on the dye adsorption, particle size and zeta potential of the colored polymer nanospheres were investigated by equilibrium dialysis, transmission electron microscopy and nanoparticle size/Zeta potential analyzer. The results show that the more sulfonic acid groups were on the cationic nanospheres the greater was the adsorption of reactive dyes at the same dye concentration. When the number of sulfonic acid groups was the same, the more hydrophobic the reactive dyes were, the greater the adsorption amount on the cationic nanospheres. In addition, the amount of dye adsorbed by the color polymer nanospheres increased with increasing dye concentration. The absolute value of Zeta potential decreased followed by an increase, while the average hydrated particle size increased first and then decreased.

Key words: reactive dye, dye structure, adsorption quantity, Zeta potential, hydrated particle size, colored polymer nanosphere, fiber dyeing

CLC Number: 

  • TQ31

Fig.1

Molecular structures of different reactive dyes. (a) Reactive orange 16; (b) Reactive yellow 95; (c) Reactive red 218; (d) Reactive blue 49; (e) Reactive blue 222"

Fig.2

Effect of different concentrations of reactive dyes on adsorption amount of composite nanospheres"

Fig.3

Effect of different concentrations of reactive dyes on Zeta potential of composite nanospheres"

Fig.4

Effect of different concentrations of reactive dyes on particle size of composite nanospheres"

Fig.5

TEM images of different reactive dye nanospheres. (a) Reactive Orange 16; (b) Reactive Blue 49; (c) Reactive Blue 222(× 100 000)"

Fig.6

Effect of reactive dyes concentration with the same sulfonic acid on adsorption amount of composite nanospheres"

Tab.1

Molecular weight and relative molecular weight per sulfonic acid group of three different reactive dyes"

染料名称 染料相对
分子质量		 磺酸基
数目		 单位磺酸基所承载的
相对分子质量
活性黄95 797.07 3 265.69
活性红218 852.15 3 284.05
活性蓝49 882.17 3 294.06

Fig.7

Effect of reactive dyes concentration with same sulfonic acid on Zeta potential of composite nanospheres"

Fig.8

Effect of reactive dyes concentration with same sulfonic acid on particle size of composite nanospheres"

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