纺织学报 ›› 2021, Vol. 42 ›› Issue (03): 181-189.doi: 10.13475/j.fzxb.20200601410

所属专题： 阻燃纤维及纺织品

• 综合述评 • 上一篇    下一篇

光诱导表面改性技术在织物阻燃中的应用研究进展

周颖雨1, 王锐1,2, 靳高岭3, 王文庆1,2   

  1. 1.北京服装学院 材料设计与工程学院, 北京 100029
    2.北京服装学院 服装材料研究开发与评价北京市重点实验室, 北京 100029
    3.中国化学纤维工业协会, 北京 100020
  • 收稿日期:2020-06-05 修回日期:2020-11-27 出版日期:2021-03-15 发布日期:2021-03-17
  • 作者简介:周颖雨(1995—),女,硕士生。主要研究方向为阻燃聚酯织物的制备。
  • 基金资助:
    国家重点研发计划项目(2017YFB0309002);北京学者项目(RCQJ20303);北京市科技计划一般项目(KM202010012004)

Research progress of applications of photo-induced surface modification technique in flame retardant fabrics

ZHOU Yingyu1, WANG Rui1,2, JIN Gaoling3, WANG Wenqing1,2   

  1. 1. School of Material Design & Engineeing, Beijing Institute of Fashion Technology, Beijing 100029, China
    2. Key Laboratory of Clothing Materials R&D and Assessment, Beijing Institute of Fashion Technology,Beijing 100029, China
    3. China Chemical Fibers Association, Beijing 100020, China
  • Received:2020-06-05 Revised:2020-11-27 Online:2021-03-15 Published:2021-03-17

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摘要：

为提高纺织品的阻燃耐久性、耐水洗性,解决传统阻燃改性手段无法满足绿色、环保理念的矛盾,进一步拓宽光诱导表面改性制备阻燃织物的技术手段、研究领域,是行之有效的方法之一。阐述了光诱导表面改性技术的反应机制、涂层阻燃机制、表面后整理方法,介绍了光诱导改性阻燃在棉、聚酯、聚酰胺、聚丙烯腈等织物中的应用现状,分析了当前阻燃改性存在的问题。指出:未来的发展重点将是扩大光诱导的光源,尤其是能量低、生物安全的自然光;光诱导的可控聚合技术将有望成为实现织物表面阻燃涂层设计与可控生长的重要技术方法,以此推动光诱导表面处理技术在功能性阻燃织物中的广泛应用。

关键词: 光诱导反应, 可控聚合, 阻燃机制, 阻燃整理, 表面改性, 阻燃织物, 功能纺织品

Abstract:

In order to improve the durability and washable resistance of flame retardant textiles, and to balance between the flame retardant modification and green finishing, environmental protection, photo-induced surface modification for flame retardancy is one of the effective methods. The reaction mechanism of photo-induced surface modification, the flame retardant mechanism of coating and the finishing method for substrate surfaces were systematically described. Photo-induced flame retardancy treatment for cotton, polyester, polyamide, and polyacrylonitrile fabrics were mainly introduced, and the existing problems of flame retardant modification were analyzed. This review indicates that future developments of flame-retardant surface treatments for textiles need be concentrated on expanding photo-inducing light sources, especially natural light with low energy and bio-safety. The photo-controlled polymerization technology is expected to become an important technical method for facilitating the design and controlled growth of flame retardant coatings on fabric surfaces,so as to promote the wider application of the photo-induced surface treatment technology for functional flame-retardant fabrics.

Key words: photo-induced reaction, controlled polymerization, flame retardant mechanism, flame retardant finishing, surface modification, flame retardant fabric, functional textiles

中图分类号: 

  • TQ342

图1

“Grafting to”示意图"

图2

“Grafting from”示意图"

表1

光诱导反应在样品表面制备不同的阻燃涂层"

基材 阻燃添加剂 作用方式 阻燃效果(较原样品增加或降低的百分数)/% 参考文献
热释放速率峰值 总热释放量 LOI值
棉 CH、DNA 接枝-单体 -38 -45 — [50]
棉 PDHA 接枝-聚合 -65 -74 2 [33]
棉 ETMM树脂、AN、TAIC 交联 -78 -71 85 [38]
蚕丝 DEMEP 接枝共聚 — — 25 [51]
PA66 DOPO-DAAM 接枝-单体 -22 — 55 [52]
CO/PET Am 接枝-聚合物 — — 66 [53]
PAN GMA、水合肼、磷酸 接枝-聚合物 -60 -38 90 [19]
PET APP、MMEP 聚合 — — 55 [54]
木板 CO-SH、TTC、DA 交联 -10 -73 27 [55]
GRE VPA 交联 -98 -95 — [40]
RPU BHAAPE、MAAR、PUA 交联 — — 36 [39]
EVA 酪蛋白、DNA 交联 -26 -4 — [56]
PMMA PA、TGICA、TAEP 交联 — — 27 [57]
PC PUA、二氧化硅、支化聚乙烯亚胺 交联 — — 24 [58]
木板 TAP、DMAA、PETMP、PET3A 交联 — — 15 [59]
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