纺织学报 ›› 2021, Vol. 42 ›› Issue (02): 1-6.doi: 10.13475/j.fzxb.20210106206

• 特邀论文 •    下一篇

丝素粉体/颜料复合体耐热真空升华色牢度提升机制

曹根阳, 王运利, 盛丹, 潘恒, 徐卫林()   

  1. 武汉纺织大学 纺织新材料与先进加工技术国家重点实验室, 湖北 武汉 430200
  • 收稿日期:2021-01-05 修回日期:2021-01-25 出版日期:2021-02-15 发布日期:2021-02-23
  • 通讯作者: 徐卫林
  • 作者简介:曹根阳(1981—),男,副教授,博士。主要研究方向为高性能纤维的染色。
  • 基金资助:
    中央引导地方科技发展资金专项(2020ZYD038)

Promotion mechanism of color fastness to sublimation in thermovacuum environmental conditions for fibroin powder/pigment complex

CAO Genyang, WANG Yunli, SHENG Dan, PAN Heng, XU Weilin()   

  1. State Key Laboratory of New Textile Materials and Advanced Processing Technologies,Wuhan Textile University, Wuhan, Hubei 430200, China
  • Received:2021-01-05 Revised:2021-01-25 Online:2021-02-15 Published:2021-02-23
  • Contact: XU Weilin

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摘要：

为提高有色织物上颜料粒子在热真空环境条件下的耐升华色牢度,考察了颜料萘酚红F3RK颗粒和丝素粉体的表面形貌、粒径和分子结构。采用颜料粒子与丝素粉体混合对织物进行颜色调控,利用负压流体场模拟热真空环境下的热力场,研究了颜料粒子和丝素粉体在不同比例下的吸附性能,并探讨了丝素粉体与颜料粒子之间的相互作用机制,构建了微纳米丝素粉体提升涂料印花织物耐升华色牢度的理论模型。结果表明:丝素粉体通过其比表面积大和含有酰胺键的官能团协同作用解决了有色织物热真空沾色问题,耐升华色牢度达到了5级。该方法对极端环境条件下提高有色织物的耐升华色牢度具有借鉴意义。

关键词: 丝素粉体, 纳米颜料, 印花, 热真空环境, 耐升华色牢度

Abstract:

In order to improve the thermal sublimation fastness of pigment particles on colored fabrics under thermovacuum environmental conditions, surface morphology, particle size and molecular structure of naphthol red F3RK pigment particles and silk fibroin powders were investigated, and the color of the fabric was tuned by mixing pigment particles with silk fibroin powder at different ratios. The subatomospheric pressure is used to simulate the thermal force field in the thermalvacuum environment, under which the adsorption performance was studied under different mixing ratios between pigment particles and silk fibroin powder. The interaction between silk fibroin powders and pigment particles were discussed, and the theoretical model was established. The results show that the silk fibroin powder is effective in improving thermal sublimation of colored fabrics in thermovacuum environmental conditions due to the synergistic effect of its large specific surface area and amido bonds. Employment of this method increases thermal sublimation fastness to level 5. The results of this study are of referencing significance for improving the thermal sublimation fastness of colored fabrics under extreme environmental conditions.

Key words: silk fibroin powder, nano-pigment, printing, thermovacuum environmental condition, thermal sublimation fastness

中图分类号: 

  • TS194.2

图1

丝素粉体及萘酚红F3RK性能"

图2

萘酚红F3RK粒子及其被丝素粉体吸附形貌图"

图3

复合比例对丝素粉体吸附量的影响"

图4

不同粉体的储能模量"

图5

微纳米丝素粉体对涂料膜结构调控模型"

图6

丝素粉体调控前后经6.5次高真空高低温循环样品图"

表1

丝素粉体调控织物耐热升华色牢度"

样品 耐热升华色牢度/级
红色 黄色
未调控样品 1 2
调控样品 5 5
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