纺织学报 ›› 2026, Vol. 47 ›› Issue (05): 172-181.doi: 10.13475/j.fzxb.20250902801

• 染整工程 • 上一篇    下一篇

聚多巴胺/十八胺/氧化锌协同改性香云纱的超疏水与防紫外线性能

郑晶晶1,2(), 曹源1, 陈佳桦1, 吕健元3   

  1. 1 浙江理工大学 服装学院, 浙江 杭州 310018
    2 浙江理工大学 浙江省数智风格与创意设计研究中心, 浙江 杭州 310018
    3 浙江开源文化发展有限公司, 浙江 湖州 313200
  • 收稿日期:2025-09-08 修回日期:2026-03-12 出版日期:2026-05-15 发布日期:2026-07-10
  • 作者简介:郑晶晶(1982—),女,副教授,硕士。主要研究方向为服装感性工学与纺织品面料的评价和设计。E-mail:zjj_cecily@zstu.edu.cn。
  • 基金资助:
    浙江省自然科学基金项目(Y15E050106);浙江理工大学教育教学改革项目(JGZD202405)

Superhydrophobicity and UV resistance of polydopamine/octadecylamine/zinc oxide synergistic modified gambiered Canton silk

ZHENG Jingjing1,2(), CAO Yuan1, CHEN Jiahua1, LÜ Jianyuan3   

  1. 1 College of Fashion Design and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2 Zhejiang Digital Intelligence Style and Creative Design Research Center, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    3 Zhejiang Kaiyuan Cultural Development Co., Ltd., Huzhou, Zhejiang 313200, China
  • Received:2025-09-08 Revised:2026-03-12 Published:2026-05-15 Online:2026-07-10

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摘要：

针对传统香云纱功能单一问题,开展协同改性香云纱的超疏水与防紫外线性能研究,制备兼具超疏水和紫外线防护性能的多功能香云纱,以拓展其在户外服饰及高端功能纺织品领域的应用。基于聚多巴胺(PDA)自聚合构建功能化沉积层、利用十八胺(ODA)的疏水性接枝到香云纱上赋予其超疏水与自清洁性能,同时采用乙烯基三乙氧基硅烷(VTES)修饰氧化锌(ZnO)构建紫外线屏蔽层,实现多功能协同改性。通过优化各阶段反应参数,得到最佳工艺参数:多巴胺质量浓度4 g/L、反应时间24 h、温度40 ℃、ODA质量分数3%、相对于ZnO质量15%的质量分数为4%的VTES、VTES-ZnO。在此条件下所得PDA/ODA/VTES-ZnO改性香云纱的静态接触角达153°、滑动角为10°,紫外线防护系数达265.26,长波紫外线和中波紫外线透过率分别降至3.54%和3.10%。改性香云纱在保持原有丝绸风格与穿着舒适性的同时,赋予其优异的超疏水、自清洁及防紫外线性能,且具有良好的耐久性,成功实现了香云纱织物多功能协同改性,为传统丝绸功能升级提供有效路径。

关键词: 香云纱, 聚多巴胺, 十八胺, 氧化锌, 超疏水, 防紫外线, 自清洁性能, 功能性纺织品

Abstract:

Objective Gambiered Canton silk is a national intangible cultural heritage. Renowned for its unique luster, permeability, and eco-friendly dyeing process, it holds significant cultural and economic value. However, its application has been constrained by inherent functional limitations. As a natural protein fiber, it is susceptible to moisture absorption, which can lead to mildew growth in humid environments. Furthermore, prolonged exposure to sunlight causes photoyellowing and degradation from ultraviolet radiation, compromising its aesthetic and structural integrity. In order to address the issue of the single functionality of traditional gambiered Canton silk, this study aims to prepare a multi-functional fabric with both superhydrophobic and ultraviolet protection properties through a multi-step chemical modification process. This enhancement seeks to expand its applications in modern sectors such as outdoor apparel and high-end technical textiles, thereby contributing to the sustainable inheritance and innovation of this cultural heritage.

Method Based on the self-polymerization property of dopamine (DA) to form polydopamine (PDA), the surface of the gambiered Canton silk was modified. By investigating the influences of DA concentration, reaction time and reaction temperature on the hydrophobicity of the fabric, the optimal modification process conditions were determined, and the successful deposition of PDA on the gambiered Canton silk was confirmed through physical and chemical performance characterization. Octadecylamine (ODA) was grafted onto the PDA modified gambiered Canton silk to further reduce the surface energy and endow the fabric with superhydrophobic and self-cleaning properties. The microstructure, chemical composition and wearing performance of the PDA/ODA modified gambiered Guangdong gauze were also analyzed and tested. Finally, vinyltriethoxysilane (VTES) was adopted to modify zinc oxide (ZnO) nanoparticles to improve the dispersion of ZnO and obtain the optimal concentration of modification. The VTES-ZnO dispersion was adopted for secondary modifcation of the fabric, ultimately endowing the gambiered Canton silk with excellent ultraviolet protection performance.

Results The optimized modified fabric achieved superhydrophobicity with a contact angle of 153° and a sliding angle smaller than 10°. For ultraviolet protection, its ultraviolet protection foctor (UPF) value reached 265.26, with ultraviolet A(UVA) and ultraviolet B(UVB) transmittances of 3.54% and 3.10%, respectively, meeting national ultraviolet protection standards. After 50 wash cycles, its UPF value was 237.62, and after 100 rubbing cycles, its UPF value still reached 224.69, showing excellent durability. Scanning electron microscope images revealed that PDA increased surface roughness, ODA formed a lamellar structure, and VTES-ZnO created a stable nano-composite layer. The infrared spectra anaylsis confirmed the successful bonding of PDA, ODA, and VTES-ZnO to the fabric, with characteristic peaks of functional groups like —OH, —CH2, and Si—O—Si appearing. Additionally, the fabric maintained good air permeability (365 mm/s) and improved mechanical properties and color fastness.

Conclusion The PDA/ODA/VTES-ZnO ternary modification system was proved to be an effective strategy for the functional enhancement of gambiered Canton silk. It successfully endowed the traditional textile with durable superhydrophobicity, outstanding ultraviolet resistance, and robust durability against washing and rubbing. Crucially, this was achieved without compromising its inherent aesthetic and comfort properties, such as its soft handle and permeability. By overcoming the key functional defects of the traditional fabric, this technology provides a scientific and practical reference for the functional reconstruction of other traditional textiles, thereby promoting the modern inheritance and broader application of this valuable intangible cultural heritage.

Key words: gambiered Canton silk, polydopamine, octadecylamine, zinc oxide, superhydrophobic, ultraviolet protection, self-cleaning performance, functional textiles

中图分类号: 

  • TS195.6

图1

改性香云纱的制备流程"

图2

DA质量浓度对香云纱疏水性能的影响"

图3

反应时间对香云纱疏水性能的影响"

图4

反应温度对香云纱疏水性能的影响"

图5

ODA质量分数对香云纱疏水性能的影响"

图6

ZnO粉末在改性前后的表面形态"

图7

VTES质量分数对ZnO表面修饰效果的影响"

图8

反应时间对香云纱疏水性能的影响"

图9

反应温度对香云纱疏水性能的影响"

图10

VTES-ZnO质量分数对香云纱疏水性能的影响"

图11

改性前后香云纱的表面形貌"

图12

改性前后香云纱的红外光谱图"

表1

改性前后香云纱紫外线防护性能"

样品 UPF TUVA/% TUVB/%
未改性香云纱 22.66 41.96 30.87
PDA改性香云纱 42.34 32.67 24.12
PDA/ODA改性香云纱 95.48 16.42 13.19
PDA/ODA/VTES-ZnO改性香云纱 265.26 3.54 3.10

图13

紫外线防护耐久性"

表2

改性前后香云纱的接触角与滑动角"

样品 接触角/
(°)		 滑动角/
(°)
未改性香云纱 124 26
PDA改性香云纱 135 20
PDA/ODA改性香云纱 151 8
PDA/ODA/VTES-ZnO改性香云纱 154 10

图14

改性前后香云纱对油红O染液的自清洁性能对比"

表3

改性前后香云纱的色牢度与透气率"

样品 耐皂洗色
牢度/级		 耐光色
牢度/级		 耐摩擦色
牢度/级		 透气率/
(mm·s-1)
变色 沾色 耐干摩 耐湿摩
未改性香云纱 3 3 3 3 4 460
PDA改性
香云纱		 4 4~5 4 4 4~5 416
PDA/ODA
改性香云纱		 4~5 4~5 4 4~5 5 379
PDA/ODA/
VTES-ZnO
改性香云纱		 5 5 5 5 5 365
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