光致变色纺织品的制备及其防伪应用

doi:10.13475/j.fzxb.20250908301

纺织学报 ›› 2026, Vol. 47 ›› Issue (02): 214-221.doi: 10.13475/j.fzxb.20250908301

光致变色纺织品的制备及其防伪应用

黄雍宝¹^,², 王一洲¹, 李梦琪¹, 万贝贝¹, 宋悦¹, 杨帆¹^,²()

¹ 德州学院纺织服装学院, 山东德州 253023
² 新疆大学纺织与服装学院, 新疆乌鲁木齐 830046

收稿日期:2025-09-22 修回日期:2025-12-12 出版日期:2026-02-15 发布日期:2026-04-24
通讯作者: 杨帆(1989—),男,副教授,博士。主要研究方向为智能可穿戴纺织品。E-mail:yangf@dzu.edu.cn。
作者简介:黄雍宝(1998—),男,硕士生。主要研究方向为智能敷料。
说明:本文入围中国纺织工程学会第26届陈维稷论文卓越行动计划
基金资助:
国家自然科学基金项目(22104010);山东省高等学校青年创新团队计划项目(2023KJ271)

Preparation of photochromic textiles and their anti-counterfeiting applications

HUANG Yongbao¹^,², WANG Yizhou¹, LI Mengqi¹, WAN Beibei¹, SONG Yue¹, YANG Fan¹^,²()

¹ College of Textile and Clothing, Dezhou University, Dezhou, Shandong 253023, China
² College of Textile and Clothing, Xinjiang University, Urumqi, Xinjiang 830046, China

Received:2025-09-22 Revised:2025-12-12 Published:2026-02-15 Online:2026-04-24

摘要/Abstract

摘要：

针对传统防伪技术动态响应能力弱与安全性不足的问题,开发了一种新型光致变色织物,并系统评估其在防伪应用中的性能。通过构建硝基苯并螺吡喃-聚甲基丙烯酸酯混合溶剂体系,成功制备出高稳定性的光致变色油墨,并基于该油墨实现了功能性纺织品的制备。对所制备光致变色织物的化学结构、光学性能、透气性、摩擦色牢度、疏水性及防伪性能等进行测试与表征。结果表明:该光致变色织物在紫外光照下1 s内即可迅速显色,移除光源后快速褪色,2 min后完全恢复初始状态,且具备良好的可重复使用性;透气率超过100 mm/s,耐摩擦色牢度达4~5级,无掉色或脱色现象,耐光色牢度为3~4级;接触角大于90°,表现出优良的疏水性能;此外,结合二维码技术设计的双模态动态防伪标签,在紫外光照下可实现动态显色,仅在撤光后30 s的时间窗口内可有效读取二维码信息。该光致变色纺织品的颜色褪变行为难以通过普通印刷技术复制,显著增强了防伪性能,为在高端防伪领域的应用提供了新策略。

关键词: 光致变色材料, 智能纺织品, 防伪技术, 功能性纺织品, 紫外光响应, 防伪油墨, 防伪二维码, 防伪纺织品

Abstract:

Objective In response to the problems of weak dynamic response capability and insufficient security of traditional anti-counterfeiting technologies, this study aims to develop a new type of photochromic textile and construct a high-security dynamic authentication system suitable for smart textiles.

Method Highly stable photochromic ink was prepared by constructing a nitrobenzopyrylospiran-poly methyl methacrylate mixed solvent system. Polyester yarns of 16.67 tex were immersed, padded with 70% wet pickup, dried at 50 ℃ for 30 min, before being woven into plain fabrics. To enhance the recognizability of the anti-counterfeiting Quick Response (QR) codes, the same treated polyester yarns were used to embroider the QR codes onto the plain fabrics that were woven from the untreated polyester yarns. Characterization involved chemical structure, optical properties, air permeability testing, friction and light fastness evaluation, contact angle measurement, and ultraviolet illumination-response trials using a 365 nm lamp.

Results The photochromic textile exhibited exceptional responsiveness, achieving visible coloration within 1 s under 365 nm ultraviolet irradiation and complete decoloration within 2 min after light removal, demonstrating excellent reversibility across multiple cycles. Analysis using Fourier Transform Infrared Spectroscopy, confirmed successful ink fixation via hydrogen bonding evidenced by a broad peak near 3 300 cm^-1, aromatic C—H interactions appearing at 3 030 cm^-1, and potential C—N bond formation indicated by a shoulder peak around 1 180 cm^-1. Ultraviolet-Visible spectroscopy revealed that ultraviolet exposure induced a prominent absorption band at 500 nm, corresponding to a transition from white coloration to rose-red. Before irradiation, the fabric exhibited high reflectivity across 400-700 nm with CIE Lab parameters showing L^* near 100 and a^* and b^* close to zero, yielding RGB values of 235, 232, 223. After ultraviolet exposure, L^* decreased significantly while a^* rose to approximately +54 and b^* turned negative, producing RGB values of 146, 99, 141, characteristic of rose-red hues. The average air permeability of the fabric reached 145.57 mm/s with a coefficient of variation of only 6.39%, indicating uniform structure and satisfactory wearing comfort. Color fastness testing yielded ratings of 4 to 5 for both dry and wet rubbing resistance, and 3 to 4 for light fastness, confirming adequate durability for indoor applications. Continuous 12 h xenon lamp exposure demonstrated gradual absorbance decay under illumination while baseline absorbance remained stable, indicating irreversible photo-oxidation of photochromic molecules without substrate degradation, consistent with the observed light fastness rating. The textile exhibited robust hydrophobicity, with contact angles all exceeding 90° over 3 s. For anti-counterfeiting functionality, the embroidered QR code remained machine-readable only during a narrow 30 s window after ultraviolet removal, becoming undetectable within 2 min as color faded spontaneously.

Conclusion This photochromic textile system constitutes a robust platform for advanced dynamic anti-counterfeiting applications, integrating rapid optical responsivity, mechanical durability, and superior hydrophobicity. The dual-mode authentication mechanism with its narrow temporal window and non-replicable fading behavior substantially enhances security compared to static identifiers. Future research should focus on improving long-term photostability through molecular engineering, developing multi-dimensional encryption protocols, and optimizing industrial-scale inkjet printing for precise color kinetic control. This work establishes a viable technological pathway for implementing intelligent, traceable anti-counterfeiting solutions in smart wearable textiles and high-value product authentication, offering significant potential for integration with blockchain-based traceability systems.

Key words: photochromic material, intelligent textiles, anti-counterfeiting technology, functional textiles, ultraviolet light response, anti-counterfeiting ink, anti-counterfeiting QR code, anti-counterfeiting textiles

中图分类号:

TS195.5

黄雍宝, 王一洲, 李梦琪, 万贝贝, 宋悦, 杨帆. 光致变色纺织品的制备及其防伪应用[J]. 纺织学报, 2026, 47(02): 214-221.

HUANG Yongbao, WANG Yizhou, LI Mengqi, WAN Beibei, SONG Yue, YANG Fan. Preparation of photochromic textiles and their anti-counterfeiting applications[J]. Journal of Textile Research, 2026, 47(02): 214-221.

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链接本文: http://www.fzxb.org.cn/CN/10.13475/j.fzxb.20250908301

http://www.fzxb.org.cn/CN/Y2026/V47/I02/214

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参考文献 25

[1]	GAYIALIS S P, KECHAGIAS E, PAPADOPOULOS G A, et al. Design of a blockchain-driven system for product counterfeiting restraint in the supply chain[M]// Advances in production management systems. production management for the factory of the future. Cham: Springer International Publishing, 2019: 474-481.
[2]	KHALILZADEH R, BABAZADEH-MAMAQANI M, MOHAMMADI-JORJAFKI M, et al. Advanced anticounterfeiting polymer inks for high-level encryption and authentication technologies[J]. Progress in Materials Science, 2025, 153: 101487. doi: 10.1016/j.pmatsci.2025.101487
[3]	ZHAN Z K, LI S H, SHEN L, et al. Smart and secure: fluorescent polymers revolutionizing anti-counterfeiting strategies[J]. Advanced Materials Technologies, 2025, 10(23): e01366. doi: 10.1002/admt.v10.23
[4]	KUMAR S, BANKA H, KAUSHIK B, et al. A review and analysis of secure and lightweight ECC-based RFID authentication protocol for Internet of vehicles[J]. Transactions on Emerging Telecommunications Technologies, 2021, 32(11): e4354. doi: 10.1002/ett.v32.11
[5]	DUAN J T, LI G Q, XIONG Y Z, et al. Scalable plasmonic physical unclonable functions empowered by a multi-dimensional expanding strategy[J]. Advanced Photonics Nexus, 2025, 4(1): 016003-016003.
[6]	BIN AHMAD KAYANI A, KURIAKOSE S, MONSHIPOURI M, et al. UV photochromism in transition metal oxides and hybrid materials[J]. Small, 2021, 17(32): 2100621. doi: 10.1002/smll.v17.32
[7]	王小艳, 杨书康, 肖国威, 等. 光响应螺噁嗪掺杂长余辉发光纤维的制备及其性能[J]. 纺织学报, 2025, 46(2): 1-9.
	WANG Xiaoyan, YANG Shukang, XIAO Guowei, et al. Preparation and performance of photoresponsive long-afterglow phosphorescent fibers with spirooxazine doping[J]. Journal of Textile Research, 2025, 46(2): 1-9. doi: 10.1177/004051757604600101
[8]	XU C, QIAO Z H, NIU J R, et al. Study on a novel dye with multi-stimulus response based on spiropyran[J]. Dyes and Pigments, 2025, 239: 112775. doi: 10.1016/j.dyepig.2025.112775
[9]	HASSAN F, TANG Y Q, BISOYI H K, et al. Photochromic carbon nanomaterials: an emerging class of light-driven hybrid functional materials[J]. Advanced Materials, 2024, 36(32): 2401912. doi: 10.1002/adma.v36.32
[10]	SHARMA D, GOYAL S, KUMAR K, et al. Advanced functional spiropyran-based smart materials with rapid and reversible photochromic response for optical sensing applications[J]. Advanced Materials Technologies, 2025, 10(10): 2401288. doi: 10.1002/admt.v10.10
[11]	李达, 郭鹍鹏, 张芳, 等. 苯并噻唑偶氮苯化合物的双模式光致变色性能及其在光信息存储中的应用[J]. 高等学校化学学报, 2025, 46(9): 78-84.
	LI Da, GUO Kunpeng, ZHANG Fang, et al. Dual-mode photochromic properties of a benzothiazole-azobenzene compound and its application in optical information storage[J]. Chemical Journal of Chinese Universities, 2025, 46(9): 78-84.
[12]	GUPTA I, SINGH S, BHAGWAN S, et al. Rare earth (RE) doped phosphors and their emerging applications: a review[J]. Ceramics International, 2021, 47(14): 19282-19303. doi: 10.1016/j.ceramint.2021.03.308
[13]	NEACSU A, CHIHAIA V, ALEXIEV V, et al. Specifics of the molecular conformations and physicochemical properties of merocyanine form of spirooxazine derivative: insights from experimental and molecular dynamics studies[J]. Materials, 2025, 18(11): 2505. doi: 10.3390/ma18112505
[14]	WAN J M, XU J, ZHU S Y, et al. Photochromic composites with fast light response, high contrast, and waterproof properties[J]. Journal of Cleaner Production, 2023, 419: 138281. doi: 10.1016/j.jclepro.2023.138281
[15]	赵明顺, 陈枭雄, 于金超, 等. 光致变色聚乳酸纤维的纺制及其微观结构与性能[J]. 纺织学报, 2023, 44(7): 10-17.
	ZHAO Mingshun, CHEN Xiaoxiong, YU Jinchao, et al. Spinning and microstructure and properties of photochromic polylactic acid fibers[J]. Journal of Textile Research, 2023, 44(7): 10-17.
[16]	MANEA-SAGHIN A M, ION A E, KAJZAR F, et al. Second order nonlinear optical properties of poled films containing azobenzenes tailored with azulen-1-yl-pyridine[J]. Heliyon, 2023, 9(6): e17360. doi: 10.1016/j.heliyon.2023.e17360
[17]	LI B S, ZHU W Y, LIU J R, et al. Grafting photochromic spiropyran polymer brushes on graphene oxide surfaces via surface-initiated ring-opening metathesis polymerization[J]. RSC Advances, 2024, 14(6): 3748-3756. doi: 10.1039/D3RA08076E
[18]	ZHANG M, ZHOU Q, DONG Q S, et al. Electrospun bioactive poly(ε-caprolactone) nanofibrous scaffolds incorporated with natural decellularized bone extracellular matrix for bone regeneration[J]. European Cells and Materials, 2025, 49: 35-54. doi: 10.22203/eCM.v049a05
[19]	WANG S P, WU L M, LI H, et al. A Cu²⁺ triggered reversible photochromic system: the structure photochromic response relationship study and potential applications[J]. Royal Society Open Science, 2023, 10(6): 230121. doi: 10.1098/rsos.230121
[20]	李炤中. 具有智能变色特性的电/光响应液晶高分子复合材料的制备与性能研究[D]. 北京: 北京科技大学, 2025.
	LI Zhaozhong. Research on preparation and performance of electro-/photo-responsive liquid crystal polymer composites with color-changing properties[D]. Beijing: University of Science and Technology Beijing, 2025.
[21]	LI Y L, ZHANG F, SHEN L Y, et al. Robust and long-lived photochromic textiles with spiropyran derivatives[J]. ACS Applied Optical Materials, 2025, 3(2): 346-357. doi: 10.1021/acsaom.4c00488
[22]	欧宗权, 于金超, 潘志娟. 光致变色聚乳酸/聚3-羟基丁酸酯共混纤维的纺制及其结构与性能[J]. 纺织学报, 2024, 45(12): 9-17. doi: 10.13475/j.fzxb.20230905101
	OU Zongquan, YU Jinchao, PAN Zhijuan. Spinning of photochromic polylactic acid/polyhydroxybutyrate blend fiber and its structure and properties[J]. Journal of Textile Research, 2024, 45(12): 9-17. doi: 10.13475/j.fzxb.20230905101
[23]	LIN L, MA X Y, XUE X Y, et al. In-situ growth of photochromic microcapsules for the preparation of fast-response, high color-fastness smart textiles[J]. Composites Communications, 2025, 57: 102467. doi: 10.1016/j.coco.2025.102467
[24]	ZHANG Y, GAO Z P, LIU F, et al. Electrostatic assembly of photochromic TiO₂/phosphomolybdic acid composite nanoparticles for light-responsive rewritable papers[J]. ACS Applied Nano Materials, 2022, 5(9): 13218-13226. doi: 10.1021/acsanm.2c02954
[25]	杨梦凡, 王潮霞, 殷允杰, 等. 棉织物的螺吡喃微胶囊印花及其光致变色性能[J]. 纺织学报, 2022, 43(9): 137-142.
	YANG Mengfan, WANG Chaoxia, YIN Yunjie, et al. Printing and photochromic properties of spiropyran microcapsules on cotton fabrics[J]. Journal of Textile Research, 2022, 43(9): 137-142.

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光致变色纺织品的制备及其防伪应用

Preparation of photochromic textiles and their anti-counterfeiting applications

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