纺织学报 ›› 2025, Vol. 46 ›› Issue (08): 245-253.doi: 10.13475/j.fzxb.20240900702

• 综合述评 • 上一篇    下一篇

聚苯硫醚薄膜的制备与改性及其应用研究进展

任天翔1, 陈江炳2, 房涛荣3, 詹莹韬2, 洪玉洁1, 许志强2, 徐煜东1(), 占海华1,4   

  1. 1.现代纺织技术创新中心(鉴湖实验室), 浙江 绍兴 312030
    2.凯泰特种纤维科技有限公司, 浙江 绍兴 312000
    3.浙江雅琪诺装饰材料有限公司, 浙江 绍兴 312000
    4.绍兴文理学院 纺织服装学院, 浙江 绍兴 312000
  • 收稿日期:2024-09-04 修回日期:2025-04-03 出版日期:2025-08-15 发布日期:2025-08-15
  • 通讯作者: 徐煜东(1994—),男,中级工程师,硕士。主要研究方向为高性能纤维及其复合材料的开发和应用。E-mail:yudong.xu@foxmail.com。
  • 作者简介:任天翔(1998—),男,初级工程师,硕士。主要研究方向为聚苯硫醚纤维及其复合材料的应用。
  • 基金资助:
    现代纺织技术创新中心(鉴湖实验室)科研专项基金项目(CXZX2023003HD)

Research progress in preparation, modification and application of polyphenylene sulfide film

REN Tianxiang1, CHEN Jiangbing2, FANG Taorong3, ZHAN Yingtao2, HONG Yujie1, XU Zhiqiang2, XU Yudong1(), ZHAN Haihua1,4   

  1. 1. Modern Textile Technology Innovation Center (Jianhu Laboratory), Shaoxing, Zhejiang 312030, China
    2. CTA High-tech Fiber Co., Ltd., Shaoxing, Zhejiang 312000, China
    3. Zhejiang Yaqinuo Decoration Material Co., Ltd., Shaoxing, Zhejiang 312000, China
    4. College of Textile and Garment, Shaoxing University, Shaoxing, Zhejiang 312000, China
  • Received:2024-09-04 Revised:2025-04-03 Published:2025-08-15 Online:2025-08-15

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摘要：

针对高性能聚苯硫醚(PPS)薄膜在研发过程中缺乏系统性理论指导的问题,阐述了挤出流延和挤出吹塑工艺对PPS薄膜结构和性能的影响,探讨了PPS薄膜在导电性能改性、表面活性改性及多功能改性方面的研究进展,详细综述了PPS薄膜在电容器、传感器和复合材料等领域的应用,并展望了PPS薄膜未来的发展方向。分析认为:挤出流延结合双向拉伸工艺是PPS薄膜产业化生产的一项成熟技术;PPS薄膜导电性能改性的关键在于改善碳质材料在PPS基体中的均匀分散性,表面活性改性中大气压等离子体改性技术值得进一步探索与推广,多功能改性需综合考量材料性能与环境健康之间的平衡;PPS薄膜在电容器和传感器领域的应用可聚焦于提升薄膜的耐热性、稳定性和抗电击穿特性等性能,玻璃纤维、碳纤维增强PPS薄膜复合材料在未来有着巨大的发展潜力。本综述旨在为PPS薄膜在传统产业升级和高端技术领域的发展提供有益的借鉴与参考。

关键词: 聚苯硫醚薄膜, 挤出吹塑工艺, 挤出流延工艺, 导电性能, 表面活性改性, 多功能改性

Abstract:

Significance Polyphenylene sulfide (PPS) film is an exceptional thermoplastic engineering plastic, characterized by a macromolecular chain structure that combines rigid phenylene rings with flexible thioether linkages. This unique combination endows the material with outstanding thermal resistance, flame retardancy, dielectric properties, and mechanical strength. Consequently, the application of PPS films has become increasingly widespread in high-end technological fields such as new energy vehicles, electronics, and aerospace. In recent years, driven by the inherent electrical insulation properties and relatively low surface chemical reactivity of PPS films, as well as the demand for high-performance functional film materials, researchers have conducted extensive studies on the preparation, modification, and application of PPS films.

Progress The raw material used for PPS film fabrication is a linear-structured resin with higher molecular weight and enhanced thermal stability. This study systematically elucidates the effects of extrusion casting and extrusion blow molding on the structure and properties of PPS films and provides a comparative analysis of the performance of uniaxially and biaxially stretched films. The influence of carbon nanotubes, graphene, and their derivatives as nanofillers on the electrical conductivity of PPS films is investigated, along with a detailed discussion of the conduction mechanisms of carbon-based materials within the PPS matrix. From the perspective of modification mechanisms, the effectiveness of plasma treatment in enhancing surface roughness and chemical activity is analyzed in depth. A comparative analysis is conducted on the principles and effects of low-temperature plasma modification and atmospheric-pressure plasma modification. Additionally, recent advances in the functional modifications of PPS films, including antibacterial, UV-resistant, and superhydrophobic properties, are explored. A comprehensive review is provided on the applications of PPS films in capacitors, sensors, and composite materials. Specifically, the dielectric breakdown resistance and self-healing characteristics of PPS films are analyzed, and their applications in phosphorescent oxygen sensors, fiber-optic acoustic sensors, and biomedical sensors are further introduced. PPS-based composite materials are further categorized into lightweight metal/PPS film composites, glass fiber/PPS film composites, and carbon fiber/PPS film composites. Finally, the future research directions and development prospects of PPS films are discussed.

Conclusion and prospect As a high-performance specialty engineering plastic, PPS has become a critical strategic material for the modernization of traditional industries and the advancement of high-end technologies worldwide. Given the challenges associated with PPS resin, including its high melting temperature, rapid crystallization rate, and relatively low melt viscosity stability, the combination of extrusion casting and biaxial stretching has been established as a mature technology for the large-scale production of high-performance PPS films. To further enhance the properties of PPS films and expand their application scope, extensive research efforts have been directed toward their electrical conductivity modification, surface activity modification, and multifunctional enhancement. The incorporation of carbon-based fillers, such as carbon nanotubes and graphene, has been demonstrated to effectively improve the electrical conductivity of PPS films, while the uniform dispersion of these carbonaceous materials within the PPS matrix is crucial for ensuring the long-term stability of the film’s electrical properties. Plasma treatment has shown significant potential in enhancing the hydrophilicity and chemical reactivity of PPS film surfaces. Future research could explore the application of atmospheric-pressure plasma modification techniques in PPS film surface engineering, thereby accelerating its industrialization. Additionally, achieving a balance between material performance and sustainability is essential when pursuing multifunctional modifications of PPS films. Currently, PPS films have found widespread applications in advanced fields such as capacitors, sensors, and composite materials. Future research should focus on enhancing the high-temperature resistance, dielectric breakdown strength, self-healing capabilities, and overall stability of PPS films. Furthermore, greater attention should be given to the development of glass fiber/PPS film composites and carbon fiber/PPS film composites for applications in sports equipment, electronic devices, and new energy vehicles. As a next-generation material for both traditional industry modernization and cutting-edge technology development, PPS films hold significant potential for future applications.

Key words: extrusion blow molding process, extrusion casting process, electrical conductivity, surface activity modification, mutifunctional modification

中图分类号: 

  • TQ324.8

表1

薄膜级PPS树脂的性能指标"

性能指标 对位聚苯
硫醚占比		 熔体质量流动速
率/(g·(10 min)-1)		 重均摩尔质量/
(kg·mol-1)
基础指标 80%以上 10~130 30~90
优选指标 90%以上 30~100 40~70

表2

聚苯硫醚薄膜的性能"

性能类别 PPS薄膜具体性能参数
力学特性 拉伸强度300 MPa、拉伸伸长率60%、冲击强度60 J/mm、模量4.6×104 MPa、耐蠕变性及耐疲劳性优异
耐热性 熔点281 ℃、热变形温度200 ℃、长期使用温度160 ℃、热膨胀系数3×10-6 K-1
阻燃性 自身阻燃性能达到UL94 VTM-0级、极限氧指数(LOI)>40%
化学性能 在硫酸、盐酸、氢氧化钠、氢氧化钾等溶液中表现出高稳定性,200 ℃下不溶于一般有机溶剂
电学性能 介电常数3.0、体积电阻率5×10-17 Ω·cm、具有优异的电绝缘性能
其它性能 对γ射线、中子束等放射线耐辐射指数为1×108 Gy;75%湿度下吸湿率为0.05%、吸湿膨胀系数为1.5×10-6
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