Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (12): 15-20.doi: 10.13475/j.fzxb.20210204706

• Fiber Materials • Previous Articles     Next Articles

Preparation and properties of cellulose/calcium alginate blend fiber

CHEN Zihan1, YAO Yongbo2(), SHENG Junlu2, YAN Zhiyong2, ZHANG Yumei3, WANG Huaping3   

  1. 1. Fashion Design Academy, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China
    2. Key Laboratory of Yarn Materials Forming and Composite Processing Technology of Zhejiang Province, Jiaxing University, Jiaxing, Zhejiang 314001, China
    3. State Key Laboratory of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received:2021-02-20 Revised:2021-09-13 Online:2021-12-15 Published:2021-12-29
  • Contact: YAO Yongbo E-mail:yaoyongbo@foxmail.com

RichHTML

34

PDF (PC)

244

Abstract:

In order to reduce the flammability of cellulose fibers, ionic liquid 1-allyl-3-methylimidazole chloride ([AMIM]Cl) was used as co-solvent for cellulose and alginic acid. Then, the cellulose/calcium alginate blend fiber was prepared with calcium chloride solution as the coagulation bath by dry-jet wet spinning. The effect of cellulose/calcium alginate blend ratio on the structure and properties of the fibers were studied. The results show that the cross-section of the blend fibers is dense, and the hydrogen bond interactions exist between cellulose and calcium alginate molecules. Despite the fact of the mechanical strength of the blend fibers decreases with the increase of calcium alginate content, the tensile strength reaches 123 MPa when the content of calcium alginate is 30%, and the self-extinguishing time from fire of this fiber is only 1.1 s, indicating excellent self-extinguishing property. In addition, the moisture regain of cellulose/calcium alginate blend fibers is 7.33%-7.75%, representing good hygrophilic property and wearability for regenerated cellulose fibers.

Key words: cellulose, calcium alginate, dry-jet wet spinning, flame retardant fiber, ionic liquid

CLC Number: 

  • TQ341.5

Tab.1

Spinning conditions for cellulose/calcium alginate blend fibers"

样品
编号		 海藻酸钙质量
分数/%		 凝固浴组成 牵伸
倍数
1# 0 水 4
2# 10 5%氯化钙溶液 4
3# 20 5%氯化钙溶液 4
4# 30 5%氯化钙溶液 4

Fig.1

Spinning schematic diagram of cellulose/calcium alginate blend fibers"

Fig.2

FT-IR spectra of cellulose/calcium alginate blend fiber fibers"

Fig.3

XRD pattern of cellulose/calcium alginate blend fibers"

Fig.4

Cross-section SEM images of cellulose/calcium alginate blend fibers"

Fig.5

Thermogravimetric curves of cellulose/calcium alginate blend fibers"

Tab.2

Mechanical properties of cellulose/calcium alginate blend fibers"

样品
编号		 直径/
μm		 断裂强
度/MPa		 初始模
量/GPa		 断裂伸
长率/%
1# 73.2±4.3 195±22.9 3.41±0.48 14.7±2.3
2# 69.1±5.2 189±31.8 3.14±0.68 15.9±3.1
3# 63.4±6.7 139±34.7 3.01±0.54 10.4±1.9
4# 65.9±4.9 123±35.9 2.58±0.73 8.7±1.1

Fig.6

Combustion properties of cellulose/calcium alginate blend fibers. (a)1# before combustion; (b)1# after combustion;(c)2# before combustion; (d)2# after combustion;(e)3# before combustion; (f)3# after combustion;(g)4# before combustion; (h)4# after combustion"

Fig.7

Hygroscopic properties of cellulose/calcium alginate blend fibers"

[1] 胡学超, 宋丽贞. 二十一世纪的宠儿:纤维素纤维[J]. 纺织学报, 1998, 19(1):63-64,26.
HU Xuechao, SONG Lizhen. The darling of the 21st century:cellulose fiber[J]. Journal of Textile Research, 1998, 19(1):63-64,26.
[2] 韩海云. 中欧消防员灭火防护服标准比较[J]. 消防科学与技术, 2010, 29(8):718-722.
HAN Haiyun. Comparative study on fire fighting protective clothing standards between China and European Union[J]. Fire Science and Technology, 2010, 29(8):718-722.
[3] 李振辉, 李霞, 于捍江, 等. 阻燃粘胶纤维研究进展[J]. 高分子通报, 2019(4):33-39.
LI Zhenhui, LI Xia, YU Hanjiang, et al. Research and advancement of flame-retardant fiber of regenerated cellulose[J]. Chinese Polymer Bulletin, 2019(4):33-39.
[4] 李树锋, 程博闻, 孙坤松, 等. 接枝改性阻燃高湿模量粘胶纤维的性能研究[J]. 纺织学报, 2006, 27(4):60-62.
LI Shufeng, CHENG Bowen, SUN Kunsong, et al. Study on the flame retardant HWM viscose fibers modified by grafting[J]. Journal of Textile Research, 2006, 27(4):60-62.
[5] 程博闻. 环境友好型阻燃纤维素纤维的阻燃性能及机理研究[J]. 天津工业大学学报, 2005, 24(1):1-3.
CHENG Bowen. Study on properties and mechanism of eco-friendly fire-retardant cellulose[J]. Journal of Tiangong University, 2005, 24(1):1-3.
[6] WU Kaijian, YAO Yongbo, YU Jinchao, et al. Cellulose/aromatic polysulfonamide blended fibers with improved properties[J]. Cellulose, 2017, 24(8):3377-3386.
doi: 10.1007/s10570-017-1351-5
[7] 程筒, 姚勇波, 陈忠丽, 等. 基于N-甲基吗啉-N-氧化物溶剂制备聚芳砜酰胺/纤维素阻燃纤维[J]. 纺织学报, 2019, 40(7):1-7.
CHENG Tong, YAO Yongbo, CHEN Zhongli, et al. Preparation of flame retardant aromatic polysulfonamide/cellulose fibers with N-methylmorpholine-N-oxide monohydrate as solvent[J]. Journal of Textile Research, 2019, 40(7):1-7.
[8] LEE Kuenyong, MOONEY David J. Alginate: properties and biomedical applications[J]. Progress in Polymer Science, 2012, 37(1):106-126.
pmid: 22125349
[9] ZHANG Chuanjie, LIU Yun, CUI Li, et al. Bio-based calcium alginate nonwoven fabrics: flame retardant and thermal degradation properties[J]. Journal of Analy-tical & Applied Pyrolysis, 2016, 122(11):13-23.
[10] KIM Yoojoo, YOON Keejong, KO Sohkwon. Preparation and properties of alginate superabsorbent filament fibers crosslinked with glutaraldehyde[J]. Journal of Applied Polymer Science, 2000, 78(10):1797-1804.
doi: 10.1002/(ISSN)1097-4628
[11] MUENDUEN Phisalaphong, SUWANMAJO Thapanar, TAMMARATE Pramote. Synjournal and characterization of bacterial cellulose/alginate blend membranes[J]. Journal of Applied Polymer Science, 2010, 107(5):3419-3424.
doi: 10.1002/(ISSN)1097-4628
[12] MAXIM M L, WHITE J F, BLOAK L E, et al. Advance biopolymer composite materials from ionic liquid solutions[M]. Ionic Liquids: Science and Applications, 2012:29-36.
[13] YANG G, ZHANG L, TAO P, et al. Effects of Ca2+ bridge cross-linking on structure and pervaporation of cellulose/alginate blend membranes[J]. Journal of Membrane Science, 2000, 175(1):53-60.
doi: 10.1016/S0376-7388(00)00407-5
[14] SHAMSHINA J L, GURAU G, BLOCK L E, et al. Chitin-calcium alginate composite fibers for wound care dressings spun from ionic liquid solution[J]. Journal of Materials Chemistry B, 2014, 2(25):3924-3936.
doi: 10.1039/C4TB00329B
[15] ZUGENMAIER P. Order in cellulosics: historical review of crystal structure research on cellulose[J]. Carbohydrate Polymers, 2021, 254:117417.
doi: 10.1016/j.carbpol.2020.117417
[16] XU Z, YAO Y, SHENG J, et al. Rheology of cellulose/alginic acid blends with 1-allyl-3-methylimidazolium chloride as solvent[J]. Polymer Engineering & Science, 2020, 60(2):243-249.
[17] PAWEL Sikorski, FRODE Mo, GUDMUND Skjak Braek, et al. Evidence for egg-box-compatible interactions in calcium-alginate gels from fiber X-ray diffraction[J]. Biomacromolecules, 2007, 8(7):2098-2103.
pmid: 17530892
[18] ZHANG X S, XIA Y Z, SHI M W, et al. The flame retardancy of alginate/flame retardant viscose fibers investigated by vertical burning test and cone calorimeter[J]. Chinese Chemical Letters, 2018, 29(3):489-492.
doi: 10.1016/j.cclet.2017.07.023
[19] WANG B, LI P, XU Y J, et al. Bio-based, nontoxic and flame-retardant cotton/alginate blended fibres as filling materials: thermal degradation properties, flammability and flame-retardant mechanism[J]. Composites Part B: Engineering, 2020, 194:108038.
doi: 10.1016/j.compositesb.2020.108038
[20] SIROKA B, NOISTERNIG M, GRIESSER U J, et al. Characterization of cellulosic fibers and fabrics by sorption/desorption[J]. Carbohydrate Research, 2008, 343(12):2194-2199.
doi: 10.1016/j.carres.2008.01.037
[21] YAO Y, ZHANG E, XIA X, et al. Morphology and properties of cellulose/silk fibroin blend fiber preparedwith 1-butyl-3-methylimidazolium chloride as solvent[J]. Cellulose, 2015, 22(1):625-635.
doi: 10.1007/s10570-014-0520-z
[1] LI Zhenzhen , ZHI Chao , YU Lingjie , ZHU Hai , DU Mingjuan. Preparation and properties of waste cotton regenerative aerogel / warp-knitted spacer fabric composites [J]. Journal of Textile Research, 2022, 43(01): 167-171.
[2] LUO Xiaolei , LIU Lin , YAO Juming . Preparation and study of pure biomass cellulose aerogels for flame retardancy  [J]. Journal of Textile Research, 2022, 43(01): 1-8.
[3] FANG Yinchun , SUN Weihao. Research progress in flame retardant cellulose aerogel [J]. Journal of Textile Research, 2022, 43(01): 43-48.
[4] ZHANG Tingting, XU Kexin, JIN Mengtian, GE Shijie, GAO Guohong, CAI Yixiao, WANG Huaping. Recent progress in preparation of cellulose-based organic-inorganic photocatalysts nanohybrids and it's application in water treatment [J]. Journal of Textile Research, 2021, 42(07): 175-183.
[5] LIU Ke, CHEN Shuang, XIAO Ru. Preparation and properties of synergistic flame retardant copolyamide 6 fiber with phosphaphenanthrene group [J]. Journal of Textile Research, 2021, 42(07): 11-18.
[6] XU Kai, TIAN Xing, CAO Ying, HE Yaqi, XIA Yanzhi, QUAN Fengyu. Preparation and property of flame retardant polyester/calcium alginate fiber composites [J]. Journal of Textile Research, 2021, 42(07): 19-24.
[7] LIN Shenggen, LIU Xiaohui, SU Xiaowei, HE Ju, REN Yuanlin. Preparation and properties of Lyocell fibers and fabrics modified with new phytic acid based flame retardant [J]. Journal of Textile Research, 2021, 42(07): 25-30.
[8] GU Weiwen, WANG Wenqing, WEI Lifei, SUN Chenying, HAO Dan, WEI Jianfei, WANG Rui. Influence of carbon dots on properties of flame retardant poly(ethylene terephthalate) [J]. Journal of Textile Research, 2021, 42(07): 1-10.
[9] YU Meiqiong, YUAN Hongmei, CHEN Lihui. Rheological properties of cellulose/LiCl/ N, N-dimethylacetamide solution [J]. Journal of Textile Research, 2021, 42(05): 23-30.
[10] HU Jing, ZHANG Kaiwei, LI Ranran, LIN Jinyou, LIU Yuqing. Preparation of flax layered nano-cellulose and properties of its reinforced thermoelectric composites [J]. Journal of Textile Research, 2021, 42(02): 47-52.
[11] YUAN Jiugang, JI Ji, XUE Qi, JIANG Zhe, FAN Xuerong, GAO Weidong. Dissolution and regeneration of wool keratin in choline thioglycolate [J]. Journal of Textile Research, 2021, 42(01): 35-39.
[12] LI Junyu, JIANG Peiqing, ZHANG Wenqi, LI Wenbin. Effect of atomic layer deposition technology on functionalization of cellulose membrane [J]. Journal of Textile Research, 2020, 41(12): 26-30.
[13] MA Yue, GUO Jing, YIN Juhui, ZHAO Miao, GONG Yumei. Preparation and characterization of cellulose/dialdehyde cellulose/Antarctic krill protein antibacterial fibers [J]. Journal of Textile Research, 2020, 41(11): 34-40.
[14] LIU Fang, MA Yanxue, CHEN Xiaoguang, LIU Shuhui, ZHANG Yizhen, REN Zhipeng, LI Kangqi, TONG Yixuan, REN Luotong, LI Yuling. Study on process performance of ramie fiber anaerobic biological degumming system [J]. Journal of Textile Research, 2020, 41(11): 89-94.
[15] QU Yongshuai, SHI Zhaohe, ZHANG Ruiyun, ZHAO Shuyuan, LIU Liu. Effect of anthraquinone additive on properties of glycol solvent degummed ramie fibers [J]. Journal of Textile Research, 2020, 41(11): 81-88.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 33 -34 .
[2] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 35 -36 .
[3] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 107 .
[4] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 109 -620 .
[5] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 101 -102 .
[6] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 105 -107 .
[7] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 108 -110 .
[8] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 111 -113 .
[9] PAN Xu-wei;GU Xin-jian;HAN Yong-sheng;CHENG Yao-dong. Research on quick response of apparel supply chain for collaboration[J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(1): 54 -57 .
[10] HUANG Xiao-hua;SHEN Ding-quan. Degumming and dyeing of pineapple leaf fiber[J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(1): 75 -77 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd