Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (08): 8-16.doi: 10.13475/j.fzxb.20210301109

• Academic Salon Column for New Insight of Textile Science and Technology: Recycling and Biodegradable Fiber • Previous Articles     Next Articles

Progress in preparation and structure-property relationship of bio-based polyesters of isohexides

WANG Yaning1,2, ZHOU Chufan2, WU Jing1,3(), WANG Huaping2,3   

  1. 1. Co-Innovation Center for Textile Industry, Donghua University, Shanghai 201620, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received:2021-03-01 Revised:2021-05-17 Online:2021-08-15 Published:2021-08-24
  • Contact: WU Jing E-mail:wuj@dhu.edu.cn

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Abstract:

As a family of diols derived from carbohydrates, isohexides are promising building blocks for preparation of new bio-based and biodegradable polymers due to their attractive properties including high rigidity, chirality, hydrophilicity and low toxicity. In this review, a few types of isohexide-based aliphatic and semi-aromatic homo- and co-polyesters extensively studied in recent years were systematically discussed in terms of their synthesis, thermal properties, physical properties, biodegradability and potential applications. Furthermore, the polymerization process for higher efficiency and the structure-property relationship of these polyesters were also examined. It can be concluded that the introduction of isohexides building blocks effectively increases the glass transition temperature of polymers and promote the ability of hydrolysis and biodegradation, thus offering great potential in the construction of environmentally friendly polyesters which are expected to be used in engineering plastics, fibers, biomedical fields, and so on. It is pointed out that the large-scale commercialization of such bio-based polyesters requires further development of more efficient and mild polymerization process to overcome the problems in heat sensitivity and thermal degradation.

Key words: bio-based material, biodegradable material, polyester, isohexide, isosorbide, structure-property relationship

CLC Number: 

  • TQ323

Fig.1

Three isomers of isohexides. (a)Isosorbide; (b)Isomannide;(c)Isoidide"

Fig.2

Synthetic route of polyesters based on isohexides and aliphatic dicarboxylic acid chlorides"

Fig.3

Synthetic route of polyesters based on isosorbide and dicarboxylic acids with different chain lengths"

Fig.4

Chemical structures and synthetic routes of typical copolyesters based on isosorbide"

Fig.5

Synthesis of copolyesters with isosorbide, succinic acid and different diols"

Fig.6

SEM images of PCIT(a) and 14% PEICT (b) nanofibers"

Fig.7

TEM images of 10% PCIT/honey (a) and 5% ZnO/PCIT (b) nanofibers"

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