纺织学报 ›› 2026, Vol. 47 ›› Issue (1): 240-249.doi: 10.13475/j.fzxb.20250304802
王世豪1, 徐晓禹2, 郑挺3, 王金星4, 姚德刚5, 王俊5, 叶翔宇6, 田慧7, 李婷8, 朱斐超1(
)
WANG Shihao1, XU Xiaoyu2, ZHENG Ting3, WANG Jinxing4, YAO Degang5, WANG Jun5, YE Xiangyu6, TIAN Hui7, LI Ting8, ZHU Feichao1(
)
摘要:
碳纤维非织造材料是通过非织造生产工艺对不同碳纤维原料进行加工得到的同时具有碳纤维和非织造材料性能的特殊材料。为推动该材料的应用,综述了针刺、水刺、湿法、熔喷、静电纺丝法、离心纺丝法等碳纤维非织造材料的原料、成形工艺、产品优势与面临的问题。分别讨论了国内外碳纤维毡、碳纤维纸、碳纤维膜的产能规模,产品性能及最新研究进展,受限于碳纤维材料的性能瓶颈与产能约束,国内在碳纤维非织造材料的工业化生产仍处于追赶阶段,而科研领域对碳纤维材料的研究热度持续高涨与成果产出频现,预示未来碳纤维非织造材料在国内规模化发展的市场前景。最后展望了碳纤维非织造材料的发展方向,为碳纤维非织造材料的高值化应用提供借鉴。
中图分类号:
| [1] | 葛慧敏. 非织造空气过滤材料压缩状态结构与性能的预测研究[D]. 上海: 东华大学, 2025: 52. |
| GE Huimin. Study on the prediction of the structure and properties of nonwoven air filter materials under compression state. Shanghai: Donghua University, 2025: 52. | |
| [2] | 孙颖颖. 超柔软水刺非织造布的制备工艺研究[J]. 纺织科学研究, 2024, 35(4): 52-54. |
| SUN Yingying. Study on preparation technology of super soft spunlaced nonwovens[J]. Textile Science Research, 2024, 35(4): 52-54. | |
| [3] | 曹洪硕, 周明正, 敖静, 等. 高分散水性碳纤维的制备[J]. 中国造纸, 2024, 43(4): 48-54. |
| CAO Hongshuo, ZHOU Mingzheng, AO Jing, et al. Preparation of highly dispersed aqueous carbon fibers[J]. China Pulp & Paper, 2024, 43(4): 48-54. | |
| [4] | YUE Z R, LIU C, VAKILI A, et al. Meltblown solvated mesophase pitch-based carbon fibers: fiber evolution and characteristics[J]. C, 2017, 3(3): 26. |
| [5] | WANG S C, BAI J X, INNOCENT M T, et al. Lignin-based carbon fibers: formation, modification and potential applications[J]. Green Energy & Environment, 2022, 7(4): 578-605. |
| [6] | 徐威, 夏磊, 周兴海, 等. 纺丝工艺及预氧化条件对离心纺聚丙烯腈基纳米碳纤维的影响[J]. 纺织学报, 2016, 37(2): 7-12. |
| XU Wei, XIA Lei, ZHOU Xinghai, et al. Influence of spinning process and pre-oxidation conditions on PAN-based carbon nanofibers fabricated by centrifugal spinning[J]. Journal of Textile Research, 2016, 37(2): 7-12. | |
| [7] | 曹作暄. PAN基碳纤维针刺毡制备工艺及性能的研究[D]. 大连: 大连理工大学, 2012: 22. |
| CAO Zuoxuan. The investigation of preparation technics and properties of needle-punching felt made of PAN-based carbon fiber[D]. Dalian: Dalian University of Technology, 2012: 22. | |
| [8] |
JABBOUR L, CHAUSSY D, EYRAUD B, et al. Highly conductive graphite/carbon fiber/cellulose composite papers[J]. Composites Science and Technology, 2012, 72(5): 616-623.
doi: 10.1016/j.compscitech.2012.01.006 |
| [9] | 梁富敬. 碳纤维非织造布生产及其应用[J]. 非织造布, 2009, 17(6): 7-9. |
| LIANG Fujing. Production and application of carbon fiber nonwovens[J]. Nonwovens, 2009, 17(6): 7-9. | |
| [10] | 张倩玉, 李伏虎, 金芮昕. 沥青基碳纤维的制备与应用研究进展[J]. 化工新型材料, 2023, 51(S2): 565-568. |
| ZHANG Qianyu, LI Fuhu, JIN Ruixin. Research progress in preparation and application of pitch-based carbon fiber[J]. New Chemical Materials, 2023, 51(S2): 565-568. | |
| [11] |
SUN Z, ZUSSMAN E, YARIN A L, et al. Compound core-shell polymer nanofibers by co-electro-spinning[J]. Advanced Materials, 2003, 15(22): 1929-1932.
doi: 10.1002/adma.v15:22 |
| [12] |
CHIANG Y C, CHIN W T, HUANG C C, et al. The application of hollow carbon nanofibers prepared by electrospinning to carbon dioxide capture[J]. Polymers, 2021, 13(19): 3275.
doi: 10.3390/polym13193275 |
| [13] |
YE C, WU H, ZHU S P, et al. Microstructure of high thermal conductivity mesophase pitch-based carbon fibers[J]. New Carbon Materials, 2021, 36(5): 980-985.
doi: 10.1016/S1872-5805(21)60050-1 |
| [14] | 沥青基碳纤维的性能和用途[J]. 合成纤维, 2014, 43(11): 53-54. |
| Properties and uses of pitch-based carbon fiber[J]. Synthetic Fiber in China, 2014, 43(11): 53-54. | |
| [15] | 梁燕, 徐爱武, 张贺轩, 等. 黏胶基碳纤维的发展及应用[J]. 化纤与纺织技术, 2022, 51(5): 10-12. |
| LIANG Yan, XU Aiwu, ZHANG Hexuan, et al. Development and application of viscose-based carbon fiber[J]. Chemical Fiber & Textile Technology, 2022, 51(5): 10-12. | |
| [16] | 王宏岗, 许萍. 中国碳纤维市场发展状况分析[J]. 中外能源, 2025, 30(4): 64-69. |
| WANG Honggang, XU Ping. Analysis of development of China's carbon fiber market[J]. Sino-Global Energy, 2025, 30(4): 64-69. | |
| [17] | 苏君明, 邵海成, 肖志超, 等. 低烧蚀率针刺炭纤维炭/炭复合材料喉衬的制备与性能研究[J]. 炭素技术, 2013, 32(6): 7-11. |
| SU Junming, SHAO Haicheng, XIAO Zhichao, et al. Preparation and properties of needling carbon/carbon composites throat with low ablation rate[J]. Carbon Techniques, 2013, 32(6): 7-11. | |
| [18] | ZHENG Z R, REN L L, WANG H Y. Preparation and properties of thermal insulation felts for firefighting protective clothing[J]. Journal of Industrial Textiles, 2024, 54: 15280837241276917. |
| [19] |
FRANK E, HERMANUTZ F, BUCHMEISER M R. Carbon fibers: precursors, manufacturing, and properties[J]. Macromolecular Materials and Engineering, 2012, 297(6): 493-501.
doi: 10.1002/mame.v297.6 |
| [20] | 沈国炜. 熔融纺丝制备高性能中空沥青基碳纤维[D]. 北京: 北京化工大学, 2007: 4-5. |
| SHEN Guowei. Melt-spinning of hollow fibers from mesophase pitch[D]. Beijing: Beijing University of Chemical Technology, 2007: 4-5. | |
| [21] | 姚锋, 权银洙, 彭公秋, 等. 中间相沥青基碳纤维发展现状与分析[J]. 高科技纤维与应用, 2024, 49(5): 25-32. |
| YAO Feng, QUAN Yinzhu, PENG Gongqiu, et al. Development status and analysis of mesophase pitch-based carbon fibers[J]. Hi-Tech Fiber & Application, 2024, 49(5): 25-32. | |
| [22] | 钱伯章. 辽宁诺科碳材中间相沥青基碳纤维实现量产[J]. 合成纤维, 2019, 48(11): 56. |
| QIAN Bozhang. Liaoning Nuoke carbon mesophase pitch-based carbon fiber realizes mass production[J]. Synthetic Fiber in China, 2019, 48(11): 56. | |
| [23] |
BREITENBACH S, UNTERWEGER C, LUMETZBERGER A, et al. Viscose-based porous carbon fibers: improving yield and porosity through optimization of the carbonization process by design of experiment[J]. Journal of Porous Materials, 2021, 28(3): 727-739.
doi: 10.1007/s10934-020-01026-4 |
| [24] |
XIE Z Y, WANG F, ZHAO N, et al. Hydrophobisation of activated carbon fiber and the influence on the adsorption selectivity towards carbon disulfide[J]. Applied Surface Science, 2011, 257(8): 3596-3602.
doi: 10.1016/j.apsusc.2010.11.085 |
| [25] | 何延彤. 粘胶基活性碳纤维毡抗菌敷料的制备及其性能研究[D]. 上海: 东华大学, 2024: 73-75. |
| HE Yantong. Study on preparation and properties of viscose-based activated carbon fiber felt antibacterial dressing. Shanghai: Donghua University, 2024: 73-75. | |
| [26] | 嵇阿琳, 崔红, 李贺军, 等. 两种针刺纤维性能与成型性分析[J]. 固体火箭技术, 2010, 33(2): 222-224, 228. |
| JI Alin, CUI Hong, LI Hejun, et al. Investigation on property and figuration for two kinds of needling fiber[J]. Journal of Solid Rocket Technology, 2010, 33(2): 222-224, 228. | |
| [27] | 董洪年, 杨明, 林天一, 等. 针刺密度对碳/碳复合材料力学行为影响的仿真分析[J]. 材料导报, 2025, 39(9): 52-57. |
| DONG Hongnian, YANG Ming, LIN Tianyi, et al. Effects of needle density on mechanical behavior of carbon/carbon composite[J]. Materials Reports, 2025, 39(9): 52-57. | |
| [28] | 杨国勇, 刘振宇, 张楠, 等. 碳/碳复合材料针刺制品性能分析及工艺参数优化[J/OL]. 复合材料科学与工程, 2025: 1-7. |
| YANG Guoyong, LIU Zhenyu, ZHANG Nan, et al. Product performance analysis and process parameter optimization of needle-punched C/C composite mate-rial[J/OL]. Composites Science and Engineering, 2025: 1-7. | |
| [29] | 付晓娟. 电磁屏蔽非织造布的研究与开发[D]. 西安: 西安工程大学, 2015: 20-21. |
| FU Xiaojuan. The research and development of non-woven fabric for electromagnetic shielding[D]. Xi'an: Xi'an Polytechnic University, 2015: 20-21. | |
| [30] |
WU X F, TANG B, CHEN J, et al. Epoxy composites with high cross-plane thermal conductivity by constructing all-carbon multidimensional carbon fiber/graphite networks[J]. Composites Science and Technology, 2021, 203: 108610.
doi: 10.1016/j.compscitech.2020.108610 |
| [31] | 李东洁, 李杰, 郑亲涛, 等. 气体扩散层用碳纤维纸制备和性能研究[J]. 造纸装备及材料, 2021, 50(4): 45-49. |
| LI Dongjie, LI Jie, ZHENG Qintao, et al. Study on preparation and properties of carbon paper for the gas diffusion layer[J]. Papermaking Equipment & Materials, 2021, 50(4): 45-49. | |
| [32] |
MATHUR R B, MAHESHWARI P H, DHAMI T L, et al. Processing of carbon composite paper as electrode for fuel cell[J]. Journal of Power Sources, 2006, 161(2): 790-798.
doi: 10.1016/j.jpowsour.2006.05.053 |
| [33] | 张美云, 钟林新, 彭新文. 碳纤维屏蔽纸制造过程中纤维分散性能的研究[J]. 中华纸业, 2008, 29(6): 10-13. |
| ZHANG Meiyun, ZHONG Linxin, PENG Xinwen. A study on dispersing properties of carbon fibers in the process of carbon fibers in the process of carbon fiber shielding paper[J]. China Pulp & Paper Industry, 2008, 29(6): 10-13. | |
| [34] | 华飞果, 吴帅, 童树华, 等. 短切碳纤维最佳分散工艺研究[J]. 中国造纸, 2019, 38(4): 41-44. |
| HUA Feiguo, WU Shuai, TONG Shuhua, et al. Study on the best dispersing technology of chopped carbon fibers[J]. China Pulp & Paper, 2019, 38(4): 41-44. | |
| [35] |
ZHANG X R, PEI X Q, MU B, et al. Effect of carbon fiber surface treatments on the flexural strength and tribological properties of short carbon fiber/polyimide composites[J]. Surface and Interface Analysis, 2008, 40(5): 961-965.
doi: 10.1002/sia.v40:5 |
| [36] |
LAKSHMINARAYANAN P V, TOGHIANI H, PITTMAN C U. Nitric acid oxidation of vapor grown carbon nanofibers[J]. Carbon, 2004, 42(12/13): 2433-2442.
doi: 10.1016/j.carbon.2004.04.040 |
| [37] | 王贺团, 沈志刚, 邓明妤, 等. 碳纤维表面电化学氧化处理技术研究进展[J]. 化工新型材料, 2023, 51(S2): 48-52. |
| WANG Hetuan, SHEN Zhigang, DENG Mingyu, et al. Research progress on electrochemical oxidation treatment technology of carbon fiber surface[J]. New Chemical Materials, 2023, 51(S2): 48-52. | |
| [38] | 胡蓉蓉, 李梦佳, 华飞果, 等. 两亲改性碳纤维制备质子交换膜燃料电池用碳纸的研究[J]. 中国造纸, 2020, 39(3): 15-21. |
| HU Rongrong, LI Mengjia, HUA Feiguo, et al. Study on preparation of carbon paper for proton exchange membrane fuel cell by amphiphilic modified carbon fibers[J]. China Pulp & Paper, 2020, 39(3): 15-21. | |
| [39] | 邢迪. 柔性超薄短切碳纤维复合材料的成型及其电磁屏蔽性能研究[D]. 广州: 华南理工大学, 2019: 42-57. |
| XING Di. Molding and electromagnetic interference shielding performance of flexible and ultrathin chopped carbon fiber composites[D]. Guangzhou: South China University of Technology, 2019: 42-57. | |
| [40] |
WANG H Y, ZU D, JIANG X Y, et al. Bifunctional activated carbon ultrathin fibers: combining the removal of VOCs and PM in one material[J]. Advanced Fiber Materials, 2023, 5(6): 1934-1948.
doi: 10.1007/s42765-023-00309-0 |
| [41] | 王晶, 徐圣俊, 杨革生, 等. Lyocell熔喷纤维炭膜的吸附性能[J]. 纤维素科学与技术, 2017, 25(1): 45-49. |
| WANG Jing, XU Shengjun, YANG Gesheng, et al. Adsorption of lyocell melt-blown fibers carbon membranes[J]. Journal of Cellulose Science and Technology, 2017, 25(1): 45-49. | |
| [42] | 吴志语. 高效离心纺丝制备聚丙烯腈碳纤维纸及其性能研究[D]. 武汉: 武汉纺织大学, 2023: 11-23. |
| WU Zhiyu. Preparation and properties of polyacrylonitrile carbon fiber paper by high efficiency centrifugal spinning[D]. Wuhan: Wuhan Textile University, 2023: 11-23. | |
| [43] |
QU E L, CHEN T, XIAO Q Z, et al. Flexible freestanding 3D Si/C composite nanofiber film fabricated using the electrospinning technique for lithium-ion batteries anode[J]. Solid State Ionics, 2019, 337: 70-75.
doi: 10.1016/j.ssi.2019.04.017 |
| [44] | ZHANG L K, CHEN Y, LIU Q, et al. Ultrathin flexible electrospun carbon nanofibers reinforced graphene microgasbags films with three-dimensional conductive network toward synergetic enhanced electromagnetic interference shielding[J]. Journal of Materials Science & Technology, 2022, 111: 57-65. |
| [45] | 兰谢冬, 秦统, 吕苗. 无针静电纺丝技术制备PAN纳米纤维膜材料研究[J]. 宝钢技术, 2025(2): 33-38. |
| LAN Xiedong, QIN Tong, LYU Miao. Research on the preparation of PAN nanofiber membrane material using needle-free electrospinning technology[J]. Baosteel Technology, 2025(2): 33-38. |
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